Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives

Morphology, grating formation dynamics and electro-optical performance of transflective multiplexing with holographic polymer dispersed liquid crystal (HPDLC) were investigated in the presence of silica nanoparticles (Aerosil R812 (RS) and modified Aerosil 200 (MS)) and silicon monomer (vinyltrimeth...

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Format: Article
Language:English
Published: Budapest University of Technology and Economics 2011-01-01
Series:eXPRESS Polymer Letters
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Online Access:http://www.expresspolymlett.com/letolt.php?file=EPL-0001751&mi=cd
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description Morphology, grating formation dynamics and electro-optical performance of transflective multiplexing with holographic polymer dispersed liquid crystal (HPDLC) were investigated in the presence of silica nanoparticles (Aerosil R812 (RS) and modified Aerosil 200 (MS)) and silicon monomer (vinyltrimethoxy silane (VTMS)) by using three coherent laser beams. The addition of Si additive significantly augmented the diffraction efficiencies of transmission and reflection gratings due to the enhanced phase separation with large LC channels. The film was driven only with Si additives which are enriched at the polymer-LC interfaces. As the additive content increased, driving voltage decreased to a minimum of 30 V at 2.0 wt% VTMS. It was found that the interface modification and large droplet size are crucial to operate the film. Among the three types of Si additive, VTMS showed the highest electro-optical performance due to its low viscosity and high reactivity.
format Article
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institution Kabale University
issn 1788-618X
language English
publishDate 2011-01-01
publisher Budapest University of Technology and Economics
record_format Article
series eXPRESS Polymer Letters
spelling doaj-art-3cd76e6bddda458ba2c66823e011925b2025-08-20T03:33:15ZengBudapest University of Technology and EconomicseXPRESS Polymer Letters1788-618X2011-01-0151738110.3144/expresspolymlett.2011.8Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additivesMorphology, grating formation dynamics and electro-optical performance of transflective multiplexing with holographic polymer dispersed liquid crystal (HPDLC) were investigated in the presence of silica nanoparticles (Aerosil R812 (RS) and modified Aerosil 200 (MS)) and silicon monomer (vinyltrimethoxy silane (VTMS)) by using three coherent laser beams. The addition of Si additive significantly augmented the diffraction efficiencies of transmission and reflection gratings due to the enhanced phase separation with large LC channels. The film was driven only with Si additives which are enriched at the polymer-LC interfaces. As the additive content increased, driving voltage decreased to a minimum of 30 V at 2.0 wt% VTMS. It was found that the interface modification and large droplet size are crucial to operate the film. Among the three types of Si additive, VTMS showed the highest electro-optical performance due to its low viscosity and high reactivity.http://www.expresspolymlett.com/letolt.php?file=EPL-0001751&mi=cdNanocompositesmultiplexingHPDLCtransflective gratingsilica
spellingShingle Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
eXPRESS Polymer Letters
Nanocomposites
multiplexing
HPDLC
transflective grating
silica
title Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
title_full Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
title_fullStr Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
title_full_unstemmed Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
title_short Transflective multiplexing of holographic polymer dispersed liquid crystal using Si additives
title_sort transflective multiplexing of holographic polymer dispersed liquid crystal using si additives
topic Nanocomposites
multiplexing
HPDLC
transflective grating
silica
url http://www.expresspolymlett.com/letolt.php?file=EPL-0001751&mi=cd