Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery

Enhancing oil recovery efficiency is vital in the energy industry. This study investigates magnesium oxide (MgO) nanoparticles combined with sodium dodecyl sulfate (SDS) surfactants to reduce interfacial tension (IFT) and improve oil recovery. Pendant drop method measurements revealed a 70% IFT redu...

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Main Authors: Youssef E. Kandiel, Gamal Attia, Farouk Metwalli, Rafik Khalaf, Omar Mahmoud
Format: Article
Language:English
Published: MDPI AG 2025-01-01
Series:Energies
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Online Access:https://www.mdpi.com/1996-1073/18/2/249
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author Youssef E. Kandiel
Gamal Attia
Farouk Metwalli
Rafik Khalaf
Omar Mahmoud
author_facet Youssef E. Kandiel
Gamal Attia
Farouk Metwalli
Rafik Khalaf
Omar Mahmoud
author_sort Youssef E. Kandiel
collection DOAJ
description Enhancing oil recovery efficiency is vital in the energy industry. This study investigates magnesium oxide (MgO) nanoparticles combined with sodium dodecyl sulfate (SDS) surfactants to reduce interfacial tension (IFT) and improve oil recovery. Pendant drop method measurements revealed a 70% IFT reduction, significantly improving nanoparticle dispersion stability due to SDS. Alterations in Zeta Potential and viscosity, indicating enhanced colloidal stability under reservoir conditions, were key findings. These results suggest that the MgO-SDS system offers a promising and sustainable alternative to conventional methods, although challenges such as scaling up and managing nanoparticle–surfactant dynamics remain. The preparation of MgO nanofluids involved magnetic stirring and ultrasonic homogenization to ensure thorough mixing. Characterization techniques included density, viscosity, pH, Zeta Potential, electric conductivity, and electrophoretic mobility assessments for the nanofluid and surfactant–nanofluid systems. Paraffin oil was used as the oil phase, with MgO nanoparticle concentrations ranging from 0.01 to 0.5 wt% and a constant SDS concentration of 0.5 wt%. IFT reduction was significant, from 47.9 to 26.9 mN/m with 0.1 wt% MgO nanofluid. Even 0.01 wt% MgO nanoparticles reduced the IFT to 41.8 mN/m. Combining MgO nanoparticles with SDS achieved up to 70% IFT reduction, enhancing oil mobility. Changes in Zeta Potential (from −2.54 to 3.45 mV) and pH (from 8.4 to 10.8) indicated improved MgO nanoparticle dispersion and stability, further boosting oil displacement efficiency under experimental conditions. The MgO-SDS system shows promise as a cleaner, cost-effective Enhanced Oil Recovery (EOR) method. However, challenges such as nanoparticle stability under diverse conditions, surfactant adsorption management, and scaling up require further research, emphasizing interdisciplinary approaches and rigorous field studies.
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spelling doaj-art-40668c4d7bb241e8b985c6b0c84632c92025-01-24T13:30:46ZengMDPI AGEnergies1996-10732025-01-0118224910.3390/en18020249Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil RecoveryYoussef E. Kandiel0Gamal Attia1Farouk Metwalli2Rafik Khalaf3Omar Mahmoud4Department of Petroleum Engineering, Faculty of Engineering and Technology, Future University in Egypt (FUE), Cairo 11835, EgyptDepartment of Geology, Faculty of Science, Helwan University, Cairo 11795, EgyptDepartment of Geology, Faculty of Science, Helwan University, Cairo 11795, EgyptDepartment of Geology, Faculty of Science, Helwan University, Cairo 11795, EgyptDepartment of Petroleum Engineering, Faculty of Engineering and Technology, Future University in Egypt (FUE), Cairo 11835, EgyptEnhancing oil recovery efficiency is vital in the energy industry. This study investigates magnesium oxide (MgO) nanoparticles combined with sodium dodecyl sulfate (SDS) surfactants to reduce interfacial tension (IFT) and improve oil recovery. Pendant drop method measurements revealed a 70% IFT reduction, significantly improving nanoparticle dispersion stability due to SDS. Alterations in Zeta Potential and viscosity, indicating enhanced colloidal stability under reservoir conditions, were key findings. These results suggest that the MgO-SDS system offers a promising and sustainable alternative to conventional methods, although challenges such as scaling up and managing nanoparticle–surfactant dynamics remain. The preparation of MgO nanofluids involved magnetic stirring and ultrasonic homogenization to ensure thorough mixing. Characterization techniques included density, viscosity, pH, Zeta Potential, electric conductivity, and electrophoretic mobility assessments for the nanofluid and surfactant–nanofluid systems. Paraffin oil was used as the oil phase, with MgO nanoparticle concentrations ranging from 0.01 to 0.5 wt% and a constant SDS concentration of 0.5 wt%. IFT reduction was significant, from 47.9 to 26.9 mN/m with 0.1 wt% MgO nanofluid. Even 0.01 wt% MgO nanoparticles reduced the IFT to 41.8 mN/m. Combining MgO nanoparticles with SDS achieved up to 70% IFT reduction, enhancing oil mobility. Changes in Zeta Potential (from −2.54 to 3.45 mV) and pH (from 8.4 to 10.8) indicated improved MgO nanoparticle dispersion and stability, further boosting oil displacement efficiency under experimental conditions. The MgO-SDS system shows promise as a cleaner, cost-effective Enhanced Oil Recovery (EOR) method. However, challenges such as nanoparticle stability under diverse conditions, surfactant adsorption management, and scaling up require further research, emphasizing interdisciplinary approaches and rigorous field studies.https://www.mdpi.com/1996-1073/18/2/249MgO nanoparticlesinterfacial tension reductionenhanced oil recoverysustainable nanotechnology
spellingShingle Youssef E. Kandiel
Gamal Attia
Farouk Metwalli
Rafik Khalaf
Omar Mahmoud
Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
Energies
MgO nanoparticles
interfacial tension reduction
enhanced oil recovery
sustainable nanotechnology
title Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
title_full Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
title_fullStr Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
title_full_unstemmed Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
title_short Innovative Role of Magnesium Oxide Nanoparticles and Surfactant in Optimizing Interfacial Tension for Enhanced Oil Recovery
title_sort innovative role of magnesium oxide nanoparticles and surfactant in optimizing interfacial tension for enhanced oil recovery
topic MgO nanoparticles
interfacial tension reduction
enhanced oil recovery
sustainable nanotechnology
url https://www.mdpi.com/1996-1073/18/2/249
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