Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils
Ultrathin electrolytic copper foils with a thickness of 6 μm were prepared by a test machine using copper sulfate electrolyte with gelatin, hydroxyethyl cellulose (HEC), and sulfonic acid-containing organics as additives. The effects of four sulfonic acid-containing organic additives, sodium 3-merca...
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| Language: | English |
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MDPI AG
2025-01-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/30/2/229 |
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| author | Wei Wang Jun Tao Kaiwen Tong Zhiqiang Xu Fuqi Zhong Jianping Dong Yanxia Chen Zhengbing Fu Caiqin Qin |
| author_facet | Wei Wang Jun Tao Kaiwen Tong Zhiqiang Xu Fuqi Zhong Jianping Dong Yanxia Chen Zhengbing Fu Caiqin Qin |
| author_sort | Wei Wang |
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| description | Ultrathin electrolytic copper foils with a thickness of 6 μm were prepared by a test machine using copper sulfate electrolyte with gelatin, hydroxyethyl cellulose (HEC), and sulfonic acid-containing organics as additives. The effects of four sulfonic acid-containing organic additives, sodium 3-mercaptopropanesulfonate (MPS), bis-(sodium sulfopropyl)-disulfide (SPS), sodium 3-[[(dimethylamino)thioxomethyl]thio]propanesulfonate (DPS), and sodium 3-((4,5-dihydrothiazol-2-yl)thio)propane-1-sulfonate (TPS), on the physical property of copper foils were investigated. The results show that all these additives can effectively improve the gloss and tensile strength of electrolytic copper foil, and the texture coefficients of Cu(111) selectivity increase. The synergistic use of HEC and TPS can effectively reduce the pinholes of copper foil. |
| format | Article |
| id | doaj-art-38d2d39732b040dc9c59eb8b76ffc5b8 |
| institution | Kabale University |
| issn | 1420-3049 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-38d2d39732b040dc9c59eb8b76ffc5b82025-01-24T13:43:11ZengMDPI AGMolecules1420-30492025-01-0130222910.3390/molecules30020229Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper FoilsWei Wang0Jun Tao1Kaiwen Tong2Zhiqiang Xu3Fuqi Zhong4Jianping Dong5Yanxia Chen6Zhengbing Fu7Caiqin Qin8Jiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaJiangxi XinboRui Technology Co., Yingtan 335000, ChinaSchool of Chemistry and Materials Science, Hubei Engineering University, Xiaogan 432000, ChinaUltrathin electrolytic copper foils with a thickness of 6 μm were prepared by a test machine using copper sulfate electrolyte with gelatin, hydroxyethyl cellulose (HEC), and sulfonic acid-containing organics as additives. The effects of four sulfonic acid-containing organic additives, sodium 3-mercaptopropanesulfonate (MPS), bis-(sodium sulfopropyl)-disulfide (SPS), sodium 3-[[(dimethylamino)thioxomethyl]thio]propanesulfonate (DPS), and sodium 3-((4,5-dihydrothiazol-2-yl)thio)propane-1-sulfonate (TPS), on the physical property of copper foils were investigated. The results show that all these additives can effectively improve the gloss and tensile strength of electrolytic copper foil, and the texture coefficients of Cu(111) selectivity increase. The synergistic use of HEC and TPS can effectively reduce the pinholes of copper foil.https://www.mdpi.com/1420-3049/30/2/229sulfonated organicshydroxyethyl celluloseelectrolytic copper foiltensile strengthpinhole |
| spellingShingle | Wei Wang Jun Tao Kaiwen Tong Zhiqiang Xu Fuqi Zhong Jianping Dong Yanxia Chen Zhengbing Fu Caiqin Qin Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils Molecules sulfonated organics hydroxyethyl cellulose electrolytic copper foil tensile strength pinhole |
| title | Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils |
| title_full | Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils |
| title_fullStr | Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils |
| title_full_unstemmed | Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils |
| title_short | Effects of Four Sulfonate-Containing Additives and Hydroxyethyl Cellulose on the Properties of Electrolytic Copper Foils |
| title_sort | effects of four sulfonate containing additives and hydroxyethyl cellulose on the properties of electrolytic copper foils |
| topic | sulfonated organics hydroxyethyl cellulose electrolytic copper foil tensile strength pinhole |
| url | https://www.mdpi.com/1420-3049/30/2/229 |
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