Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand
In this work, we present the design and synthesis of the <i>bis</i>thiosemicarbazone ligand H<sub>3</sub>L<sup>Me</sup> by means of an iminic condensation reaction between 2-hydroxyisophthalaldehyde and 4-methyl-3-thiosemicarbazide. This ligand is bicompartmental,...
Saved in:
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2023-11-01
|
| Series: | Chemistry Proceedings |
| Subjects: | |
| Online Access: | https://www.mdpi.com/2673-4583/14/1/39 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850241250900312064 |
|---|---|
| author | Isabel Velo-Heleno Sandra Fernández-Fariña Uxía Barreiro-Sisto Laura Rodríguez-Silva Rosa Pedrido |
| author_facet | Isabel Velo-Heleno Sandra Fernández-Fariña Uxía Barreiro-Sisto Laura Rodríguez-Silva Rosa Pedrido |
| author_sort | Isabel Velo-Heleno |
| collection | DOAJ |
| description | In this work, we present the design and synthesis of the <i>bis</i>thiosemicarbazone ligand H<sub>3</sub>L<sup>Me</sup> by means of an iminic condensation reaction between 2-hydroxyisophthalaldehyde and 4-methyl-3-thiosemicarbazide. This ligand is bicompartmental, pentadentate [N<sub>2</sub>S<sub>2</sub>O] and potentially trianionic. The presence of a spacer constituted by a phenol group facilitates the coordination of transition metal ions, giving rise to a great variety of structures. To confirm the purity of the ligand, different characterization techniques were employed, including elemental analysis, mass spectrometry, infrared spectroscopy, and nuclear magnetic resonance. The acquisition of suitable crystals of H<sub>3</sub>L<sup>Me</sup> allowed us to analyze its structure through X-ray diffraction studies. |
| format | Article |
| id | doaj-art-3ab897eaee0b4748b8154151a14c6817 |
| institution | OA Journals |
| issn | 2673-4583 |
| language | English |
| publishDate | 2023-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Chemistry Proceedings |
| spelling | doaj-art-3ab897eaee0b4748b8154151a14c68172025-08-20T02:00:39ZengMDPI AGChemistry Proceedings2673-45832023-11-011413910.3390/ecsoc-27-16093Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone LigandIsabel Velo-Heleno0Sandra Fernández-Fariña1Uxía Barreiro-Sisto2Laura Rodríguez-Silva3Rosa Pedrido4Suprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Ciencias, Universidade de Santiago de Compostela, Campus Terra, 27002 Lugo, SpainSuprabioin Lab, Departamento de Química Inorgánica, Facultade de Química, Universidade de Santiago de Compostela, Campus Vida, 15782 Santiago de Compostela, SpainIn this work, we present the design and synthesis of the <i>bis</i>thiosemicarbazone ligand H<sub>3</sub>L<sup>Me</sup> by means of an iminic condensation reaction between 2-hydroxyisophthalaldehyde and 4-methyl-3-thiosemicarbazide. This ligand is bicompartmental, pentadentate [N<sub>2</sub>S<sub>2</sub>O] and potentially trianionic. The presence of a spacer constituted by a phenol group facilitates the coordination of transition metal ions, giving rise to a great variety of structures. To confirm the purity of the ligand, different characterization techniques were employed, including elemental analysis, mass spectrometry, infrared spectroscopy, and nuclear magnetic resonance. The acquisition of suitable crystals of H<sub>3</sub>L<sup>Me</sup> allowed us to analyze its structure through X-ray diffraction studies.https://www.mdpi.com/2673-4583/14/1/39ligand<i>bis</i>thiosemicarbazonecoordination chemistry |
| spellingShingle | Isabel Velo-Heleno Sandra Fernández-Fariña Uxía Barreiro-Sisto Laura Rodríguez-Silva Rosa Pedrido Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand Chemistry Proceedings ligand <i>bis</i>thiosemicarbazone coordination chemistry |
| title | Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand |
| title_full | Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand |
| title_fullStr | Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand |
| title_full_unstemmed | Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand |
| title_short | Design, Synthesis and Characterization of a Bicompartmental <i>bis</i>thiosemicarbazone Ligand |
| title_sort | design synthesis and characterization of a bicompartmental i bis i thiosemicarbazone ligand |
| topic | ligand <i>bis</i>thiosemicarbazone coordination chemistry |
| url | https://www.mdpi.com/2673-4583/14/1/39 |
| work_keys_str_mv | AT isabelveloheleno designsynthesisandcharacterizationofabicompartmentalibisithiosemicarbazoneligand AT sandrafernandezfarina designsynthesisandcharacterizationofabicompartmentalibisithiosemicarbazoneligand AT uxiabarreirosisto designsynthesisandcharacterizationofabicompartmentalibisithiosemicarbazoneligand AT laurarodriguezsilva designsynthesisandcharacterizationofabicompartmentalibisithiosemicarbazoneligand AT rosapedrido designsynthesisandcharacterizationofabicompartmentalibisithiosemicarbazoneligand |