Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface
The self-assembled monolayer (SAM) was prepared using octadecyl trichlorosilane (OTS) in distilled solution on the copper surface. The effect of inhibitor concentration on the rate of inhibition efficiency and corrosion rate in corrosion medium on copper by using polarization curves, electrochemical...
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Wiley
2017-01-01
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Series: | International Journal of Analytical Chemistry |
Online Access: | http://dx.doi.org/10.1155/2017/4975714 |
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author | Xue Shouqing Liu Xiaohui |
author_facet | Xue Shouqing Liu Xiaohui |
author_sort | Xue Shouqing |
collection | DOAJ |
description | The self-assembled monolayer (SAM) was prepared using octadecyl trichlorosilane (OTS) in distilled solution on the copper surface. The effect of inhibitor concentration on the rate of inhibition efficiency and corrosion rate in corrosion medium on copper by using polarization curves, electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM) was studied. The results showed that OTS SAMs exhibit the better corrosion resistance; the corrosion potential of copper OTS SAMs protection increased by about 1.02 V, while the corrosion current density decreased to 0.59 μA/cm2. The corrosion rate is minimized and flattened and can reach 9.2% while the inhibition efficiency reached 95.4%, when the corrosion inhibitor has concentration of 40 ppm. |
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id | doaj-art-3b5bf202e8674771af6f7d9494b8b549 |
institution | Kabale University |
issn | 1687-8760 1687-8779 |
language | English |
publishDate | 2017-01-01 |
publisher | Wiley |
record_format | Article |
series | International Journal of Analytical Chemistry |
spelling | doaj-art-3b5bf202e8674771af6f7d9494b8b5492025-02-03T01:22:30ZengWileyInternational Journal of Analytical Chemistry1687-87601687-87792017-01-01201710.1155/2017/49757144975714Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper SurfaceXue Shouqing0Liu Xiaohui1Institute of Fine Chemicals, Heze University, Heze, Shandong 274015, ChinaDepartment of Chemistry and Chemical Engineering, Heze University, Heze, Shandong 274015, ChinaThe self-assembled monolayer (SAM) was prepared using octadecyl trichlorosilane (OTS) in distilled solution on the copper surface. The effect of inhibitor concentration on the rate of inhibition efficiency and corrosion rate in corrosion medium on copper by using polarization curves, electrochemical impedance spectroscopy (EIS), scanning electron microscope (SEM) was studied. The results showed that OTS SAMs exhibit the better corrosion resistance; the corrosion potential of copper OTS SAMs protection increased by about 1.02 V, while the corrosion current density decreased to 0.59 μA/cm2. The corrosion rate is minimized and flattened and can reach 9.2% while the inhibition efficiency reached 95.4%, when the corrosion inhibitor has concentration of 40 ppm.http://dx.doi.org/10.1155/2017/4975714 |
spellingShingle | Xue Shouqing Liu Xiaohui Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface International Journal of Analytical Chemistry |
title | Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface |
title_full | Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface |
title_fullStr | Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface |
title_full_unstemmed | Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface |
title_short | Preparation and Anticorrosion of Octadecyl Trichlorosilane SAMs for Copper Surface |
title_sort | preparation and anticorrosion of octadecyl trichlorosilane sams for copper surface |
url | http://dx.doi.org/10.1155/2017/4975714 |
work_keys_str_mv | AT xueshouqing preparationandanticorrosionofoctadecyltrichlorosilanesamsforcoppersurface AT liuxiaohui preparationandanticorrosionofoctadecyltrichlorosilanesamsforcoppersurface |