Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media

This work examines the physicochemical properties and dissolution kinetics of Itakpe iron ore, Nigeria, to provide insight into its industrial and environmental applications. The iron ore had a bulk density of 4.22 g/cm3, an apparent density of 3.33 g/cm3, and a pH of 8.3, hence showing potential in...

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Main Authors: A. U. Atumeyi, A. U. Itodo, R. Sha'Ato, R. A. Wuana
Format: Article
Language:English
Published: Nigerian Society of Physical Sciences 2025-03-01
Series:African Scientific Reports
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Online Access:https://asr.nsps.org.ng/index.php/asr/article/view/260
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author A. U. Atumeyi
A. U. Itodo
R. Sha'Ato
R. A. Wuana
author_facet A. U. Atumeyi
A. U. Itodo
R. Sha'Ato
R. A. Wuana
author_sort A. U. Atumeyi
collection DOAJ
description This work examines the physicochemical properties and dissolution kinetics of Itakpe iron ore, Nigeria, to provide insight into its industrial and environmental applications. The iron ore had a bulk density of 4.22 g/cm3, an apparent density of 3.33 g/cm3, and a pH of 8.3, hence showing potential in adsorption and environmental remediation. Conductivity of 138.7 μS/cm and specific surface area of 146.81 m2/g showed potential in catalytic and adsorptive applications. The dissolution rates were significantly higher in acidic media, with a maximum weight loss of 5.65% at 360 minutes compared to 4.38% in basic media and 0.45% in neutral conditions. The zero-order kinetic model, R2 = 0.8819, showed that the dissolution process was surface-controlled in acidic media, while the Higuchi model, R2 = 0.8797, confirmed dissolution driven by diffusion. These findings emphasize the need to apply zero-order and Higuchi models in the dissolution kinetics of Itakpe iron ore. This work presents a clear quantitative comparison across media that was not developed earlier. These results support the optimized utilization of Itakpe iron ore in steel production and environmental remediation, hence indicating compatibility with various chemical conditions and that sustainable mining will help reduce harmful environmental impacts.
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spelling doaj-art-3e51be9f4b29415a9ed003e27a3a29442025-08-20T03:09:27ZengNigerian Society of Physical SciencesAfrican Scientific Reports2955-16252955-16172025-03-014110.46481/asr.2025.4.1.260Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous mediaA. U. AtumeyiA. U. ItodoR. Sha'AtoR. A. WuanaThis work examines the physicochemical properties and dissolution kinetics of Itakpe iron ore, Nigeria, to provide insight into its industrial and environmental applications. The iron ore had a bulk density of 4.22 g/cm3, an apparent density of 3.33 g/cm3, and a pH of 8.3, hence showing potential in adsorption and environmental remediation. Conductivity of 138.7 μS/cm and specific surface area of 146.81 m2/g showed potential in catalytic and adsorptive applications. The dissolution rates were significantly higher in acidic media, with a maximum weight loss of 5.65% at 360 minutes compared to 4.38% in basic media and 0.45% in neutral conditions. The zero-order kinetic model, R2 = 0.8819, showed that the dissolution process was surface-controlled in acidic media, while the Higuchi model, R2 = 0.8797, confirmed dissolution driven by diffusion. These findings emphasize the need to apply zero-order and Higuchi models in the dissolution kinetics of Itakpe iron ore. This work presents a clear quantitative comparison across media that was not developed earlier. These results support the optimized utilization of Itakpe iron ore in steel production and environmental remediation, hence indicating compatibility with various chemical conditions and that sustainable mining will help reduce harmful environmental impacts. https://asr.nsps.org.ng/index.php/asr/article/view/260Dissolution, Environment, Iron ore, Kinetics, Physicochemical
spellingShingle A. U. Atumeyi
A. U. Itodo
R. Sha'Ato
R. A. Wuana
Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
African Scientific Reports
Dissolution, Environment, Iron ore, Kinetics, Physicochemical
title Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
title_full Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
title_fullStr Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
title_full_unstemmed Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
title_short Physicochemical analysis and dissolution kinetics of Itakpe iron ore in acid, base and aqueous media
title_sort physicochemical analysis and dissolution kinetics of itakpe iron ore in acid base and aqueous media
topic Dissolution, Environment, Iron ore, Kinetics, Physicochemical
url https://asr.nsps.org.ng/index.php/asr/article/view/260
work_keys_str_mv AT auatumeyi physicochemicalanalysisanddissolutionkineticsofitakpeironoreinacidbaseandaqueousmedia
AT auitodo physicochemicalanalysisanddissolutionkineticsofitakpeironoreinacidbaseandaqueousmedia
AT rshaato physicochemicalanalysisanddissolutionkineticsofitakpeironoreinacidbaseandaqueousmedia
AT rawuana physicochemicalanalysisanddissolutionkineticsofitakpeironoreinacidbaseandaqueousmedia