Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode

Asymmetric capacitors with a non-aqueous electrolyte were constructed by using various carbons as negative and positive electrodes in order to study their performance. For asymmetric capacitors where the ratio of the BET surface area, S BET , of the negative carbon electrode to that of the positive...

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Main Authors: Lihong Wang, Masahiro Toyoda, Michio Inagaki
Format: Article
Language:English
Published: SAGE Publishing 2008-09-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1260/0263-6174.26.7.491
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author Lihong Wang
Masahiro Toyoda
Michio Inagaki
author_facet Lihong Wang
Masahiro Toyoda
Michio Inagaki
author_sort Lihong Wang
collection DOAJ
description Asymmetric capacitors with a non-aqueous electrolyte were constructed by using various carbons as negative and positive electrodes in order to study their performance. For asymmetric capacitors where the ratio of the BET surface area, S BET , of the negative carbon electrode to that of the positive carbon electrode was less than 1.7, the capacitance of the electric double layer was strongly governed by the negative carbon electrode. Their rate performance, as evaluated from the ratio of the capacitance at 200 mA to that at 20 mA, C 200 /C 20 , was determined by the mesoporous surface area of the negative carbon electrode. What is important, however, is that the negative carbon electrode in capacitors governs their characteristics, viz. their capacitance and rate performance. This conclusion was arrived at by constructing asymmetric electric double layer capacitors employing carbons with different pore structures as the negative and positive electrodes. The present result provides information which is important in the design of electrodes for electric double layer capacitors.
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series Adsorption Science & Technology
spelling doaj-art-3dfa4b0b3d2144b48128e0ea85704fd12025-01-02T22:38:06ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40382008-09-012610.1260/0263-6174.26.7.491Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative ElectrodeLihong Wang0Masahiro Toyoda1Michio Inagaki2 Central R & D, Daido Metal Co., Ltd., Maehara, Inuyama 484-0061, Japan Faculty of Engineering, Oita University, Dannoharu, Oita 870-1192, Japan Faculty of Engineering, Aichi Institute of Technology, Yakusa, Toyota 470-0392, JapanAsymmetric capacitors with a non-aqueous electrolyte were constructed by using various carbons as negative and positive electrodes in order to study their performance. For asymmetric capacitors where the ratio of the BET surface area, S BET , of the negative carbon electrode to that of the positive carbon electrode was less than 1.7, the capacitance of the electric double layer was strongly governed by the negative carbon electrode. Their rate performance, as evaluated from the ratio of the capacitance at 200 mA to that at 20 mA, C 200 /C 20 , was determined by the mesoporous surface area of the negative carbon electrode. What is important, however, is that the negative carbon electrode in capacitors governs their characteristics, viz. their capacitance and rate performance. This conclusion was arrived at by constructing asymmetric electric double layer capacitors employing carbons with different pore structures as the negative and positive electrodes. The present result provides information which is important in the design of electrodes for electric double layer capacitors.https://doi.org/10.1260/0263-6174.26.7.491
spellingShingle Lihong Wang
Masahiro Toyoda
Michio Inagaki
Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
Adsorption Science & Technology
title Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
title_full Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
title_fullStr Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
title_full_unstemmed Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
title_short Performance of Asymmetric Electric Double Layer Capacitors — Predominant Contribution of the Negative Electrode
title_sort performance of asymmetric electric double layer capacitors predominant contribution of the negative electrode
url https://doi.org/10.1260/0263-6174.26.7.491
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AT michioinagaki performanceofasymmetricelectricdoublelayercapacitorspredominantcontributionofthenegativeelectrode