Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating

Enhancing the anti-friction and anti-wear and corrosion resistant properties of mold copper plates holds significant research significance and value for the development and improvement of continuous casting molds.In this study, a Ni-Co/Al2O3&#x00A0;nanocomposite coating was electrodeposited on t...

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Main Author: WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
Format: Article
Language:zho
Published: Editorial Department of Materials Protection 2025-04-01
Series:Cailiao Baohu
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Online Access:http://www.mat-pro.com/fileup/1001-1560/PDF/20250408.pdf
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author WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
author_facet WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
author_sort WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
collection DOAJ
description Enhancing the anti-friction and anti-wear and corrosion resistant properties of mold copper plates holds significant research significance and value for the development and improvement of continuous casting molds.In this study, a Ni-Co/Al2O3&#x00A0;nanocomposite coating was electrodeposited on the surface of a Cu-Cr-Zr alloy substrate with the assistance of ultrasonic during the electroplating process, and the plating bath was formulated by incorporating nano-Al2O3&#x00A0;particles with an average diameter of 20 nm into a sulfamate-based electrolyte system.Subsequently, the composite coating was systematically characterized through friction and wear testing, high-temperature oxidation evaluation,microhardness measurement, adhesion assessment, and corrosion resistance analysis.Results showed that the optimal process parameters were current density of 5 A/dm2, bath temperature of 50 ℃, nano-Al2O3&#x00A0;concentration of 10 g/L, deposition time of 1.00 h, ultrasonic power of 200 W, and mechanical stirring at 500 r/min.Under this process,the Ni-Co/Al2O3&#x00A0;nanocomposite coating exhibited the highest surface microhardness, the finest and most compact structure arrangement, the uniformly dispersed nanoparticles embedded in the metal matrix without obvious agglomeration, and the optimal microscopic morphology.Moreover, the Ni-Co/Al2O3&#x00A0;nanocomposite coating prepared with ultrasonic assistance had excellent high-temperature oxidation resistance at 400 ℃; Compared with Cu-Cr-Zr alloy and Ni-Co alloy coatings, Ni-Co/Al2O3&#x00A0;nanocomposite coating possessed the best anti-friction and anti-wear performance and corrosion resistance
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publisher Editorial Department of Materials Protection
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spelling doaj-art-41f066ce0c1d481e8f2567d426ecf8422025-08-20T03:08:52ZzhoEditorial Department of Materials ProtectionCailiao Baohu1001-15602025-04-01584788910.16577/j.issn.1001-1560.2025.0062Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite CoatingWANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng0(School of Materials and Metallurgy, Liaoning University of Science and Technology, Anshan 114051, China) Enhancing the anti-friction and anti-wear and corrosion resistant properties of mold copper plates holds significant research significance and value for the development and improvement of continuous casting molds.In this study, a Ni-Co/Al2O3&#x00A0;nanocomposite coating was electrodeposited on the surface of a Cu-Cr-Zr alloy substrate with the assistance of ultrasonic during the electroplating process, and the plating bath was formulated by incorporating nano-Al2O3&#x00A0;particles with an average diameter of 20 nm into a sulfamate-based electrolyte system.Subsequently, the composite coating was systematically characterized through friction and wear testing, high-temperature oxidation evaluation,microhardness measurement, adhesion assessment, and corrosion resistance analysis.Results showed that the optimal process parameters were current density of 5 A/dm2, bath temperature of 50 ℃, nano-Al2O3&#x00A0;concentration of 10 g/L, deposition time of 1.00 h, ultrasonic power of 200 W, and mechanical stirring at 500 r/min.Under this process,the Ni-Co/Al2O3&#x00A0;nanocomposite coating exhibited the highest surface microhardness, the finest and most compact structure arrangement, the uniformly dispersed nanoparticles embedded in the metal matrix without obvious agglomeration, and the optimal microscopic morphology.Moreover, the Ni-Co/Al2O3&#x00A0;nanocomposite coating prepared with ultrasonic assistance had excellent high-temperature oxidation resistance at 400 ℃; Compared with Cu-Cr-Zr alloy and Ni-Co alloy coatings, Ni-Co/Al2O3&#x00A0;nanocomposite coating possessed the best anti-friction and anti-wear performance and corrosion resistancehttp://www.mat-pro.com/fileup/1001-1560/PDF/20250408.pdfcu-cr-zr; ni-co/al<sub>2</sub>o<sub>3</sub> nanocomposite coating; microhardness; corrosion resistance; anti friction and wear performance
spellingShingle WANG Hongyu, WANG Yiyong, WANG Lubin, LIANG Zhipeng
Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
Cailiao Baohu
cu-cr-zr; ni-co/al<sub>2</sub>o<sub>3</sub> nanocomposite coating; microhardness; corrosion resistance; anti friction and wear performance
title Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
title_full Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
title_fullStr Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
title_full_unstemmed Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
title_short Study on the Microstructure and Properties of Al<sub>2</sub>O<sub>3</sub> Reinforced Ni-Co Based Composite Coating
title_sort study on the microstructure and properties of al sub 2 sub o sub 3 sub reinforced ni co based composite coating
topic cu-cr-zr; ni-co/al<sub>2</sub>o<sub>3</sub> nanocomposite coating; microhardness; corrosion resistance; anti friction and wear performance
url http://www.mat-pro.com/fileup/1001-1560/PDF/20250408.pdf
work_keys_str_mv AT wanghongyuwangyiyongwanglubinliangzhipeng studyonthemicrostructureandpropertiesofalsub2subosub3subreinforcednicobasedcompositecoating