Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state

Detonation performance is crucial for evaluating the power of high explosives (HEs), and the equation of state (EOS) that accurately describes the high-temperature, high-pressure, and high-temperature, medium-pressure states of detonation products is key to assessing the damage efficiency of these e...

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Main Authors: Yong Han, Qin Liu, Yingliang Duan, Yaqi Zhao, Xinping Long
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-02-01
Series:Defence Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2214914724002502
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author Yong Han
Qin Liu
Yingliang Duan
Yaqi Zhao
Xinping Long
author_facet Yong Han
Qin Liu
Yingliang Duan
Yaqi Zhao
Xinping Long
author_sort Yong Han
collection DOAJ
description Detonation performance is crucial for evaluating the power of high explosives (HEs), and the equation of state (EOS) that accurately describes the high-temperature, high-pressure, and high-temperature, medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials. This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions. A new gas EOS for detonation products, called VHL (Virial-Han-Long), is proposed. The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified, and its performance in evaluating explosive detonation and working capabilities is explored. The results demonstrate that VHL exhibits high precision in calculating detonation performance. Subsequently, the detonation performance of three new HEs (ICM-101, ONC, and TNAZ) was calculated and compared to traditional HEs (TATB, CL-20, and HMX). The results indicate that ONC has superior detonation performance compared to the other explosives, while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure. The detonation characteristics of TNAZ are comparable to those of the standard HE HMX. From the perspective of products, considering the comprehensive work performance (mechanical work and detonation heat), both ONC and ICM-101 demonstrate relatively superior performance.
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spelling doaj-art-3debf41c0de04a4cad85b4ff3ca0d7732025-08-20T03:00:51ZengKeAi Communications Co., Ltd.Defence Technology2214-91472025-02-0144839710.1016/j.dt.2024.10.007Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of stateYong Han0Qin Liu1Yingliang Duan2Yaqi Zhao3Xinping Long4Institute of Chemical Materials, China Academy of Engineering Physics, Youxian District, Mianyang, 621000, ChinaInstitute of Chemical Materials, China Academy of Engineering Physics, Youxian District, Mianyang, 621000, ChinaInstitute of Chemical Materials, China Academy of Engineering Physics, Youxian District, Mianyang, 621000, ChinaInstitute of Chemical Materials, China Academy of Engineering Physics, Youxian District, Mianyang, 621000, ChinaChina Academy of Engineering Physics, Youxian District, Mianyang, 621000, China; Corresponding author.Detonation performance is crucial for evaluating the power of high explosives (HEs), and the equation of state (EOS) that accurately describes the high-temperature, high-pressure, and high-temperature, medium-pressure states of detonation products is key to assessing the damage efficiency of these energetic materials. This article examines the limitations of the VLW EOS in representing the thermodynamic states of explosive detonation gas products under high-temperature and medium-to high-pressure conditions. A new gas EOS for detonation products, called VHL (Virial-Han-Long), is proposed. The accuracy of VHL in describing gas states under high-temperature and medium-to high-pressure conditions is verified, and its performance in evaluating explosive detonation and working capabilities is explored. The results demonstrate that VHL exhibits high precision in calculating detonation performance. Subsequently, the detonation performance of three new HEs (ICM-101, ONC, and TNAZ) was calculated and compared to traditional HEs (TATB, CL-20, and HMX). The results indicate that ONC has superior detonation performance compared to the other explosives, while ICM-101 shows a detonation velocity similar to CL-20 but with slightly lower detonation pressure. The detonation characteristics of TNAZ are comparable to those of the standard HE HMX. From the perspective of products, considering the comprehensive work performance (mechanical work and detonation heat), both ONC and ICM-101 demonstrate relatively superior performance.http://www.sciencedirect.com/science/article/pii/S2214914724002502Equation of stateDetonation performanceWorking capabilityThermodynamicsHigh explosive
spellingShingle Yong Han
Qin Liu
Yingliang Duan
Yaqi Zhao
Xinping Long
Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
Defence Technology
Equation of state
Detonation performance
Working capability
Thermodynamics
High explosive
title Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
title_full Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
title_fullStr Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
title_full_unstemmed Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
title_short Evaluation of detonation performance of explosives ICM-101, ONC, and TNAZ based on improved VHL equation of state
title_sort evaluation of detonation performance of explosives icm 101 onc and tnaz based on improved vhl equation of state
topic Equation of state
Detonation performance
Working capability
Thermodynamics
High explosive
url http://www.sciencedirect.com/science/article/pii/S2214914724002502
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AT yingliangduan evaluationofdetonationperformanceofexplosivesicm101oncandtnazbasedonimprovedvhlequationofstate
AT yaqizhao evaluationofdetonationperformanceofexplosivesicm101oncandtnazbasedonimprovedvhlequationofstate
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