Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette

Abstract Most commercial systems for ultraviolet-visible (UV–VIS), Fourier-transform infrared, circular dichroism (CD), and fluorescence spectroscopies are designed for measurement of liquid samples. Moreover, adapters enabling the measurement of solid samples are expensive or unavailable for most c...

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Main Authors: Jacques Doumani, Henry Mansfield, Andrey Baydin, Somesh Sasmal, Mario El Tahchi, Weilu Gao, Junichiro Kono
Format: Article
Language:English
Published: Nature Portfolio 2025-02-01
Series:Scientific Reports
Subjects:
Online Access:https://doi.org/10.1038/s41598-025-88611-2
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author Jacques Doumani
Henry Mansfield
Andrey Baydin
Somesh Sasmal
Mario El Tahchi
Weilu Gao
Junichiro Kono
author_facet Jacques Doumani
Henry Mansfield
Andrey Baydin
Somesh Sasmal
Mario El Tahchi
Weilu Gao
Junichiro Kono
author_sort Jacques Doumani
collection DOAJ
description Abstract Most commercial systems for ultraviolet-visible (UV–VIS), Fourier-transform infrared, circular dichroism (CD), and fluorescence spectroscopies are designed for measurement of liquid samples. Moreover, adapters enabling the measurement of solid samples are expensive or unavailable for most commercial instruments. Consequently, there is a significant need for solid sample adapters that enable measurement of both liquid and solid samples with a single system. Here, we report two versions of a solid sample adapter cuvette that can be used in most commercial spectroscopy instruments designed for transmission measurement of liquid samples. One version is designed for techniques that do not require changing the sample orientation, and the other allows easy sample rotation. We successfully fabricated these cuvettes by 3D printing with both fused deposition modeling and stereolithography and demonstrated how they enable us to study the optical properties of macroscopic films of aligned carbon nanotubes by performing UV–VIS and CD spectroscopy measurements with the cuvettes. These 3D printed cuvettes and their implementation will help enable a wide range of experiments at a low cost.
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spelling doaj-art-3a6164cd00ef4f25be7aff3d85a5648b2025-08-20T02:15:08ZengNature PortfolioScientific Reports2045-23222025-02-011511710.1038/s41598-025-88611-2Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvetteJacques Doumani0Henry Mansfield1Andrey Baydin2Somesh Sasmal3Mario El Tahchi4Weilu Gao5Junichiro Kono6Department of Electrical and Computer Engineering, Rice UniversityDepartment of Electrical and Computer Engineering, Rice UniversityDepartment of Electrical and Computer Engineering, Rice UniversityDepartment of Materials Science and NanoEngineering, Rice UniversityDepartment of Physics, Lebanese UniversityDepartment of Electrical and Computer Engineering, The University of UtahDepartment of Electrical and Computer Engineering, Rice UniversityAbstract Most commercial systems for ultraviolet-visible (UV–VIS), Fourier-transform infrared, circular dichroism (CD), and fluorescence spectroscopies are designed for measurement of liquid samples. Moreover, adapters enabling the measurement of solid samples are expensive or unavailable for most commercial instruments. Consequently, there is a significant need for solid sample adapters that enable measurement of both liquid and solid samples with a single system. Here, we report two versions of a solid sample adapter cuvette that can be used in most commercial spectroscopy instruments designed for transmission measurement of liquid samples. One version is designed for techniques that do not require changing the sample orientation, and the other allows easy sample rotation. We successfully fabricated these cuvettes by 3D printing with both fused deposition modeling and stereolithography and demonstrated how they enable us to study the optical properties of macroscopic films of aligned carbon nanotubes by performing UV–VIS and CD spectroscopy measurements with the cuvettes. These 3D printed cuvettes and their implementation will help enable a wide range of experiments at a low cost.https://doi.org/10.1038/s41598-025-88611-2CuvetteSpectrophotometryCircular DichroismCarbon Nanotubes
spellingShingle Jacques Doumani
Henry Mansfield
Andrey Baydin
Somesh Sasmal
Mario El Tahchi
Weilu Gao
Junichiro Kono
Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
Scientific Reports
Cuvette
Spectrophotometry
Circular Dichroism
Carbon Nanotubes
title Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
title_full Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
title_fullStr Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
title_full_unstemmed Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
title_short Enabling solid sample analysis in liquid spectrophotometers with a 3D-printed cuvette
title_sort enabling solid sample analysis in liquid spectrophotometers with a 3d printed cuvette
topic Cuvette
Spectrophotometry
Circular Dichroism
Carbon Nanotubes
url https://doi.org/10.1038/s41598-025-88611-2
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