ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC

The determination of cypermethrin, one of the most sought pyrethroid insecticides having a wide range of activities, by isocratic RP-HPLC is considered. The analysis of substances (technical products) with different content of both the geometrical (cis-, trans-) and optical (zetacypermethrin and alf...

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Main Authors: L. A. Nosikova, A. N. Kochetov
Format: Article
Language:Russian
Published: MIREA - Russian Technological University 2017-02-01
Series:Тонкие химические технологии
Subjects:
Online Access:https://www.finechem-mirea.ru/jour/article/view/76
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author L. A. Nosikova
A. N. Kochetov
author_facet L. A. Nosikova
A. N. Kochetov
author_sort L. A. Nosikova
collection DOAJ
description The determination of cypermethrin, one of the most sought pyrethroid insecticides having a wide range of activities, by isocratic RP-HPLC is considered. The analysis of substances (technical products) with different content of both the geometrical (cis-, trans-) and optical (zetacypermethrin and alfacypermethrin) isomers of cypermethrin was carried out. Information about the content of the most active forms of cis- allows evaluating the effectiveness of the biological substance based only on RP-HPLC data, which in turn can be a decisive factor in the of the substance assessment supplier / manufacturer or ready commercial products. The optimum concentration range for determining the geometric isomers of cypermethrin in the working solution is from 0.2 to 1.0 mg/ml. The substance detection limit in working solutions/washings is 0.005 mg/ml.
format Article
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institution Kabale University
issn 2410-6593
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language Russian
publishDate 2017-02-01
publisher MIREA - Russian Technological University
record_format Article
series Тонкие химические технологии
spelling doaj-art-406a840525404e36b85d2e04459f42ae2025-08-20T03:56:33ZrusMIREA - Russian Technological UniversityТонкие химические технологии2410-65932686-75752017-02-01121768210.32362/2410-6593-2017-12-1-76-8276ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLCL. A. Nosikova0A. N. Kochetov1Moscow Technological University (Institute of Fine Chemical Technologies)CJCS «METTEM-Technology»The determination of cypermethrin, one of the most sought pyrethroid insecticides having a wide range of activities, by isocratic RP-HPLC is considered. The analysis of substances (technical products) with different content of both the geometrical (cis-, trans-) and optical (zetacypermethrin and alfacypermethrin) isomers of cypermethrin was carried out. Information about the content of the most active forms of cis- allows evaluating the effectiveness of the biological substance based only on RP-HPLC data, which in turn can be a decisive factor in the of the substance assessment supplier / manufacturer or ready commercial products. The optimum concentration range for determining the geometric isomers of cypermethrin in the working solution is from 0.2 to 1.0 mg/ml. The substance detection limit in working solutions/washings is 0.005 mg/ml.https://www.finechem-mirea.ru/jour/article/view/76«pest control» insecticidscis-uvcypermethrinzeta-cypermethrinalpha-cypermethrindeterminationtrans-isomersrp-hplc«pest control»
spellingShingle L. A. Nosikova
A. N. Kochetov
ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
Тонкие химические технологии
«pest control» insecticids
cis-
uv
cypermethrin
zeta-cypermethrin
alpha-cypermethrin
determination
trans-isomers
rp-hplc
«pest control»
title ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
title_full ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
title_fullStr ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
title_full_unstemmed ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
title_short ESTABLISHMENT OF ISOMERIC COMPOSITION OF INSECTICIDAL CYPERMETHRIN SUBSTANCE BY RP-HPLC
title_sort establishment of isomeric composition of insecticidal cypermethrin substance by rp hplc
topic «pest control» insecticids
cis-
uv
cypermethrin
zeta-cypermethrin
alpha-cypermethrin
determination
trans-isomers
rp-hplc
«pest control»
url https://www.finechem-mirea.ru/jour/article/view/76
work_keys_str_mv AT lanosikova establishmentofisomericcompositionofinsecticidalcypermethrinsubstancebyrphplc
AT ankochetov establishmentofisomericcompositionofinsecticidalcypermethrinsubstancebyrphplc