Quantum properties of proton subsystem in proton semiconductors

The quantum mechanism of the relaxation motion of the most mobile charge carriers (protons) in crystals with hydrogen bonds (HBC) in the range of low temperature (70-100 K) is studied. The energy spectrum of the proton in the unperturbed potential field of a crystal lattice modeled as a one-dimensi...

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Main Authors: V.A. Kalytka, A.I. Aliferov, Z.K. Baimukhanov, A.D. Mekhtiev, A.D. Alkina
Format: Article
Language:English
Published: Academician Ye.A. Buketov Karaganda University 2018-03-01
Series:Қарағанды университетінің хабаршысы. Физика сериясы
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Online Access:https://phs.buketov.edu.kz/index.php/physics-vestnik/article/view/213
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author V.A. Kalytka
A.I. Aliferov
Z.K. Baimukhanov
A.D. Mekhtiev
A.D. Alkina
author_facet V.A. Kalytka
A.I. Aliferov
Z.K. Baimukhanov
A.D. Mekhtiev
A.D. Alkina
author_sort V.A. Kalytka
collection DOAJ
description The quantum mechanism of the relaxation motion of the most mobile charge carriers (protons) in crystals with hydrogen bonds (HBC) in the range of low temperature (70-100 K) is studied. The energy spectrum of the proton in the unperturbed potential field of a crystal lattice modeled as a one-dimensional periodic potential relief of a rectangular shape is investigated in the quasi-classical approximation by the Wentzel – Kramers – Brillouin method (WKB-method) at ohmic contacts at the crystal boundaries (the work function of the proton from the crystal is assumed to be finite). The band structure of the energy spectrum of lowtemperature relaxers (protons) in proton materials was discovered, the word parameters of the band structure (width of the forbidden zone, «bottom» and «ceiling» of the energy zone minimum and maximum distances between two fixed energy bands). The populations of quasi-discrete energy levels (within the limits of the corresponding energy bands) by protons are calculated using an balanced (equilibrium) density matrix constructed on the basis of Boltzmann's quantum statistics for protons tunneling through a rectangular potential barrier. With the help of a quasi-stationary equilibrium density matrix, an expression is constructed for the polarization of the proton subsystem perturbed by an external homogeneous harmonic time-varying electric field.
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2663-5089
language English
publishDate 2018-03-01
publisher Academician Ye.A. Buketov Karaganda University
record_format Article
series Қарағанды университетінің хабаршысы. Физика сериясы
spelling doaj-art-3f4fba4c54d04b2e810e01beeb6083cd2025-08-20T03:18:12ZengAcademician Ye.A. Buketov Karaganda UniversityҚарағанды университетінің хабаршысы. Физика сериясы2518-71982663-50892018-03-01891Quantum properties of proton subsystem in proton semiconductorsV.A. KalytkaA.I. AliferovZ.K. BaimukhanovA.D. MekhtievA.D. Alkina The quantum mechanism of the relaxation motion of the most mobile charge carriers (protons) in crystals with hydrogen bonds (HBC) in the range of low temperature (70-100 K) is studied. The energy spectrum of the proton in the unperturbed potential field of a crystal lattice modeled as a one-dimensional periodic potential relief of a rectangular shape is investigated in the quasi-classical approximation by the Wentzel – Kramers – Brillouin method (WKB-method) at ohmic contacts at the crystal boundaries (the work function of the proton from the crystal is assumed to be finite). The band structure of the energy spectrum of lowtemperature relaxers (protons) in proton materials was discovered, the word parameters of the band structure (width of the forbidden zone, «bottom» and «ceiling» of the energy zone minimum and maximum distances between two fixed energy bands). The populations of quasi-discrete energy levels (within the limits of the corresponding energy bands) by protons are calculated using an balanced (equilibrium) density matrix constructed on the basis of Boltzmann's quantum statistics for protons tunneling through a rectangular potential barrier. With the help of a quasi-stationary equilibrium density matrix, an expression is constructed for the polarization of the proton subsystem perturbed by an external homogeneous harmonic time-varying electric field. https://phs.buketov.edu.kz/index.php/physics-vestnik/article/view/213crystals with hydrogen bondsthe band structure of the proton energy spectrum in the HBCquasiclassical approximation in quantum mechanicsthe equilibrium density matrix for protonsenergy zones of the proton in HBC
spellingShingle V.A. Kalytka
A.I. Aliferov
Z.K. Baimukhanov
A.D. Mekhtiev
A.D. Alkina
Quantum properties of proton subsystem in proton semiconductors
Қарағанды университетінің хабаршысы. Физика сериясы
crystals with hydrogen bonds
the band structure of the proton energy spectrum in the HBC
quasiclassical approximation in quantum mechanics
the equilibrium density matrix for protons
energy zones of the proton in HBC
title Quantum properties of proton subsystem in proton semiconductors
title_full Quantum properties of proton subsystem in proton semiconductors
title_fullStr Quantum properties of proton subsystem in proton semiconductors
title_full_unstemmed Quantum properties of proton subsystem in proton semiconductors
title_short Quantum properties of proton subsystem in proton semiconductors
title_sort quantum properties of proton subsystem in proton semiconductors
topic crystals with hydrogen bonds
the band structure of the proton energy spectrum in the HBC
quasiclassical approximation in quantum mechanics
the equilibrium density matrix for protons
energy zones of the proton in HBC
url https://phs.buketov.edu.kz/index.php/physics-vestnik/article/view/213
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AT aialiferov quantumpropertiesofprotonsubsysteminprotonsemiconductors
AT zkbaimukhanov quantumpropertiesofprotonsubsysteminprotonsemiconductors
AT admekhtiev quantumpropertiesofprotonsubsysteminprotonsemiconductors
AT adalkina quantumpropertiesofprotonsubsysteminprotonsemiconductors