Synthesis and Structural Characterization of a Metal Cluster and a Coordination Polymer Based on the [Mn6(μ4-O)2]10+ Unit
A new 1-D coordination polymer {[Mn6O2(O2CMe)10(H2O)4]⋅2.5H2O}∞ (1 ⋅2.5H2O)∞ and the cluster [Mn6O2(O2(O2CPh)10 (py)2(MeCN)(H2O)]⋅2MeCN (2 ⋅2MeCN) are reported. Both compounds were synthesized by room temperature reactions of [Mn3(𝜇3-O)(O2CR)6(L)2(L)] (R = Me, L = L = py, (1 ⋅2.5H2O)∞; R = Ph, L =...
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| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
Wiley
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/367128 |
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