POLAROGRAPHIC AND POTENTIOSTATIC REDUCTION OF CARBODIIMIDES: A MECHANISTIC STUDY

The polarographic reduction of aromatic carbodiimides in anhydrous aprotic solvents goes through a carbene intermediate by a diffusion controlled process in two one-electron steps. The first step is the rate-determining step and converts the carbodiirnide to a radical anion (6) that reduces further...

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Bibliographic Details
Format: Article
Language:English
Published: University of Tehran 1996-09-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31115_463d94080e3c9aa9ac65a38b7140113b.pdf
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