Spiky Nickel Electrodes for Electrochemical Oxygen Evolution Catalysis by Femtosecond Laser Structuring

Micro- and nanostructured Ni/NiO surfaces were generated by femtosecond laser structuring for oxygen evolution reaction in alkaline water electrolysis cells. For two different angles between the laser beam and the nickel surface, two different types of laser-structured electrodes were prepared, char...

Full description

Saved in:
Bibliographic Details
Main Authors: Felix Rieck genannt Best, Jürgen Koch, Gerhard Lilienkamp, Franz Körkemeyer, Hans Jürgen Maier, Jürgen Caro, Karsten Lange
Format: Article
Language:English
Published: Wiley 2018-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.1155/2018/9875438
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Micro- and nanostructured Ni/NiO surfaces were generated by femtosecond laser structuring for oxygen evolution reaction in alkaline water electrolysis cells. For two different angles between the laser beam and the nickel surface, two different types of laser-structured electrodes were prepared, characterized, and compared with a plane tempered nickel electrode. Their electrochemical activities for the oxygen evolution reaction were tested by using cyclic and linear sweep voltammetry. The chemical surface composition was investigated by X-ray photoelectron spectroscopy. Laser structuring increased the overall electrochemical performance by more than one order of magnitude. The overpotential of the laser-structured electrodes for the oxygen evolution reaction was decreased by more than 100 mV due to high defect densities of the structures created by the laser ablation process.
ISSN:2090-3529
2090-3537