Comprehensive structural study of lanthanide(III) chloride hydrates: [RECl3·xH2O (RE = La–Nd, Sm–Lu; x = 6, 7)]

Comprehensive structural study of lanthanide(III) chloride hydrates: [RECl3·xH2O (RE = La–Nd, Sm–Lu; x = 6, 7)]

A comprehensive crystallographic study is presented of the complete series of rare-earth(III) chloride hydrates. Early lanthanides form dimeric [(H2O)7RE(μ-Cl)2RE(H2O)7]4+ binuclear complexes in which each RE atom (RE = La3+, Ce3+) is coordinated by seven H2O molecules and two bridging inner-sphere...

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Bibliographic Details
Main Authors: Thimira Kandabadage, Beau Legnon, Sviatoslav Baranets
Format: Article
Language:English
Published: International Union of Crystallography 2024-12-01
Series:Acta Crystallographica Section E: Crystallographic Communications
Subjects:
crystal structure
rare-earth metals
periodic trends
coordination
hydrates
Online Access:https://journals.iucr.org/paper?S2056989024011319
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