Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries

Highlights A double-layered protective film based on zinc-based coordination compound and ZnF2-rich solid electrolyte interphase layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The double-layered architecture can effectively modulate...

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Main Authors: Chengwang Zhou, Zhezheng Ding, Shengzhe Ying, Hao Jiang, Yan Wang, Timing Fang, You Zhang, Bing Sun, Xiao Tang, Xiaomin Liu
Format: Article
Language:English
Published: SpringerOpen 2024-11-01
Series:Nano-Micro Letters
Subjects:
Online Access:https://doi.org/10.1007/s40820-024-01551-w
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author Chengwang Zhou
Zhezheng Ding
Shengzhe Ying
Hao Jiang
Yan Wang
Timing Fang
You Zhang
Bing Sun
Xiao Tang
Xiaomin Liu
author_facet Chengwang Zhou
Zhezheng Ding
Shengzhe Ying
Hao Jiang
Yan Wang
Timing Fang
You Zhang
Bing Sun
Xiao Tang
Xiaomin Liu
author_sort Chengwang Zhou
collection DOAJ
description Highlights A double-layered protective film based on zinc-based coordination compound and ZnF2-rich solid electrolyte interphase layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The double-layered architecture can effectively modulate Zn2+ flux and suppress the zinc dendrite growth, thus facilitating the uniform zinc deposition. The as-developed zinc-(dual) halogen batteries based on double-layered protective film can present high areal capacity and satisfactory cycling stability.
format Article
id doaj-art-390f20ad0e964a9e9dbbde3cb15440f9
institution Kabale University
issn 2311-6706
2150-5551
language English
publishDate 2024-11-01
publisher SpringerOpen
record_format Article
series Nano-Micro Letters
spelling doaj-art-390f20ad0e964a9e9dbbde3cb15440f92025-08-20T03:43:01ZengSpringerOpenNano-Micro Letters2311-67062150-55512024-11-0117111710.1007/s40820-024-01551-wElectrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen BatteriesChengwang Zhou0Zhezheng Ding1Shengzhe Ying2Hao Jiang3Yan Wang4Timing Fang5You Zhang6Bing Sun7Xiao Tang8Xiaomin Liu9School of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversityCentre for Clean Energy Technology, School of Mathematical and Physical Sciences, Faculty of Science, University of Technology SydneySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversitySchool of Textiles and Clothing, School of Chemistry and Chemical Engineering, Qingdao UniversityHighlights A double-layered protective film based on zinc-based coordination compound and ZnF2-rich solid electrolyte interphase layer has been successfully fabricated on the zinc metal anode via electrode/electrolyte synergistic optimization. The double-layered architecture can effectively modulate Zn2+ flux and suppress the zinc dendrite growth, thus facilitating the uniform zinc deposition. The as-developed zinc-(dual) halogen batteries based on double-layered protective film can present high areal capacity and satisfactory cycling stability.https://doi.org/10.1007/s40820-024-01551-wZn metal anodesDouble-layered protective filmElectrode/electrolyte optimizationAqueous zinc-(dual) halogen batteries
spellingShingle Chengwang Zhou
Zhezheng Ding
Shengzhe Ying
Hao Jiang
Yan Wang
Timing Fang
You Zhang
Bing Sun
Xiao Tang
Xiaomin Liu
Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
Nano-Micro Letters
Zn metal anodes
Double-layered protective film
Electrode/electrolyte optimization
Aqueous zinc-(dual) halogen batteries
title Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
title_full Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
title_fullStr Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
title_full_unstemmed Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
title_short Electrode/Electrolyte Optimization-Induced Double-Layered Architecture for High-Performance Aqueous Zinc-(Dual) Halogen Batteries
title_sort electrode electrolyte optimization induced double layered architecture for high performance aqueous zinc dual halogen batteries
topic Zn metal anodes
Double-layered protective film
Electrode/electrolyte optimization
Aqueous zinc-(dual) halogen batteries
url https://doi.org/10.1007/s40820-024-01551-w
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