Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles

This study aims to discover innovative thermal storage materials that fulfill the specifications of concentrated solar power systems. Thermal storage materials based on ternary eutectic (Hitec) with nano-SiO2 and nano-MgO are investigated. Simultaneous thermal analysis and laser flash analysis are u...

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Main Authors: Baiyuan Tian, Chuang Zhu, Manting Gu, Minhao Xu, Wenxuan He
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Journal of Science: Advanced Materials and Devices
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Online Access:http://www.sciencedirect.com/science/article/pii/S2468217925000024
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author Baiyuan Tian
Chuang Zhu
Manting Gu
Minhao Xu
Wenxuan He
author_facet Baiyuan Tian
Chuang Zhu
Manting Gu
Minhao Xu
Wenxuan He
author_sort Baiyuan Tian
collection DOAJ
description This study aims to discover innovative thermal storage materials that fulfill the specifications of concentrated solar power systems. Thermal storage materials based on ternary eutectic (Hitec) with nano-SiO2 and nano-MgO are investigated. Simultaneous thermal analysis and laser flash analysis are used to study the main properties of materials. The results indicate that the inclusion of nano-SiO2 and nano-MgO reduces the melting point while enhancing the latent heat of the base salt. Doping the base salt with 0.3 wt% nano-SiO2 and 0.7 wt% nano-MgO results in molten salt nanocomposites with an average specific heat of 2.16 J/(g⋅K), which is 54.3% higher than that of the base salt. This surpasses the specific heat of the base salt mixed with a single type of nanoparticle. The thermal conductivity of this nanocomposite is increased by 13.13% to 0.836 W/(m⋅K) compared to the base salt. Furthermore, this study demonstrated that the effect of interfacial thermal resistance on specific heat capacity and heat transfer characteristics is the opposite. While the nanoparticles can increase the specific heat capacity of the molten salt, they can also reduce the heat transfer rate within this material.
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id doaj-art-3e2654fe9e2d4fb7b692ef92375ea27b
institution Kabale University
issn 2468-2179
language English
publishDate 2025-06-01
publisher Elsevier
record_format Article
series Journal of Science: Advanced Materials and Devices
spelling doaj-art-3e2654fe9e2d4fb7b692ef92375ea27b2025-02-07T04:47:59ZengElsevierJournal of Science: Advanced Materials and Devices2468-21792025-06-01102100849Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticlesBaiyuan Tian0Chuang Zhu1Manting Gu2Minhao Xu3Wenxuan He4School of Energy and Electrical Engineering, Qinghai University, Xining, 810016, ChinaSchool of Energy and Electrical Engineering, Qinghai University, Xining, 810016, China; Engineer School, Qinghai Institute of Technology, Xining, 810016, China; Corresponding author. School of Energy and Electrical Engineering, Qinghai University, Xining, 810016, China.School of Energy and Electrical Engineering, Qinghai University, Xining, 810016, ChinaSchool of Energy and Electrical Engineering, Qinghai University, Xining, 810016, ChinaSchool of Energy and Electrical Engineering, Qinghai University, Xining, 810016, ChinaThis study aims to discover innovative thermal storage materials that fulfill the specifications of concentrated solar power systems. Thermal storage materials based on ternary eutectic (Hitec) with nano-SiO2 and nano-MgO are investigated. Simultaneous thermal analysis and laser flash analysis are used to study the main properties of materials. The results indicate that the inclusion of nano-SiO2 and nano-MgO reduces the melting point while enhancing the latent heat of the base salt. Doping the base salt with 0.3 wt% nano-SiO2 and 0.7 wt% nano-MgO results in molten salt nanocomposites with an average specific heat of 2.16 J/(g⋅K), which is 54.3% higher than that of the base salt. This surpasses the specific heat of the base salt mixed with a single type of nanoparticle. The thermal conductivity of this nanocomposite is increased by 13.13% to 0.836 W/(m⋅K) compared to the base salt. Furthermore, this study demonstrated that the effect of interfacial thermal resistance on specific heat capacity and heat transfer characteristics is the opposite. While the nanoparticles can increase the specific heat capacity of the molten salt, they can also reduce the heat transfer rate within this material.http://www.sciencedirect.com/science/article/pii/S2468217925000024Molten salt nanocompositesThermal storageLatent heatSpecific heatThermal conductivity
spellingShingle Baiyuan Tian
Chuang Zhu
Manting Gu
Minhao Xu
Wenxuan He
Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
Journal of Science: Advanced Materials and Devices
Molten salt nanocomposites
Thermal storage
Latent heat
Specific heat
Thermal conductivity
title Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
title_full Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
title_fullStr Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
title_full_unstemmed Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
title_short Thermophysical properties enhancement of KNO3–NaNO3–NaNO2 mixed with SiO2/MgO nanoparticles
title_sort thermophysical properties enhancement of kno3 nano3 nano2 mixed with sio2 mgo nanoparticles
topic Molten salt nanocomposites
Thermal storage
Latent heat
Specific heat
Thermal conductivity
url http://www.sciencedirect.com/science/article/pii/S2468217925000024
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AT mantinggu thermophysicalpropertiesenhancementofkno3nano3nano2mixedwithsio2mgonanoparticles
AT minhaoxu thermophysicalpropertiesenhancementofkno3nano3nano2mixedwithsio2mgonanoparticles
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