Tris(2,2'-bipyridine-4,4'-dicarboxylic acid)ruthenium(II), a Redox Sensitizer Affording Water Oxidation to Oxygen in the Absence of Heterogeneous Catalyst

Tris(2,2'-bipyridine-4,4'-dicarboxylic acid)ruthenium(II), a Redox Sensitizer Affording Water Oxidation to Oxygen in the Absence of Heterogeneous Catalyst

Oxygen is generated under visible light illumination of highly acidic (0.5 M H2SO4) aqueous solutions of tris(2,2-bipyridine-4,4'-dicarboxylic acid)ruthenium(II) containing S2O82⊖ as electron acceptor in the absence of heterogeneous redox catalyst. An autocatalytic reaction mechanism is propos...

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Bibliographic Details
Main Authors:	Jean Desilvestro, Dung Duonghong, Mieke Kleijn, Michael Grätzel
Format:	Article
Language:	deu
Published:	Swiss Chemical Society 1985-04-01
Series:	CHIMIA
Online Access:	https://www.chimia.ch/chimia/article/view/9657
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