Metrological assessment of TDR performance for measurement of potassium concentration in soil solution

ABSTRACT Despite the growing use of the time domain reflectometry (TDR) technique to monitoring ions in the soil solution, there are few studies that provide insight into measurement error. To overcome this lack of information, a methodology, based on the central limit theorem error, was used to qua...

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Main Authors: Isaac de M. Ponciano, Jarbas H. de Miranda, Richard A. Cooke, Vanessa de F. Grah, Alisson J. P. da Silva
Format: Article
Language:English
Published: Universidade Federal de Campina Grande 2016-04-01
Series:Revista Brasileira de Engenharia Agrícola e Ambiental
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Online Access:http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662016000400343&lng=en&tlng=en
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author Isaac de M. Ponciano
Jarbas H. de Miranda
Richard A. Cooke
Vanessa de F. Grah
Alisson J. P. da Silva
author_facet Isaac de M. Ponciano
Jarbas H. de Miranda
Richard A. Cooke
Vanessa de F. Grah
Alisson J. P. da Silva
author_sort Isaac de M. Ponciano
collection DOAJ
description ABSTRACT Despite the growing use of the time domain reflectometry (TDR) technique to monitoring ions in the soil solution, there are few studies that provide insight into measurement error. To overcome this lack of information, a methodology, based on the central limit theorem error, was used to quantify the uncertainty associated with using the technique to estimate potassium ion concentration in two soil types. Mathematical models based on electrical conductivity and soil moisture derived from TDR readings were used to estimate potassium concentration, and the results were compared to potassium concentration determined by flame spectrophotometry. It was possible to correct for random and systematic errors associated with TDR readings, significantly increasing the accuracy of the potassium estimation methodology. However, a single TDR reading can lead to an error of up to ± 18.84 mg L-1 K+ in soil solution (0 to 3 dS m-1), with a 95.42% degree of confidence, for a loamy sand soil; and an error of up to ± 12.50 mg L-1 of K+ (0 to 2.5 dS m-1) in soil solution, with a 95.06% degree of confidence, for a sandy clay soil.
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spelling doaj-art-3ae3a0d3c35c44b3a4b135d10bbeb51f2025-08-20T02:16:22ZengUniversidade Federal de Campina GrandeRevista Brasileira de Engenharia Agrícola e Ambiental1807-19292016-04-0120434334910.1590/1807-1929/agriambi.v20n4p343-349S1415-43662016000400343Metrological assessment of TDR performance for measurement of potassium concentration in soil solutionIsaac de M. PoncianoJarbas H. de MirandaRichard A. CookeVanessa de F. GrahAlisson J. P. da SilvaABSTRACT Despite the growing use of the time domain reflectometry (TDR) technique to monitoring ions in the soil solution, there are few studies that provide insight into measurement error. To overcome this lack of information, a methodology, based on the central limit theorem error, was used to quantify the uncertainty associated with using the technique to estimate potassium ion concentration in two soil types. Mathematical models based on electrical conductivity and soil moisture derived from TDR readings were used to estimate potassium concentration, and the results were compared to potassium concentration determined by flame spectrophotometry. It was possible to correct for random and systematic errors associated with TDR readings, significantly increasing the accuracy of the potassium estimation methodology. However, a single TDR reading can lead to an error of up to ± 18.84 mg L-1 K+ in soil solution (0 to 3 dS m-1), with a 95.42% degree of confidence, for a loamy sand soil; and an error of up to ± 12.50 mg L-1 of K+ (0 to 2.5 dS m-1) in soil solution, with a 95.06% degree of confidence, for a sandy clay soil.http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662016000400343&lng=en&tlng=enteorema do limite centralinstrumentaçãocondutividade elétrica
spellingShingle Isaac de M. Ponciano
Jarbas H. de Miranda
Richard A. Cooke
Vanessa de F. Grah
Alisson J. P. da Silva
Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
Revista Brasileira de Engenharia Agrícola e Ambiental
teorema do limite central
instrumentação
condutividade elétrica
title Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
title_full Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
title_fullStr Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
title_full_unstemmed Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
title_short Metrological assessment of TDR performance for measurement of potassium concentration in soil solution
title_sort metrological assessment of tdr performance for measurement of potassium concentration in soil solution
topic teorema do limite central
instrumentação
condutividade elétrica
url http://www.scielo.br/scielo.php?script=sci_arttext&pid=S1415-43662016000400343&lng=en&tlng=en
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