Recovery of molybdenum from simulated wastewater by arginine

The high-efficiency and environmentally friendly recycle for recovering molybdenum from molybdenum wastewater utilizing arginine was studied in this paper. The optimum experimental conditions were determined through single-factor experiment. When pH = 2.1, arginine dosage n (arginine) /n (Mo) = 1, t...

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Main Authors: Bu-Chan Zhou, Xiao-Jun Zheng, Wei-Jiang Chen, Qi Li, Zhi-Peng Lai, Miao-Miao Wang, Ming Chen
Format: Article
Language:English
Published: Elsevier 2024-01-01
Series:Desalination and Water Treatment
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Online Access:http://www.sciencedirect.com/science/article/pii/S1944398624000572
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author Bu-Chan Zhou
Xiao-Jun Zheng
Wei-Jiang Chen
Qi Li
Zhi-Peng Lai
Miao-Miao Wang
Ming Chen
author_facet Bu-Chan Zhou
Xiao-Jun Zheng
Wei-Jiang Chen
Qi Li
Zhi-Peng Lai
Miao-Miao Wang
Ming Chen
author_sort Bu-Chan Zhou
collection DOAJ
description The high-efficiency and environmentally friendly recycle for recovering molybdenum from molybdenum wastewater utilizing arginine was studied in this paper. The optimum experimental conditions were determined through single-factor experiment. When pH = 2.1, arginine dosage n (arginine) /n (Mo) = 1, the temperature was set at 25 ℃, the Mo concentration decreased from 19.19 g/L to 75.4 mg/L, and recovery ratio of Mo reached 99.61%. In the experiment of coexisting ions, the effects of Cl-, SO42-, CO32-, Na+, Ca2+, and Mg2+ on the recovery rate of Mo were relatively slight, but the inhibitory effects of PO43- and Fe3+ increased with their concentrations. Mo8O26−4, when combined with positively charged arginine, facilitated precipitation, and thereby achieving the goal of recovering molybdenum from molybdenum wastewater. The results showed that roasting the sediment at 600 ℃ for 2 h was a certain economic benefits method to obtain high purity of MoO3. This research provides a novel approach for the molybdenum wastewater recovery and treatment, boasting advantages such as improved recovery efficiency, reduced treatment costs, and simplified operation. It can be applied in the treatment and recovery of molybdenum wastewater and other industrial waste in the near future.
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spelling doaj-art-4331cafc366c4092b391f05c024b58b02025-08-20T02:01:14ZengElsevierDesalination and Water Treatment1944-39862024-01-0131710004310.1016/j.dwt.2024.100043Recovery of molybdenum from simulated wastewater by arginineBu-Chan Zhou0Xiao-Jun Zheng1Wei-Jiang Chen2Qi Li3Zhi-Peng Lai4Miao-Miao Wang5Ming Chen6Collaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, ChinaCollaborative Innovation Center for Development and Utilization of Rare Metal Resources Co-sponsored by Ministry of Education and Jiangxi Province, Ganzhou 341000, China; Jiangxi Province Key Laboratory of Mining and Metallurgy Environmental Pollution Control, Ganzhou 341000, China; College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China; Corresponding author at: College of Resources and Environment Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China.The high-efficiency and environmentally friendly recycle for recovering molybdenum from molybdenum wastewater utilizing arginine was studied in this paper. The optimum experimental conditions were determined through single-factor experiment. When pH = 2.1, arginine dosage n (arginine) /n (Mo) = 1, the temperature was set at 25 ℃, the Mo concentration decreased from 19.19 g/L to 75.4 mg/L, and recovery ratio of Mo reached 99.61%. In the experiment of coexisting ions, the effects of Cl-, SO42-, CO32-, Na+, Ca2+, and Mg2+ on the recovery rate of Mo were relatively slight, but the inhibitory effects of PO43- and Fe3+ increased with their concentrations. Mo8O26−4, when combined with positively charged arginine, facilitated precipitation, and thereby achieving the goal of recovering molybdenum from molybdenum wastewater. The results showed that roasting the sediment at 600 ℃ for 2 h was a certain economic benefits method to obtain high purity of MoO3. This research provides a novel approach for the molybdenum wastewater recovery and treatment, boasting advantages such as improved recovery efficiency, reduced treatment costs, and simplified operation. It can be applied in the treatment and recovery of molybdenum wastewater and other industrial waste in the near future.http://www.sciencedirect.com/science/article/pii/S1944398624000572MolybdenumArgininePrecipitationResource recoveryWastewater
spellingShingle Bu-Chan Zhou
Xiao-Jun Zheng
Wei-Jiang Chen
Qi Li
Zhi-Peng Lai
Miao-Miao Wang
Ming Chen
Recovery of molybdenum from simulated wastewater by arginine
Desalination and Water Treatment
Molybdenum
Arginine
Precipitation
Resource recovery
Wastewater
title Recovery of molybdenum from simulated wastewater by arginine
title_full Recovery of molybdenum from simulated wastewater by arginine
title_fullStr Recovery of molybdenum from simulated wastewater by arginine
title_full_unstemmed Recovery of molybdenum from simulated wastewater by arginine
title_short Recovery of molybdenum from simulated wastewater by arginine
title_sort recovery of molybdenum from simulated wastewater by arginine
topic Molybdenum
Arginine
Precipitation
Resource recovery
Wastewater
url http://www.sciencedirect.com/science/article/pii/S1944398624000572
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