Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion
Three materials of perovskite structure, CaMn1−xMxO3−δ (M = Mg or Mg and Ti), have been examined as oxygen carriers in continuous operation of chemical-looping combustion (CLC) in a circulating fluidized bed system with the designed fuel power 300 W. Natural gas was used as fuel. All three materials...
Saved in:
| Main Authors: | , , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2014-01-01
|
| Series: | International Journal of Chemical Engineering |
| Online Access: | http://dx.doi.org/10.1155/2014/412517 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832559270587006976 |
|---|---|
| author | Peter Hallberg Malin Källén Dazheng Jing Frans Snijkers Jasper van Noyen Magnus Rydén Anders Lyngfelt |
| author_facet | Peter Hallberg Malin Källén Dazheng Jing Frans Snijkers Jasper van Noyen Magnus Rydén Anders Lyngfelt |
| author_sort | Peter Hallberg |
| collection | DOAJ |
| description | Three materials of perovskite structure, CaMn1−xMxO3−δ (M = Mg or Mg and Ti), have been examined as oxygen carriers in continuous operation of chemical-looping combustion (CLC) in a circulating fluidized bed system with the designed fuel power 300 W. Natural gas was used as fuel. All three materials were capable of completely converting the fuel to carbon dioxide and water at 900°C. All materials also showed the ability to release gas phase oxygen when fluidized by inert gas at elevated temperature (700–950°C); that is, they were suitable for chemical looping with oxygen uncoupling (CLOU). Both fuel conversion and oxygen release improved with temperature. All three materials also showed good mechanical integrity, as the fraction of fines collected during experiments was small. These results indicate that the materials are promising oxygen carriers for chemical-looping combustion. |
| format | Article |
| id | doaj-art-42520391164744b1a4963aa75d463f88 |
| institution | Kabale University |
| issn | 1687-806X 1687-8078 |
| language | English |
| publishDate | 2014-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Chemical Engineering |
| spelling | doaj-art-42520391164744b1a4963aa75d463f882025-02-03T01:30:29ZengWileyInternational Journal of Chemical Engineering1687-806X1687-80782014-01-01201410.1155/2014/412517412517Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping CombustionPeter Hallberg0Malin Källén1Dazheng Jing2Frans Snijkers3Jasper van Noyen4Magnus Rydén5Anders Lyngfelt6Department of Energy and Environment, Chalmers University of Technology, 412 96 Gothenburg, SwedenDepartment of Energy and Environment, Chalmers University of Technology, 412 96 Gothenburg, SwedenDepartment of Inorganic Environmental Chemistry, Chalmers University of Technology, 412 96 Gothenburg, SwedenFlemish Institute for Technological Research (VITO), 2400 Mol, BelgiumFlemish Institute for Technological Research (VITO), 2400 Mol, BelgiumDepartment of Energy and Environment, Chalmers University of Technology, 412 96 Gothenburg, SwedenDepartment of Energy and Environment, Chalmers University of Technology, 412 96 Gothenburg, SwedenThree materials of perovskite structure, CaMn1−xMxO3−δ (M = Mg or Mg and Ti), have been examined as oxygen carriers in continuous operation of chemical-looping combustion (CLC) in a circulating fluidized bed system with the designed fuel power 300 W. Natural gas was used as fuel. All three materials were capable of completely converting the fuel to carbon dioxide and water at 900°C. All materials also showed the ability to release gas phase oxygen when fluidized by inert gas at elevated temperature (700–950°C); that is, they were suitable for chemical looping with oxygen uncoupling (CLOU). Both fuel conversion and oxygen release improved with temperature. All three materials also showed good mechanical integrity, as the fraction of fines collected during experiments was small. These results indicate that the materials are promising oxygen carriers for chemical-looping combustion.http://dx.doi.org/10.1155/2014/412517 |
| spellingShingle | Peter Hallberg Malin Källén Dazheng Jing Frans Snijkers Jasper van Noyen Magnus Rydén Anders Lyngfelt Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion International Journal of Chemical Engineering |
| title | Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion |
| title_full | Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion |
| title_fullStr | Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion |
| title_full_unstemmed | Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion |
| title_short | Experimental Investigation of CaMnO3−δ Based Oxygen Carriers Used in Continuous Chemical-Looping Combustion |
| title_sort | experimental investigation of camno3 δ based oxygen carriers used in continuous chemical looping combustion |
| url | http://dx.doi.org/10.1155/2014/412517 |
| work_keys_str_mv | AT peterhallberg experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT malinkallen experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT dazhengjing experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT franssnijkers experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT jaspervannoyen experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT magnusryden experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion AT anderslyngfelt experimentalinvestigationofcamno3dbasedoxygencarriersusedincontinuouschemicalloopingcombustion |