Squaraine Dyes for Organic Photomultiplication Photodetectors with 220% External Quantum Efficiency at 1240 nm
Abstract Near‐infrared (NIR) light detection at wavelengths λ > 1100 nm is essential in modern science and technology. Emerging organic semiconductors are promising for solution‐processed, flexible, and large‐area NIR organic photodetectors (OPDs), but only a few organic chromophores with peak ab...
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| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2025-07-01
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| Series: | Advanced Science |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/advs.202502320 |
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| Summary: | Abstract Near‐infrared (NIR) light detection at wavelengths λ > 1100 nm is essential in modern science and technology. Emerging organic semiconductors are promising for solution‐processed, flexible, and large‐area NIR organic photodetectors (OPDs), but only a few organic chromophores with peak absorption beyond the silicon bandgap are available. Furthermore, the external quantum efficiency (EQE) and specific detectivity (D*) of NIR OPDs are restricted by insufficient exciton dissociation and high dark/noise current. Here, the combination of strong electron‐accepting and ‐donating groups is used to synthesize a selection of novel NIR squaraine dyes with superior redshifted absorptions, peaking at 1165 nm in solution and extending to 1240 nm in a blend film. To overcome the tradeoff between long wavelength absorption and high photoresponse, NIR photons are detected utilizing a gain OPD design, where photomultiplication occurs via squaraine hole trap‐induced injection of external charges. The OPD can achieve an EQE of 220% at 1240 nm and still maintains 25% in the absorption tail at 1400 nm, thereby surpassing existing NIR OPDs in a broad wavelength range beyond 1100 nm. The measured maximum D* equals 109 Jones at 1240 nm, and the detectivity estimated from the shot noise is ≈1011 Jones, independent of the bias voltage. |
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| ISSN: | 2198-3844 |