Optochemical control of G1 cell cycle by regulating CDK4/6 degradation

Summary: Cancer progression is characterized by dysregulated G1/S phase transition mediated by CDK4/6-dependent Rb protein phosphorylation. Although CDK4/6 degraders show encouraging anti-tumor efficacy, it is highly desired to develop strategies to spatiotemporally control the release of active CDK...

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Main Authors: Tianyi Wang, Yaming Zhang, Yuwei Liu, Lichao Wang, Lijun Liu, Weiping Wang
Format: Article
Language:English
Published: Elsevier 2025-09-01
Series:iScience
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Online Access:http://www.sciencedirect.com/science/article/pii/S2589004225015652
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author Tianyi Wang
Yaming Zhang
Yuwei Liu
Lichao Wang
Lijun Liu
Weiping Wang
author_facet Tianyi Wang
Yaming Zhang
Yuwei Liu
Lichao Wang
Lijun Liu
Weiping Wang
author_sort Tianyi Wang
collection DOAJ
description Summary: Cancer progression is characterized by dysregulated G1/S phase transition mediated by CDK4/6-dependent Rb protein phosphorylation. Although CDK4/6 degraders show encouraging anti-tumor efficacy, it is highly desired to develop strategies to spatiotemporally control the release of active CDK4/6 degraders to further reduce adverse effects. In this study, we employ an optochemical strategy for CDK4/6 degradation by caging the CRBN ligand with a photoremovable protecting group. Light irradiation at 365 nm triggers photocleavage, thereby inducing CDK4/6 degradation via the ubiquitin-proteasome system. The resultant G1-phase arrest demonstrates spatial and temporal control over cell-cycle progression, reducing off-target effects of current therapies. This light-controlled system allows spatiotemporal CDK4/6 degradation and G1 cell-cycle arrest, providing a promising strategy to enhance specificity for cancer treatment and fundamental biological research.
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institution Kabale University
issn 2589-0042
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publishDate 2025-09-01
publisher Elsevier
record_format Article
series iScience
spelling doaj-art-427fc4602ade43bc9216347b97c7f2832025-08-23T04:48:54ZengElsevieriScience2589-00422025-09-0128911330410.1016/j.isci.2025.113304Optochemical control of G1 cell cycle by regulating CDK4/6 degradationTianyi Wang0Yaming Zhang1Yuwei Liu2Lichao Wang3Lijun Liu4Weiping Wang5Department of Nasopharyngeal Carcinoma, Sun Yat-sen University Cancer Center, State Key Laboratory of Oncology in South China, Collaborative Innovation Center for Cancer Medicine, Guangdong Key Laboratory of Nasopharyngeal Carcinoma Diagnosis and Therapy, Guangdong Provincial Clinical Research Center for Cancer, Guangzhou 510060, China; State Key Laboratory of Pharmaceutical Biotechnology, The University of Hong Kong, Hong Kong, China; Department of Pharmacology and Pharmacy, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong, China; Dr. Li Dak-Sum Research Centre, The University of Hong Kong, Hong Kong, ChinaState Key Laboratory of Pharmaceutical Biotechnology, The University of Hong Kong, Hong Kong, China; Department of Pharmacology and Pharmacy, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong, China; Dr. Li Dak-Sum Research Centre, The University of Hong Kong, Hong Kong, ChinaState Key Laboratory of Pharmaceutical Biotechnology, The University of Hong Kong, Hong Kong, China; Department of Pharmacology and Pharmacy, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong, China; Dr. Li Dak-Sum Research Centre, The University of Hong Kong, Hong Kong, ChinaNational Frontiers Science Center for Industrial Intelligence and Systems Optimization, Key Laboratory of Bioresource Research and Development of Liaoning Province, College of Life and Health Sciences, Northeastern University, Shenyang 110819, ChinaNational Frontiers Science Center for Industrial Intelligence and Systems Optimization, Key Laboratory of Bioresource Research and Development of Liaoning Province, College of Life and Health Sciences, Northeastern University, Shenyang 110819, ChinaState Key Laboratory of Pharmaceutical Biotechnology, The University of Hong Kong, Hong Kong, China; Department of Pharmacology and Pharmacy, Li Ka Shing Faculty of Medicine, The University of Hong Kong, Hong Kong, China; Dr. Li Dak-Sum Research Centre, The University of Hong Kong, Hong Kong, China; Corresponding authorSummary: Cancer progression is characterized by dysregulated G1/S phase transition mediated by CDK4/6-dependent Rb protein phosphorylation. Although CDK4/6 degraders show encouraging anti-tumor efficacy, it is highly desired to develop strategies to spatiotemporally control the release of active CDK4/6 degraders to further reduce adverse effects. In this study, we employ an optochemical strategy for CDK4/6 degradation by caging the CRBN ligand with a photoremovable protecting group. Light irradiation at 365 nm triggers photocleavage, thereby inducing CDK4/6 degradation via the ubiquitin-proteasome system. The resultant G1-phase arrest demonstrates spatial and temporal control over cell-cycle progression, reducing off-target effects of current therapies. This light-controlled system allows spatiotemporal CDK4/6 degradation and G1 cell-cycle arrest, providing a promising strategy to enhance specificity for cancer treatment and fundamental biological research.http://www.sciencedirect.com/science/article/pii/S2589004225015652BiochemistryCell biologyCancer
spellingShingle Tianyi Wang
Yaming Zhang
Yuwei Liu
Lichao Wang
Lijun Liu
Weiping Wang
Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
iScience
Biochemistry
Cell biology
Cancer
title Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
title_full Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
title_fullStr Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
title_full_unstemmed Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
title_short Optochemical control of G1 cell cycle by regulating CDK4/6 degradation
title_sort optochemical control of g1 cell cycle by regulating cdk4 6 degradation
topic Biochemistry
Cell biology
Cancer
url http://www.sciencedirect.com/science/article/pii/S2589004225015652
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AT lichaowang optochemicalcontrolofg1cellcyclebyregulatingcdk46degradation
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