Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II)
In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R22(8) motifs are formed by pairs of N—H...N hydrogen bonds. They are connected to each other through pairs of weak C—H...Cl interactions, forming a R22(16) motif, creating par...
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International Union of Crystallography
2025-07-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025005079 |
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| author | Olga V. Repina Elena Yu. Nevskaya Ilya S. Kritchenkov Victor N. Khrustalev Alexander S. Novikov Alexander G. Tskhovrebov Namiq Q. Shikhaliyev Aytan A. Niyazova Mehmet Akkurt Ajaya Bhattarai |
| author_facet | Olga V. Repina Elena Yu. Nevskaya Ilya S. Kritchenkov Victor N. Khrustalev Alexander S. Novikov Alexander G. Tskhovrebov Namiq Q. Shikhaliyev Aytan A. Niyazova Mehmet Akkurt Ajaya Bhattarai |
| author_sort | Olga V. Repina |
| collection | DOAJ |
| description | In the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R22(8) motifs are formed by pairs of N—H...N hydrogen bonds. They are connected to each other through pairs of weak C—H...Cl interactions, forming a R22(16) motif, creating parallel ribbons along the [011] axis. The molecular pairs are also linked by C—H...π and by π–π interactions, the shortest centroid-centroid distance [3.513 (2) Å] being observed between pyridyl rings. These weak interactions form parallel ribbons along the [010] axis. The resulting three-dimensional network ensures the cohesion of the crystal structure. Hirshfeld two-dimensional fingerprint plots revealed that the most significant interactions are H...H (58.0%), C...H/H...C (17.9%), Cl...H/H...Cl (10.7%), N...H/H...N (6.9%), C...C (2.9%), Pt...H/H...Pt (2.6%), and N...C/C...N (1.1%) contacts. |
| format | Article |
| id | doaj-art-3e8c694abaa745b59bfdde769eea5777 |
| institution | DOAJ |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-3e8c694abaa745b59bfdde769eea57772025-08-20T02:42:49ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-07-0181758759010.1107/S2056989025005079tx2098Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II)Olga V. Repina0Elena Yu. Nevskaya1Ilya S. Kritchenkov2Victor N. Khrustalev3Alexander S. Novikov4Alexander G. Tskhovrebov5Namiq Q. Shikhaliyev6Aytan A. Niyazova7Mehmet Akkurt8Ajaya Bhattarai9Peoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian FederationInstitute of Chemistry, Saint Petersburg State University, Universitetskaya Nab. 7/9, 199034 Saint Petersburg, Russian FederationPeoples' Friendship University of Russia, 6 Miklukho-Maklaya Street, Moscow, 117198, Russian FederationBaku Engineering University, Khirdalan City, 120 AZ0101 Hasan Aliyev Street, Baku, AzerbaijanAzerbaijan State University of Economics, M. Mukhtarov 194, 1001 Baku, AzerbaijanDepartment of Physics, Faculty of Sciences, Erciyes University, 38039 Kayseri, TürkiyeDepartment of Chemistry, M.M.A.M.C (Tribhuvan University) Biratnagar, NepalIn the title compound, [Pt(C14H14N3)Cl(C9H9N)], the platinum atom has a square-planar geometry. In the crystal, dimers with R22(8) motifs are formed by pairs of N—H...N hydrogen bonds. They are connected to each other through pairs of weak C—H...Cl interactions, forming a R22(16) motif, creating parallel ribbons along the [011] axis. The molecular pairs are also linked by C—H...π and by π–π interactions, the shortest centroid-centroid distance [3.513 (2) Å] being observed between pyridyl rings. These weak interactions form parallel ribbons along the [010] axis. The resulting three-dimensional network ensures the cohesion of the crystal structure. Hirshfeld two-dimensional fingerprint plots revealed that the most significant interactions are H...H (58.0%), C...H/H...C (17.9%), Cl...H/H...Cl (10.7%), N...H/H...N (6.9%), C...C (2.9%), Pt...H/H...Pt (2.6%), and N...C/C...N (1.1%) contacts.https://journals.iucr.org/paper?S2056989025005079crystal structuredimerssquare-planar geometryisocyanides2-aminopyridinehirshfeld surface analysis |
| spellingShingle | Olga V. Repina Elena Yu. Nevskaya Ilya S. Kritchenkov Victor N. Khrustalev Alexander S. Novikov Alexander G. Tskhovrebov Namiq Q. Shikhaliyev Aytan A. Niyazova Mehmet Akkurt Ajaya Bhattarai Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) Acta Crystallographica Section E: Crystallographic Communications crystal structure dimers square-planar geometry isocyanides 2-aminopyridine hirshfeld surface analysis |
| title | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
| title_full | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
| title_fullStr | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
| title_full_unstemmed | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
| title_short | Crystal structure and Hirshfeld surface analysis of chlorido(2,6-dimethylphenyl isocyanide)[N′-(2,6-dimethylphenyl)-N-(pyridin-2-yl)carbamimidoyl]platinum(II) |
| title_sort | crystal structure and hirshfeld surface analysis of chlorido 2 6 dimethylphenyl isocyanide n 2 6 dimethylphenyl n pyridin 2 yl carbamimidoyl platinum ii |
| topic | crystal structure dimers square-planar geometry isocyanides 2-aminopyridine hirshfeld surface analysis |
| url | https://journals.iucr.org/paper?S2056989025005079 |
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