Microbiologically influenced corrosion in uncoated and coated Mild Steel

Abstract The study aimed to investigate the corrosion performance of Zn-Ni-Cu and Zn-Ni-Cu-TiB2 coatings in the microbial-induced environment (E-Coli, ATCC 25922, and 3.5%NaCl solution). Zn-Ni-Cu and Zn-Ni-Cu-TiB2 were surfaces coated on an ASTM A-36 Steel substrate utilizing a high-velocity oxy-fue...

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Main Authors: Sheikh Idrees Ali, Sheikh Nazir Ahmad
Format: Article
Language:English
Published: Nature Portfolio 2025-04-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-90003-5
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author Sheikh Idrees Ali
Sheikh Nazir Ahmad
author_facet Sheikh Idrees Ali
Sheikh Nazir Ahmad
author_sort Sheikh Idrees Ali
collection DOAJ
description Abstract The study aimed to investigate the corrosion performance of Zn-Ni-Cu and Zn-Ni-Cu-TiB2 coatings in the microbial-induced environment (E-Coli, ATCC 25922, and 3.5%NaCl solution). Zn-Ni-Cu and Zn-Ni-Cu-TiB2 were surfaces coated on an ASTM A-36 Steel substrate utilizing a high-velocity oxy-fuel (HVOF) thermal spray process. Immersion tests following ASTM G-31, and ASTM G1-03, standards were performed in Escherichia Coli (E-Coli, American Type Culture CollectionATCC25922) bacteria medium. The effect of Zn, Ni, and Ti was studied in preventing microbial-induced corrosion.SEM, and XRD analysis before and after helped to understand the morphological and structural changes in coated/uncoated ASTM A-36 steel. Various forms of rust were ascertained in XRD analysis. The inclusion of Zn and Cu inhibited bacterial attachment to the coated surface, hence preventing significant corrosion of the underlying substrate. The coatings performed effectively and inhibited bacterial growth. The uncoated ASTM A-36 Steel specimen showed well-developed bacterial colonies on the surface and in the solution medium. All forms of rust were reported in XRD analysis for uncoated ASTM A-36 steel while few forms of rust were reported in coated ASTM A-36 steel.Electrochemical impedance spectroscopy (EIS) and Tafel polarization in Escherichia coli (E-Coli, ATCC 25922) medium demonstrated that the coated samples had greater corrosion resistance than the uncoated ASTM A-36 Steel specimens. The higher corrosion potential (Ecorr) values of the two coated samples indicated improved anodic protection.
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spelling doaj-art-3bb7dd899f2344869da0fdbb2289e7ce2025-08-20T03:10:17ZengNature PortfolioScientific Reports2045-23222025-04-0115111610.1038/s41598-025-90003-5Microbiologically influenced corrosion in uncoated and coated Mild SteelSheikh Idrees Ali0Sheikh Nazir Ahmad1Department of Mechanical Engineering, National Institute of Technology SrinagarDepartment of Mechanical Engineering, National Institute of Technology SrinagarAbstract The study aimed to investigate the corrosion performance of Zn-Ni-Cu and Zn-Ni-Cu-TiB2 coatings in the microbial-induced environment (E-Coli, ATCC 25922, and 3.5%NaCl solution). Zn-Ni-Cu and Zn-Ni-Cu-TiB2 were surfaces coated on an ASTM A-36 Steel substrate utilizing a high-velocity oxy-fuel (HVOF) thermal spray process. Immersion tests following ASTM G-31, and ASTM G1-03, standards were performed in Escherichia Coli (E-Coli, American Type Culture CollectionATCC25922) bacteria medium. The effect of Zn, Ni, and Ti was studied in preventing microbial-induced corrosion.SEM, and XRD analysis before and after helped to understand the morphological and structural changes in coated/uncoated ASTM A-36 steel. Various forms of rust were ascertained in XRD analysis. The inclusion of Zn and Cu inhibited bacterial attachment to the coated surface, hence preventing significant corrosion of the underlying substrate. The coatings performed effectively and inhibited bacterial growth. The uncoated ASTM A-36 Steel specimen showed well-developed bacterial colonies on the surface and in the solution medium. All forms of rust were reported in XRD analysis for uncoated ASTM A-36 steel while few forms of rust were reported in coated ASTM A-36 steel.Electrochemical impedance spectroscopy (EIS) and Tafel polarization in Escherichia coli (E-Coli, ATCC 25922) medium demonstrated that the coated samples had greater corrosion resistance than the uncoated ASTM A-36 Steel specimens. The higher corrosion potential (Ecorr) values of the two coated samples indicated improved anodic protection.https://doi.org/10.1038/s41598-025-90003-5Bacterium Escherichia ColiHigh-velocity oxy-fuel sprayingMicrobiologically- Induced CorrosionAirborne reactive oxygen speciesBiotic environment
spellingShingle Sheikh Idrees Ali
Sheikh Nazir Ahmad
Microbiologically influenced corrosion in uncoated and coated Mild Steel
Scientific Reports
Bacterium Escherichia Coli
High-velocity oxy-fuel spraying
Microbiologically- Induced Corrosion
Airborne reactive oxygen species
Biotic environment
title Microbiologically influenced corrosion in uncoated and coated Mild Steel
title_full Microbiologically influenced corrosion in uncoated and coated Mild Steel
title_fullStr Microbiologically influenced corrosion in uncoated and coated Mild Steel
title_full_unstemmed Microbiologically influenced corrosion in uncoated and coated Mild Steel
title_short Microbiologically influenced corrosion in uncoated and coated Mild Steel
title_sort microbiologically influenced corrosion in uncoated and coated mild steel
topic Bacterium Escherichia Coli
High-velocity oxy-fuel spraying
Microbiologically- Induced Corrosion
Airborne reactive oxygen species
Biotic environment
url https://doi.org/10.1038/s41598-025-90003-5
work_keys_str_mv AT sheikhidreesali microbiologicallyinfluencedcorrosioninuncoatedandcoatedmildsteel
AT sheikhnazirahmad microbiologicallyinfluencedcorrosioninuncoatedandcoatedmildsteel