Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand
The New Schiff base ligand 4,4'-[(1,1'-Biphenyl)-4,4'-diyl,bis-(azo)-bis-[2-Salicylidene thiosemicarbazide](HL)(BASTSC)and its complexes with Co(II), Ni(II), and Cu(II) were prepared and characterized by elemental analysis, electronic, FTIR, magnetic susceptibility measurements. The...
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University of Baghdad, College of Science for Women
2014-03-01
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| Series: | مجلة بغداد للعلوم |
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| Online Access: | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1546 |
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| author | Baghdad Science Journal |
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| description | The New Schiff base ligand 4,4'-[(1,1'-Biphenyl)-4,4'-diyl,bis-(azo)-bis-[2-Salicylidene thiosemicarbazide](HL)(BASTSC)and its complexes with Co(II), Ni(II), and Cu(II) were prepared and characterized by elemental analysis, electronic, FTIR, magnetic susceptibility measurements. The analytical and spectral data showed, the stiochiometry of the complexes to be 1:1 (metal: ligand). FTIR spectral data showed that the ligand behaves as dibasic hexadentate molecule with (N, S, O) donor sequence towards metal ions. The octahedral geometry for Co(II), Ni(II), and Cu(II) complexes and non electrolyte behavior was suggested according to the analysis data. |
| format | Article |
| id | doaj-art-3928962ff72b4532aa619be995f85e2e |
| institution | Kabale University |
| issn | 2078-8665 2411-7986 |
| language | English |
| publishDate | 2014-03-01 |
| publisher | University of Baghdad, College of Science for Women |
| record_format | Article |
| series | مجلة بغداد للعلوم |
| spelling | doaj-art-3928962ff72b4532aa619be995f85e2e2025-08-20T03:56:13ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862014-03-0111110.21123/bsj.11.1.158-165Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base LigandBaghdad Science JournalThe New Schiff base ligand 4,4'-[(1,1'-Biphenyl)-4,4'-diyl,bis-(azo)-bis-[2-Salicylidene thiosemicarbazide](HL)(BASTSC)and its complexes with Co(II), Ni(II), and Cu(II) were prepared and characterized by elemental analysis, electronic, FTIR, magnetic susceptibility measurements. The analytical and spectral data showed, the stiochiometry of the complexes to be 1:1 (metal: ligand). FTIR spectral data showed that the ligand behaves as dibasic hexadentate molecule with (N, S, O) donor sequence towards metal ions. The octahedral geometry for Co(II), Ni(II), and Cu(II) complexes and non electrolyte behavior was suggested according to the analysis data.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1546Schiff- base; Metal chelate complexes, octahedral geometry. |
| spellingShingle | Baghdad Science Journal Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand مجلة بغداد للعلوم Schiff- base; Metal chelate complexes, octahedral geometry. |
| title | Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand |
| title_full | Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand |
| title_fullStr | Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand |
| title_full_unstemmed | Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand |
| title_short | Preparation and Characterization of Some Transition Metal Complexes with ( N ,S ,O) New Schiff Base Ligand |
| title_sort | preparation and characterization of some transition metal complexes with n s o new schiff base ligand |
| topic | Schiff- base; Metal chelate complexes, octahedral geometry. |
| url | http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/1546 |
| work_keys_str_mv | AT baghdadsciencejournal preparationandcharacterizationofsometransitionmetalcomplexeswithnsonewschiffbaseligand |