Effect of Sm<sup>3+</sup> Doping on Energy Storage Property and Thermal Stability of BaSn<i><sub>x</sub></i>Ti<sub>1−<i>x</i></sub>O<sub>3</sub> Ceramics

Effect of Sm<sup>3+</sup> Doping on Energy Storage Property and Thermal Stability of BaSn<i><sub>x</sub></i>Ti<sub>1−<i>x</i></sub>O<sub>3</sub> Ceramics

Dielectric capacitors have become a key component for energy storage systems, owing to their exceptional power density and swift charge–discharge performance. In a series of lead-free ferroelectric ceramic materials, BaSn<i><sub>x</sub></i>Ti<sub>1-<i>x</i>&...

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Bibliographic Details
Main Authors:	Zhengchao Qin, Zhiyi Wang, Si Gao, Hongjuan Zheng, Jin Luo, Yunfei Liu, Yinong Lyu
Format:	Article
Language:	English
Published:	MDPI AG 2025-06-01
Series:	Crystals
Subjects:	BTS ferroelectrics energy storage thermal stability
Online Access:	https://www.mdpi.com/2073-4352/15/7/600
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Summary:	Dielectric capacitors have become a key component for energy storage systems, owing to their exceptional power density and swift charge–discharge performance. In a series of lead-free ferroelectric ceramic materials, BaSn<i><sub>x</sub></i>Ti<sub>1-<i>x</i></sub>O<sub>3</sub> (BTS) received widespread attention due to its unique properties. However, BTS ceramics with high Sn content have high efficiency (<i>η</i>) but low recovery energy storage density (W<i><sub>rec</sub></i>). We incorporated the Sm element into BTS ceramics and aimed to optimize both efficiency and recoverable energy density at moderate Sn content. With the synergistic effect between Sm and Sn, the optimal composition was found at 5% Sn content with 1% low-level Sm dopants, where the energy storage density reached 0.2310 J/cm<sup>3</sup> at 40 kV/cm. Furthermore, the thermal stability of the ceramic was investigated using temperature-dependent dielectric spectroscopy, in situ XRD, and temperature-dependent hysteresis loops. With Sm doping, the fluctuation of <i>W</i><sub>rec</sub> decreased from 18.48% to 12.01%. In general, this work not only enhances the understanding of samarium dopants but also proposes strategies for developing lead-free ferroelectric ceramics with superior energy storage properties.
ISSN:	2073-4352