Quantifying Cell-to-Cell Variations in Lithium Ion Batteries

Lithium ion batteries have conventionally been manufactured in small capacities but large volumes for consumer electronics applications. More recently, the industry has seen a surge in the individual cell capacities, as well as the number of cells used to build modules and packs. Reducing cell-to-ce...

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Main Authors: Shriram Santhanagopalan, Ralph E. White
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Electrochemistry
Online Access:http://dx.doi.org/10.1155/2012/395838
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author Shriram Santhanagopalan
Ralph E. White
author_facet Shriram Santhanagopalan
Ralph E. White
author_sort Shriram Santhanagopalan
collection DOAJ
description Lithium ion batteries have conventionally been manufactured in small capacities but large volumes for consumer electronics applications. More recently, the industry has seen a surge in the individual cell capacities, as well as the number of cells used to build modules and packs. Reducing cell-to-cell and lot-to-lot variations has been identified as one of the major means to reduce the rejection rate when building the packs as well as to improve pack durability. The tight quality control measures have been passed on from the pack manufactures to the companies building the individual cells and in turn to the components. This paper identifies a quantitative procedure utilizing impedance spectroscopy, a commonly used tool, to determine the effects of material variability on the cell performance, to compare the relative importance of uncertainties in the component properties, and to suggest a rational procedure to set quality control specifications for the various components of a cell, that will reduce cell-to-cell variability, while preventing undue requirements on uniformity that often result in excessive cost of manufacturing but have a limited impact on the cells' performance.
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spelling doaj-art-3a283da69d974d799ded0580633ea1362025-02-03T07:24:53ZengWileyInternational Journal of Electrochemistry2090-35292090-35372012-01-01201210.1155/2012/395838395838Quantifying Cell-to-Cell Variations in Lithium Ion BatteriesShriram Santhanagopalan0Ralph E. White1National Renewable Energy Laboratory, Golden, CO 80401, USAUniversity of South Carolina, Columbia, SC 29204, USALithium ion batteries have conventionally been manufactured in small capacities but large volumes for consumer electronics applications. More recently, the industry has seen a surge in the individual cell capacities, as well as the number of cells used to build modules and packs. Reducing cell-to-cell and lot-to-lot variations has been identified as one of the major means to reduce the rejection rate when building the packs as well as to improve pack durability. The tight quality control measures have been passed on from the pack manufactures to the companies building the individual cells and in turn to the components. This paper identifies a quantitative procedure utilizing impedance spectroscopy, a commonly used tool, to determine the effects of material variability on the cell performance, to compare the relative importance of uncertainties in the component properties, and to suggest a rational procedure to set quality control specifications for the various components of a cell, that will reduce cell-to-cell variability, while preventing undue requirements on uniformity that often result in excessive cost of manufacturing but have a limited impact on the cells' performance.http://dx.doi.org/10.1155/2012/395838
spellingShingle Shriram Santhanagopalan
Ralph E. White
Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
International Journal of Electrochemistry
title Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
title_full Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
title_fullStr Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
title_full_unstemmed Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
title_short Quantifying Cell-to-Cell Variations in Lithium Ion Batteries
title_sort quantifying cell to cell variations in lithium ion batteries
url http://dx.doi.org/10.1155/2012/395838
work_keys_str_mv AT shriramsanthanagopalan quantifyingcelltocellvariationsinlithiumionbatteries
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