Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light

Rice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to...

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Main Authors: Thu Huong Nguyen, Tuan Cuong Vu, Trung Phong Le, Thu Huyen Nguyen, Xuan Truong Do, Anh-Tuan Vu
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2024-10-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
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Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/20175
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author Thu Huong Nguyen
Tuan Cuong Vu
Trung Phong Le
Thu Huyen Nguyen
Xuan Truong Do
Anh-Tuan Vu
author_facet Thu Huong Nguyen
Tuan Cuong Vu
Trung Phong Le
Thu Huyen Nguyen
Xuan Truong Do
Anh-Tuan Vu
author_sort Thu Huong Nguyen
collection DOAJ
description Rice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to prepare the ZnO•SiO2 nanocomposites by a hydrothermal method. The as-synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and N2 adsorption/desorption isotherm. Their photocatalytic properties were studied by an ultraviolet-vis spectrophotometer and a fluorescence spectrophotometer. The ZnO•SiO2 nanocomposite has an excellent ability to degrade organic substances such as dyes, antibiotics, caffeine, etc. The effects of operating parameters on the photo-degradation reaction progress, including catalyst dosage, initial dye concentration, and pH of the initial dye were investigated in detail. In addition, the photodegradation rate of the dye on the ZnO•SiO2 nanocomposite was evaluated using the pseudo-first-order model. The ZnO•SiO2 nanocomposite can be used as a photocatalyst for wastewater treatment as it detaches much more easily from the solution. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).
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spelling doaj-art-407a3f6f1c97423d8b9ae234d419bff72025-02-02T02:54:11ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932024-10-0119342944110.9767/bcrec.201758461Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible LightThu Huong Nguyen0Tuan Cuong Vu1Trung Phong Le2Thu Huyen Nguyen3Xuan Truong Do4Anh-Tuan Vu5https://orcid.org/0000-0002-5546-4422School of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamNguyen Gia Thieu High School, Hanoi, Viet NamSchool of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamSchool of Chemistry and Life Sciences, Hanoi University of Science and Technology, Hanoi, Viet NamRice husk (RH) is often mentioned as an agricultural by-product, often used in the pass as fertilizer and for raw burning. With modern science, RH have been researched and found many new potential benefits and applications. In this study, RH were used to synthesize amorphous SiO2, which was used to prepare the ZnO•SiO2 nanocomposites by a hydrothermal method. The as-synthesized materials were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FT-IR), and N2 adsorption/desorption isotherm. Their photocatalytic properties were studied by an ultraviolet-vis spectrophotometer and a fluorescence spectrophotometer. The ZnO•SiO2 nanocomposite has an excellent ability to degrade organic substances such as dyes, antibiotics, caffeine, etc. The effects of operating parameters on the photo-degradation reaction progress, including catalyst dosage, initial dye concentration, and pH of the initial dye were investigated in detail. In addition, the photodegradation rate of the dye on the ZnO•SiO2 nanocomposite was evaluated using the pseudo-first-order model. The ZnO•SiO2 nanocomposite can be used as a photocatalyst for wastewater treatment as it detaches much more easily from the solution. Copyright © 2024 by Authors, Published by BCREC Publishing Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/20175photodegradationzinc oxideamorphous silicarice huskjanus green b.
spellingShingle Thu Huong Nguyen
Tuan Cuong Vu
Trung Phong Le
Thu Huyen Nguyen
Xuan Truong Do
Anh-Tuan Vu
Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
Bulletin of Chemical Reaction Engineering & Catalysis
photodegradation
zinc oxide
amorphous silica
rice husk
janus green b.
title Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
title_full Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
title_fullStr Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
title_full_unstemmed Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
title_short Synthesis of Mesoporous ZnO•SiO2 Nanocomposite from Rice Husk for Enhanced Degradation of Organic Substances Including Janus Green B under Visible Light
title_sort synthesis of mesoporous zno•sio2 nanocomposite from rice husk for enhanced degradation of organic substances including janus green b under visible light
topic photodegradation
zinc oxide
amorphous silica
rice husk
janus green b.
url https://journal.bcrec.id/index.php/bcrec/article/view/20175
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