Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts

The search for new tools appear to be crucial to ensure sustainable weed management and the study of allelochemicals in plants plays a strategic role in the eco-friendly agrochemical development. This study aims, for the first time, to identify and quantify allelopathic substances in aqueous extract...

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Main Authors: Giacomo Trespidi, Valeria Xotta, Stefania Sut, Stefan Otto, Nebojša Nikolić, Elisa Strati, Sara Vitalini, Stefano Dall’Acqua, Marcello Iriti, Roberta Masin, Donato Loddo
Format: Article
Language:English
Published: Frontiers Media S.A. 2025-05-01
Series:Frontiers in Agronomy
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Online Access:https://www.frontiersin.org/articles/10.3389/fagro.2025.1542124/full
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author Giacomo Trespidi
Valeria Xotta
Stefania Sut
Stefan Otto
Nebojša Nikolić
Elisa Strati
Sara Vitalini
Stefano Dall’Acqua
Marcello Iriti
Roberta Masin
Donato Loddo
author_facet Giacomo Trespidi
Valeria Xotta
Stefania Sut
Stefan Otto
Nebojša Nikolić
Elisa Strati
Sara Vitalini
Stefano Dall’Acqua
Marcello Iriti
Roberta Masin
Donato Loddo
author_sort Giacomo Trespidi
collection DOAJ
description The search for new tools appear to be crucial to ensure sustainable weed management and the study of allelochemicals in plants plays a strategic role in the eco-friendly agrochemical development. This study aims, for the first time, to identify and quantify allelopathic substances in aqueous extracts from leaves (BL) and roots (BR) of the invasive species Baccharis halimifolia L. (Asteraceae) and to assess their phytotoxic activity at different dilutions in both germination tests and greenhouse pot trials for the weed species Abutilon theophrasti Medik., Solanum nigrum L., Lolium rigidum Gaudin and Setaria pumila Roem. & Schult. HPLC-DAD-(ESI)-MS analysis revealed the presence of several saponins and phenolics (e.g. Apigenin and Protocatechuic acid), possibly implicated in the observed phytotoxic action. The most relevant effects were observed in the germination test, where BR was more effective than BL and at 20% v/v dilution caused a 50-75% reduction in root length of all weed species. Maximum reduction (>85%) in root length occurred at 100% v/v dilution of both extracts for all species. Pre- and post-emergence greenhouse trials showed unstable and variable herbicidal activity among the tested species and extract doses. Effects were observed mainly on the grasses S. pumila and L. rigidum, where BR application in post-emergence reduced plant biomass by 42% and 34%. This study suggests that B. halimifolia could be a potential source of natural herbicides; however, it also showed the difficulties in reproducing, under the field-like conditions of pot trials, the phytotoxic effects observed in germination tests due to radical differences in applied doses and exposure conditions. This highlights the importance of studies that consider field application and the need of green extraction methodologies that improve active substances concentration in extract.
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spelling doaj-art-43430f16f51e4e41ba89eb93c5ea05012025-08-20T02:24:54ZengFrontiers Media S.A.Frontiers in Agronomy2673-32182025-05-01710.3389/fagro.2025.15421241542124Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extractsGiacomo Trespidi0Valeria Xotta1Stefania Sut2Stefan Otto3Nebojša Nikolić4Elisa Strati5Sara Vitalini6Stefano Dall’Acqua7Marcello Iriti8Roberta Masin9Donato Loddo10Institute for Sustainable Plant Protection, National Research Council of Italy, Legnaro, Padua, ItalyDepartment of Agronomy, Food, Natural Resources, Animals and Environment, University of Padova, Legnaro, Padua, ItalyDepartment of Pharmaceutical and Pharmacological Sciences, University of Padova, Padova, ItalyInstitute for Sustainable Plant Protection, National Research Council of Italy, Legnaro, Padua, ItalyDepartment of Agronomy, Food, Natural Resources, Animals and Environment, University of Padova, Legnaro, Padua, ItalyInstitute for Sustainable Plant Protection, National Research Council of Italy, Legnaro, Padua, ItalyDepartment of Biomedical, Surgical and Dental Sciences, University of Milan, Milano, ItalyDepartment of Pharmaceutical and Pharmacological Sciences, University of Padova, Padova, ItalyDepartment of Biomedical, Surgical and Dental Sciences, University of Milan, Milano, ItalyDepartment of Agronomy, Food, Natural Resources, Animals and Environment, University of Padova, Legnaro, Padua, ItalyInstitute for Sustainable Plant Protection, National Research Council of Italy, Legnaro, Padua, ItalyThe search for new tools appear to be crucial to ensure sustainable weed management and the study of allelochemicals in plants plays a strategic role in the eco-friendly agrochemical development. This study aims, for the first time, to identify and quantify allelopathic substances in aqueous extracts from leaves (BL) and roots (BR) of the invasive species Baccharis halimifolia L. (Asteraceae) and to assess their phytotoxic activity at different dilutions in both germination tests and greenhouse pot trials for the weed species Abutilon theophrasti Medik., Solanum nigrum L., Lolium rigidum Gaudin and Setaria pumila Roem. & Schult. HPLC-DAD-(ESI)-MS analysis revealed the presence of several saponins and phenolics (e.g. Apigenin and Protocatechuic acid), possibly implicated in the observed phytotoxic action. The most relevant effects were observed in the germination test, where BR was more effective than BL and at 20% v/v dilution caused a 50-75% reduction in root length of all weed species. Maximum reduction (>85%) in root length occurred at 100% v/v dilution of both extracts for all species. Pre- and post-emergence greenhouse trials showed unstable and variable herbicidal activity among the tested species and extract doses. Effects were observed mainly on the grasses S. pumila and L. rigidum, where BR application in post-emergence reduced plant biomass by 42% and 34%. This study suggests that B. halimifolia could be a potential source of natural herbicides; however, it also showed the difficulties in reproducing, under the field-like conditions of pot trials, the phytotoxic effects observed in germination tests due to radical differences in applied doses and exposure conditions. This highlights the importance of studies that consider field application and the need of green extraction methodologies that improve active substances concentration in extract.https://www.frontiersin.org/articles/10.3389/fagro.2025.1542124/fullphytotoxicityallelopathyinvasive speciessaponinsphenolicsnatural herbicides
spellingShingle Giacomo Trespidi
Valeria Xotta
Stefania Sut
Stefan Otto
Nebojša Nikolić
Elisa Strati
Sara Vitalini
Stefano Dall’Acqua
Marcello Iriti
Roberta Masin
Donato Loddo
Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
Frontiers in Agronomy
phytotoxicity
allelopathy
invasive species
saponins
phenolics
natural herbicides
title Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
title_full Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
title_fullStr Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
title_full_unstemmed Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
title_short Phytotoxic activity and chemical characterization of Baccharis halimifolia L. (Asteraceae) aqueous extracts
title_sort phytotoxic activity and chemical characterization of baccharis halimifolia l asteraceae aqueous extracts
topic phytotoxicity
allelopathy
invasive species
saponins
phenolics
natural herbicides
url https://www.frontiersin.org/articles/10.3389/fagro.2025.1542124/full
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