Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
Rice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to...
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2024-10-01
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Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/20175 |
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author | Thu Huong Nguyen Tuan Cuong Vu Trung Phong Le Thu Huyen Nguyen Xuan Truong Do Anh-Tuan Vu |
author_facet | Thu Huong Nguyen Tuan Cuong Vu Trung Phong Le Thu Huyen Nguyen Xuan Truong Do Anh-Tuan Vu |
author_sort | Thu Huong Nguyen |
collection | DOAJ |
description | Rice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to prepare the ZnO•SiO2 nanocomposites by a hydrothermal method. The as-synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and N2 adsorption/desorption isotherm. Their photocatalytic properties were studied by an ultraviolet-vis spectrophotometer and a fluorescence spectrophotometer. The ZnO•SiO2 nanocomposite has an excellent ability to degrade organic substances such as dyes, antibiotics, caffeine, etc. The effects of operating parameters on the photo-degradation reaction progress, including catalyst dosage, initial dye concentration, and pH of the initial dye were investigated in detail. In addition, the photodegradation rate of the dye on the ZnO•SiO2 nanocomposite was evaluated using the pseudo-first-order model. The ZnO•SiO2 nanocomposite can be used as a photocatalyst for wastewater treatment as it detaches much more easily from the solution. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
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id | doaj-art-407a3f6f1c97423d8b9ae234d419bff7 |
institution | Kabale University |
issn | 1978-2993 |
language | English |
publishDate | 2024-10-01 |
publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
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series | Bulletin of Chemical Reaction Engineering & Catalysis |
spelling | doaj-art-407a3f6f1c97423d8b9ae234d419bff72025-02-02T02:54:11ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932024-10-0119342944110.9767/bcrec.201758461Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible LightThu Huong Nguyen0Tuan Cuong Vu1Trung Phong Le2Thu Huyen Nguyen3Xuan Truong Do4Anh-Tuan Vu5https://orcid.org/0000-0002-5546-4422School of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamSchool of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamSchool of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamRice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to prepare the ZnO•SiO2 nanocomposites by a hydrothermal method. The as-synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and N2 adsorption/desorption isotherm. Their photocatalytic properties were studied by an ultraviolet-vis spectrophotometer and a fluorescence spectrophotometer. The ZnO•SiO2 nanocomposite has an excellent ability to degrade organic substances such as dyes, antibiotics, caffeine, etc. The effects of operating parameters on the photo-degradation reaction progress, including catalyst dosage, initial dye concentration, and pH of the initial dye were investigated in detail. In addition, the photodegradation rate of the dye on the ZnO•SiO2 nanocomposite was evaluated using the pseudo-first-order model. The ZnO•SiO2 nanocomposite can be used as a photocatalyst for wastewater treatment as it detaches much more easily from the solution. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20175photodegradationzinc oxideamorphous silicarice huskjanus green b. |
spellingShingle | Thu Huong Nguyen Tuan Cuong Vu Trung Phong Le Thu Huyen Nguyen Xuan Truong Do Anh-Tuan Vu Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light Bulletin of Chemical Reaction Engineering & Catalysis photodegradation zinc oxide amorphous silica rice husk janus green b. |
title | Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light |
title_full | Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light |
title_fullStr | Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light |
title_full_unstemmed | Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light |
title_short | Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light |
title_sort | synthesis of mesoporous zno•sio2 nanocomposite from rice husk for enhanced degradation of organic substances including janus green b under visible light |
topic | photodegradation zinc oxide amorphous silica rice husk janus green b. |
url | https://journal.bcrec.id/index.php/bcrec/article/view/20175 |
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