Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media

The adsorption and corrosion inhibitive effect of acid red GRE (183) dye on carbon steel alloy in 1 M HCl solutions was studied using various techniques. Results of weight loss, Tafel polarization measurements and electrochemical impedance spectroscopy (EIS) techniques show that this compound has fa...

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Main Authors: M. Abd El-raouf, Olfat E. El-Azabawy, R.E. El-Azabawy
Format: Article
Language:English
Published: Egyptian Petroleum Research Institute 2015-09-01
Series:Egyptian Journal of Petroleum
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S1110062115000562
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author M. Abd El-raouf
Olfat E. El-Azabawy
R.E. El-Azabawy
author_facet M. Abd El-raouf
Olfat E. El-Azabawy
R.E. El-Azabawy
author_sort M. Abd El-raouf
collection DOAJ
description The adsorption and corrosion inhibitive effect of acid red GRE (183) dye on carbon steel alloy in 1 M HCl solutions was studied using various techniques. Results of weight loss, Tafel polarization measurements and electrochemical impedance spectroscopy (EIS) techniques show that this compound has fairly good inhibiting properties for steel corrosion in acidic bath; with efficiency around 96% at a concentration of 50 ppm. The inhibition is of a mixed anodic–cathodic nature. Factors affecting the corrosion process have been calculated and discussed. Acid red GRE (183) dye was shown to be an inhibitor in the acidic corrosion. Inhibition efficiency increased with acid red GRE (183) dye concentration but decreased with rise in temperature, corrosion inhibition is attributed to the adsorption of acid red GRE (183) dye on the carbon steel surface via a physical adsorption mechanism. Langmuir isotherm is found to provide an accurate description of the adsorption behavior of the investigated azo compound. The nature of the protective film was investigated using SEM and EDX techniques.
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issn 1110-0621
language English
publishDate 2015-09-01
publisher Egyptian Petroleum Research Institute
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series Egyptian Journal of Petroleum
spelling doaj-art-3d15fd68273b4c75b9852c4d6dee02eb2025-08-20T03:04:43ZengEgyptian Petroleum Research InstituteEgyptian Journal of Petroleum1110-06212015-09-0124323323910.1016/j.ejpe.2015.07.006Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid mediaM. Abd El-raouf0Olfat E. El-Azabawy1R.E. El-Azabawy2Egyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptEgyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptAl-Azhar University, Nasr City, Cairo, EgyptThe adsorption and corrosion inhibitive effect of acid red GRE (183) dye on carbon steel alloy in 1 M HCl solutions was studied using various techniques. Results of weight loss, Tafel polarization measurements and electrochemical impedance spectroscopy (EIS) techniques show that this compound has fairly good inhibiting properties for steel corrosion in acidic bath; with efficiency around 96% at a concentration of 50 ppm. The inhibition is of a mixed anodic–cathodic nature. Factors affecting the corrosion process have been calculated and discussed. Acid red GRE (183) dye was shown to be an inhibitor in the acidic corrosion. Inhibition efficiency increased with acid red GRE (183) dye concentration but decreased with rise in temperature, corrosion inhibition is attributed to the adsorption of acid red GRE (183) dye on the carbon steel surface via a physical adsorption mechanism. Langmuir isotherm is found to provide an accurate description of the adsorption behavior of the investigated azo compound. The nature of the protective film was investigated using SEM and EDX techniques.http://www.sciencedirect.com/science/article/pii/S1110062115000562Corrosion inhibitorsCarbon steel pipelinePolarizationEISSEMEDX
spellingShingle M. Abd El-raouf
Olfat E. El-Azabawy
R.E. El-Azabawy
Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
Egyptian Journal of Petroleum
Corrosion inhibitors
Carbon steel pipeline
Polarization
EIS
SEM
EDX
title Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
title_full Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
title_fullStr Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
title_full_unstemmed Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
title_short Investigation of adsorption and inhibitive effect of acid red GRE (183) dye on the corrosion of carbon steel in hydrochloric acid media
title_sort investigation of adsorption and inhibitive effect of acid red gre 183 dye on the corrosion of carbon steel in hydrochloric acid media
topic Corrosion inhibitors
Carbon steel pipeline
Polarization
EIS
SEM
EDX
url http://www.sciencedirect.com/science/article/pii/S1110062115000562
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AT reelazabawy investigationofadsorptionandinhibitiveeffectofacidredgre183dyeonthecorrosionofcarbonsteelinhydrochloricacidmedia