The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland

Abstract This study conducted measurements of PM2.5 (particulate matter with a diameter ≤ 2.5 µm) in Racibórz, Poland, during 2018. Samples were collected daily and analyzed for their chemical composition, specifically, the carbonaceous (elemental and organic carbon) and water-soluble ionic (Cl−, NO...

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Main Authors: Barbara Błaszczak, Natalia Zioła, Barbara Mathews, Krzysztof Klejnowski, Krzysztof Słaby
Format: Article
Language:English
Published: Springer 2020-08-01
Series:Aerosol and Air Quality Research
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Online Access:https://doi.org/10.4209/aaqr.2020.01.0013
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author Barbara Błaszczak
Natalia Zioła
Barbara Mathews
Krzysztof Klejnowski
Krzysztof Słaby
author_facet Barbara Błaszczak
Natalia Zioła
Barbara Mathews
Krzysztof Klejnowski
Krzysztof Słaby
author_sort Barbara Błaszczak
collection DOAJ
description Abstract This study conducted measurements of PM2.5 (particulate matter with a diameter ≤ 2.5 µm) in Racibórz, Poland, during 2018. Samples were collected daily and analyzed for their chemical composition, specifically, the carbonaceous (elemental and organic carbon) and water-soluble ionic (Cl−, NO3−, SO42–, Na+, NH4+, K+, Ca2+ and Mg2+) components. Additionally, the secondary inorganic aerosol (SIA) as well as the secondary and primary organic carbon (SOC and POC, respectively) content was estimated. To identify the causes of elevated PM2.5 concentrations, the contributions of these chemical species were further investigated, and the role of meteorological factors was also examined. During the measurement period, PM2.5 concentrations exceeding 50 µg m–3 were recorded on 38 days, and 7 pollution episodes were detected. Such events, however, were observed only in the heating season, when stable meteorological conditions (low air temperatures, weak winds, high relative humidity and lack of precipitation) and increased emissions of PM and its precursors from anthropogenic sources favored the accumulation of pollutants. The PM2.5 was dominated by carbonaceous aerosol, especially POC, although the SOC rose significantly during high pollution periods. Furthermore, the fraction of SIA clearly decreased as the concentration of PM2.5 increased, and its variability was greatly affected by regional and/or long-range transport events. Our results can help guide the development of effective strategies for reducing air pollution from fine particulate matter. Such control measures are particularly important in Poland, where PM2.5 concentrations remain high compared to many European countries.
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spelling doaj-art-3d2e36468c624b36868b2ae7dac3e4582025-02-09T12:19:08ZengSpringerAerosol and Air Quality Research1680-85842071-14092020-08-0120112433244710.4209/aaqr.2020.01.0013The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern PolandBarbara Błaszczak0Natalia Zioła1Barbara Mathews2Krzysztof Klejnowski3Krzysztof Słaby4Institute of Environmental Engineering of the Polish Academy of SciencesInstitute of Environmental Engineering of the Polish Academy of SciencesInstitute of Environmental Engineering of the Polish Academy of SciencesInstitute of Environmental Engineering of the Polish Academy of SciencesInstitute of Environmental Engineering of the Polish Academy of SciencesAbstract This study conducted measurements of PM2.5 (particulate matter with a diameter ≤ 2.5 µm) in Racibórz, Poland, during 2018. Samples were collected daily and analyzed for their chemical composition, specifically, the carbonaceous (elemental and organic carbon) and water-soluble ionic (Cl−, NO3−, SO42–, Na+, NH4+, K+, Ca2+ and Mg2+) components. Additionally, the secondary inorganic aerosol (SIA) as well as the secondary and primary organic carbon (SOC and POC, respectively) content was estimated. To identify the causes of elevated PM2.5 concentrations, the contributions of these chemical species were further investigated, and the role of meteorological factors was also examined. During the measurement period, PM2.5 concentrations exceeding 50 µg m–3 were recorded on 38 days, and 7 pollution episodes were detected. Such events, however, were observed only in the heating season, when stable meteorological conditions (low air temperatures, weak winds, high relative humidity and lack of precipitation) and increased emissions of PM and its precursors from anthropogenic sources favored the accumulation of pollutants. The PM2.5 was dominated by carbonaceous aerosol, especially POC, although the SOC rose significantly during high pollution periods. Furthermore, the fraction of SIA clearly decreased as the concentration of PM2.5 increased, and its variability was greatly affected by regional and/or long-range transport events. Our results can help guide the development of effective strategies for reducing air pollution from fine particulate matter. Such control measures are particularly important in Poland, where PM2.5 concentrations remain high compared to many European countries.https://doi.org/10.4209/aaqr.2020.01.0013PM2.5High pollution daysCarbonaceous aerosolPrimary and secondary organic carbonSecondary inorganic aerosolMeteorology
spellingShingle Barbara Błaszczak
Natalia Zioła
Barbara Mathews
Krzysztof Klejnowski
Krzysztof Słaby
The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
Aerosol and Air Quality Research
PM2.5
High pollution days
Carbonaceous aerosol
Primary and secondary organic carbon
Secondary inorganic aerosol
Meteorology
title The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
title_full The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
title_fullStr The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
title_full_unstemmed The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
title_short The Role of PM2.5 Chemical Composition and Meteorology during High Pollution Periods at a Suburban Background Station in Southern Poland
title_sort role of pm2 5 chemical composition and meteorology during high pollution periods at a suburban background station in southern poland
topic PM2.5
High pollution days
Carbonaceous aerosol
Primary and secondary organic carbon
Secondary inorganic aerosol
Meteorology
url https://doi.org/10.4209/aaqr.2020.01.0013
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