Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns

Abstract Hydrologic regimes are affecting terrestrial carbon transformation, chemical weathering and lateral transport. However, its impacts on dissolved carbon export patterns remains elusive. In this study, we collected a 2‐year high‐frequency dissolved inorganic (DIC) and organic carbon (DOC) dat...

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Main Authors: Xiao Li, Jian Wang, Wei Yin, Jianfeng Xu, Haibing Xiao, Hongying Zhao, Yongyong Shi, Lei Wang, Rui Hao, Haiyan Li, Yiming Huang, Hai Jiang, Zhihua Shi
Format: Article
Language:English
Published: Wiley 2025-03-01
Series:Water Resources Research
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Online Access:https://doi.org/10.1029/2024WR038221
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author Xiao Li
Jian Wang
Wei Yin
Jianfeng Xu
Haibing Xiao
Hongying Zhao
Yongyong Shi
Lei Wang
Rui Hao
Haiyan Li
Yiming Huang
Hai Jiang
Zhihua Shi
author_facet Xiao Li
Jian Wang
Wei Yin
Jianfeng Xu
Haibing Xiao
Hongying Zhao
Yongyong Shi
Lei Wang
Rui Hao
Haiyan Li
Yiming Huang
Hai Jiang
Zhihua Shi
author_sort Xiao Li
collection DOAJ
description Abstract Hydrologic regimes are affecting terrestrial carbon transformation, chemical weathering and lateral transport. However, its impacts on dissolved carbon export patterns remains elusive. In this study, we collected a 2‐year high‐frequency dissolved inorganic (DIC) and organic carbon (DOC) dataset, namely a wet year (Rainfall = 1,158 mm) and a dry year (Rainfall = 603 mm). The results showed that drought led to a significant decrease in dissolved carbon concentration and discharge during the monitoring period. During non‐storm periods, DIC and DOC shifted from dilution and chemostatic to enrichment patterns from wet to dry years, respectively. However, the export patterns were reversed during storm periods. DIC and DOC export patterns in wet year were dominated by dilution and chemostatic, respectively, while both patterns were dominated by dilution in dry year. Structural equation models revealed that the aridity index and temperature may affect dissolved carbon export patterns. We further classified storm events into three major types and conceptualized catchment‐scale transport mechanisms for dissolved carbon. Dry‐AMCs events result in DIC dilution and DOC chemostatic behavior, whereas Wet‐AMCs events result in DIC chemostatic and DOC enrichment behavior due to increased hydrological connectivity. The third type corresponds to extreme events, where larger overland flow often results in DIC dilution but DOC enrichment behavior. These findings reveal the predominant role of drought in altering carbon lateral export by decreasing concentrations and fluxes and modifying export patterns.
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institution Kabale University
issn 0043-1397
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language English
publishDate 2025-03-01
publisher Wiley
record_format Article
series Water Resources Research
spelling doaj-art-431c83ef6a044cbb877b09b5149afcdb2025-08-20T03:30:57ZengWileyWater Resources Research0043-13971944-79732025-03-01613n/an/a10.1029/2024WR038221Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export PatternsXiao Li0Jian Wang1Wei Yin2Jianfeng Xu3Haibing Xiao4Hongying Zhao5Yongyong Shi6Lei Wang7Rui Hao8Haiyan Li9Yiming Huang10Hai Jiang11Zhihua Shi12State Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaChangjiang Water Resources Protection Institute Wuhan ChinaChangjiang Water Resources Protection Institute Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaSoil and Water Conservation Monitoring Centre Danjiangkou ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaSoil and Water Conservation Monitoring Centre Danjiangkou ChinaState Environmental Protection Key Laboratory of Soil Health and Green Remediation Huazhong Agricultural University Wuhan ChinaAbstract Hydrologic regimes are affecting terrestrial carbon transformation, chemical weathering and lateral transport. However, its impacts on dissolved carbon export patterns remains elusive. In this study, we collected a 2‐year high‐frequency dissolved inorganic (DIC) and organic carbon (DOC) dataset, namely a wet year (Rainfall = 1,158 mm) and a dry year (Rainfall = 603 mm). The results showed that drought led to a significant decrease in dissolved carbon concentration and discharge during the monitoring period. During non‐storm periods, DIC and DOC shifted from dilution and chemostatic to enrichment patterns from wet to dry years, respectively. However, the export patterns were reversed during storm periods. DIC and DOC export patterns in wet year were dominated by dilution and chemostatic, respectively, while both patterns were dominated by dilution in dry year. Structural equation models revealed that the aridity index and temperature may affect dissolved carbon export patterns. We further classified storm events into three major types and conceptualized catchment‐scale transport mechanisms for dissolved carbon. Dry‐AMCs events result in DIC dilution and DOC chemostatic behavior, whereas Wet‐AMCs events result in DIC chemostatic and DOC enrichment behavior due to increased hydrological connectivity. The third type corresponds to extreme events, where larger overland flow often results in DIC dilution but DOC enrichment behavior. These findings reveal the predominant role of drought in altering carbon lateral export by decreasing concentrations and fluxes and modifying export patterns.https://doi.org/10.1029/2024WR038221dissolved carbonhydrologic regimeexport patternsstorm eventdroughtclimate change
spellingShingle Xiao Li
Jian Wang
Wei Yin
Jianfeng Xu
Haibing Xiao
Hongying Zhao
Yongyong Shi
Lei Wang
Rui Hao
Haiyan Li
Yiming Huang
Hai Jiang
Zhihua Shi
Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
Water Resources Research
dissolved carbon
hydrologic regime
export patterns
storm event
drought
climate change
title Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
title_full Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
title_fullStr Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
title_full_unstemmed Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
title_short Hydrologic Regime Determines Catchment‐Scale Dissolved Carbon Export Patterns
title_sort hydrologic regime determines catchment scale dissolved carbon export patterns
topic dissolved carbon
hydrologic regime
export patterns
storm event
drought
climate change
url https://doi.org/10.1029/2024WR038221
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