Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications
Functional polymer composites offer versatility and high performance through material fusion, but flammability is an obstacle to application. Metal–organic frameworks (MOFs) have attracted attention in the field of flame retardant due to their structural diversity and high specific surface area, but...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-06-01
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| Series: | Small Science |
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| Online Access: | https://doi.org/10.1002/smsc.202400611 |
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| author | Xue Bi Yanan Hou Ye‐Tang Pan Siqi Huo Congling Shi Jiyu He Rongjie Yang |
| author_facet | Xue Bi Yanan Hou Ye‐Tang Pan Siqi Huo Congling Shi Jiyu He Rongjie Yang |
| author_sort | Xue Bi |
| collection | DOAJ |
| description | Functional polymer composites offer versatility and high performance through material fusion, but flammability is an obstacle to application. Metal–organic frameworks (MOFs) have attracted attention in the field of flame retardant due to their structural diversity and high specific surface area, but they suffer from low efficiency and agglomeration issues when used alone. Combining with two‐dimensional (2D) nanomaterials can improve the above situation. Herein, strategies are explored for integrating MOFs with 2D materials through physical mixing and in situ growth to enhance their dispersion and flame‐retardant effects in polymers. Additionally, the integration of sensing performance can achieve intelligent monitoring and control, as well as real‐time risk assessment and system optimization. In summary, this review deeply analyzes the dispersion, interfacial interaction, and performance adjustment mechanism of composite materials and discusses in detail the application potential of MOFs and hybrids formed by 2D materials in the field of flame retardant and sensing. Finally, the opportunities and challenges faced by the integration of MOFs and 2D materials in functional polymer composites in the future are summarized and prospected. Herein, it is also expected to facilitate researchers to quickly understand the latest developments in the field and guide their effective design. |
| format | Article |
| id | doaj-art-436b379a3bda4eecadbe5eb8101b89c6 |
| institution | DOAJ |
| issn | 2688-4046 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Small Science |
| spelling | doaj-art-436b379a3bda4eecadbe5eb8101b89c62025-08-20T03:20:56ZengWiley-VCHSmall Science2688-40462025-06-0156n/an/a10.1002/smsc.202400611Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor ApplicationsXue Bi0Yanan Hou1Ye‐Tang Pan2Siqi Huo3Congling Shi4Jiyu He5Rongjie Yang6Beijing Key Laboratory of MetroFire and Passenger Transportation Safety China Academy of Safety Science andTechnology Beijing 100012 ChinaCollege of Geological Engineeringand Geomatics Chang'an University Xi'an 710064 Shaanxi ChinaBeijing Key Laboratory of MetroFire and Passenger Transportation Safety China Academy of Safety Science andTechnology Beijing 100012 ChinaSchool of Engineering, Centre for Future Materials University of Southern Queensland Springfield 4300 AustraliaBeijing Key Laboratory of MetroFire and Passenger Transportation Safety China Academy of Safety Science andTechnology Beijing 100012 ChinaNational Engineering ResearchCenter of Flame Retardant Materials School of Materials Science & Engineering, Beijing Institute of Technology Beijing 100081 PR ChinaNational Engineering ResearchCenter of Flame Retardant Materials School of Materials Science & Engineering, Beijing Institute of Technology Beijing 100081 PR ChinaFunctional polymer composites offer versatility and high performance through material fusion, but flammability is an obstacle to application. Metal–organic frameworks (MOFs) have attracted attention in the field of flame retardant due to their structural diversity and high specific surface area, but they suffer from low efficiency and agglomeration issues when used alone. Combining with two‐dimensional (2D) nanomaterials can improve the above situation. Herein, strategies are explored for integrating MOFs with 2D materials through physical mixing and in situ growth to enhance their dispersion and flame‐retardant effects in polymers. Additionally, the integration of sensing performance can achieve intelligent monitoring and control, as well as real‐time risk assessment and system optimization. In summary, this review deeply analyzes the dispersion, interfacial interaction, and performance adjustment mechanism of composite materials and discusses in detail the application potential of MOFs and hybrids formed by 2D materials in the field of flame retardant and sensing. Finally, the opportunities and challenges faced by the integration of MOFs and 2D materials in functional polymer composites in the future are summarized and prospected. Herein, it is also expected to facilitate researchers to quickly understand the latest developments in the field and guide their effective design.https://doi.org/10.1002/smsc.202400611flame retardantmetal–organic frameworksperformance and mechanismsensingtwo‐dimensional materials |
| spellingShingle | Xue Bi Yanan Hou Ye‐Tang Pan Siqi Huo Congling Shi Jiyu He Rongjie Yang Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications Small Science flame retardant metal–organic frameworks performance and mechanism sensing two‐dimensional materials |
| title | Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications |
| title_full | Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications |
| title_fullStr | Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications |
| title_full_unstemmed | Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications |
| title_short | Metal–Organic Frameworks Meet Two‐Dimensional Materials in Polymer Matrices for Flame Retardant and Sensor Applications |
| title_sort | metal organic frameworks meet two dimensional materials in polymer matrices for flame retardant and sensor applications |
| topic | flame retardant metal–organic frameworks performance and mechanism sensing two‐dimensional materials |
| url | https://doi.org/10.1002/smsc.202400611 |
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