Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films

This study evaluates the potential of natural and thermally modified starches from Kazakhstan, including cassava, potato, wheat, corn, pea, and rice, for the production of biodegradable films. Key physicochemical properties were analyzed using Fourier Transform Infrared Spectroscopy (FTIR), Differen...

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Main Authors: Marat Muratkhan, Kakimova Zhainagul, Yernaz Yermekov, Kamanova Svetlana, Dana Toimbayeva, Indira Temirova, Kiykbay Amirsana, Dina Khamitova, Yerlan Zharykbasov, Adilet Sugirbay, Saduakhasova Saule, Gulnazym Ospankulova
Format: Article
Language:English
Published: MDPI AG 2025-04-01
Series:Applied Sciences
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Online Access:https://www.mdpi.com/2076-3417/15/7/3938
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author Marat Muratkhan
Kakimova Zhainagul
Yernaz Yermekov
Kamanova Svetlana
Dana Toimbayeva
Indira Temirova
Kiykbay Amirsana
Dina Khamitova
Yerlan Zharykbasov
Adilet Sugirbay
Saduakhasova Saule
Gulnazym Ospankulova
author_facet Marat Muratkhan
Kakimova Zhainagul
Yernaz Yermekov
Kamanova Svetlana
Dana Toimbayeva
Indira Temirova
Kiykbay Amirsana
Dina Khamitova
Yerlan Zharykbasov
Adilet Sugirbay
Saduakhasova Saule
Gulnazym Ospankulova
author_sort Marat Muratkhan
collection DOAJ
description This study evaluates the potential of natural and thermally modified starches from Kazakhstan, including cassava, potato, wheat, corn, pea, and rice, for the production of biodegradable films. Key physicochemical properties were analyzed using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and a Rapid Visco Analyzer (RVA). The results show that cassava starch, with the highest magnesium content (43.07 mg/100 g) and peak viscosity (1300 RVU), exhibits superior mechanical strength and elasticity, making it ideal for durable agricultural films. Corn starch, with high crystallinity and moderate viscosity (1150 RVU), exhibits excellent stability for long-term applications. In contrast, wheat and rice starches, with lower viscosities (750 and 650 RVU, respectively) and high biodegradability, are more suitable for short-term eco-friendly applications. Modification processes improved moisture resistance and reduced retrogradation tendencies, particularly in cassava and corn starches. SEM analysis revealed that modified starches from cassava and corn have dense and uniform surface structures, enhancing film durability and flexibility. These findings highlight the potential of utilizing Kazakhstan’s starch resources for localized biodegradable film production, reducing reliance on imports while promoting sustainable agriculture.
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spelling doaj-art-38690380f5804dfcbbc752d459d766b42025-08-20T03:06:31ZengMDPI AGApplied Sciences2076-34172025-04-01157393810.3390/app15073938Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable FilmsMarat Muratkhan0Kakimova Zhainagul1Yernaz Yermekov2Kamanova Svetlana3Dana Toimbayeva4Indira Temirova5Kiykbay Amirsana6Dina Khamitova7Yerlan Zharykbasov8Adilet Sugirbay9Saduakhasova Saule10Gulnazym Ospankulova11Department of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Production Technology and Biotechnology, The Engineering–Technological Faculty, Shakarim University, Glinka 20A, Semey 071412, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Production Technology and Biotechnology, The Engineering–Technological Faculty, Shakarim University, Glinka 20A, Semey 071412, KazakhstanDepartment of Food Production Technology and Biotechnology, The Engineering–Technological Faculty, Shakarim University, Glinka 20A, Semey 071412, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanDepartment of Food Technology and Processing Products, Technical Faculty, Saken Seifullin Kazakh Agrotechnical Research University, Zhenis Avenue, 62, Astana 010011, KazakhstanThis study evaluates the potential of natural and thermally modified starches from Kazakhstan, including cassava, potato, wheat, corn, pea, and rice, for the production of biodegradable films. Key physicochemical properties were analyzed using Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimetry (DSC), X-ray diffraction (XRD), Scanning Electron Microscopy (SEM), and a Rapid Visco Analyzer (RVA). The results show that cassava starch, with the highest magnesium content (43.07 mg/100 g) and peak viscosity (1300 RVU), exhibits superior mechanical strength and elasticity, making it ideal for durable agricultural films. Corn starch, with high crystallinity and moderate viscosity (1150 RVU), exhibits excellent stability for long-term applications. In contrast, wheat and rice starches, with lower viscosities (750 and 650 RVU, respectively) and high biodegradability, are more suitable for short-term eco-friendly applications. Modification processes improved moisture resistance and reduced retrogradation tendencies, particularly in cassava and corn starches. SEM analysis revealed that modified starches from cassava and corn have dense and uniform surface structures, enhancing film durability and flexibility. These findings highlight the potential of utilizing Kazakhstan’s starch resources for localized biodegradable film production, reducing reliance on imports while promoting sustainable agriculture.https://www.mdpi.com/2076-3417/15/7/3938biodegradable filmsnatural starchesstarch modificationmechanical strengththermal stabilitysustainable agriculture
spellingShingle Marat Muratkhan
Kakimova Zhainagul
Yernaz Yermekov
Kamanova Svetlana
Dana Toimbayeva
Indira Temirova
Kiykbay Amirsana
Dina Khamitova
Yerlan Zharykbasov
Adilet Sugirbay
Saduakhasova Saule
Gulnazym Ospankulova
Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
Applied Sciences
biodegradable films
natural starches
starch modification
mechanical strength
thermal stability
sustainable agriculture
title Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
title_full Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
title_fullStr Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
title_full_unstemmed Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
title_short Comparable Analysis of Natural and Modified Starches from Kazakhstan: Physicochemical Properties, Applications, and Insights on Biodegradable Films
title_sort comparable analysis of natural and modified starches from kazakhstan physicochemical properties applications and insights on biodegradable films
topic biodegradable films
natural starches
starch modification
mechanical strength
thermal stability
sustainable agriculture
url https://www.mdpi.com/2076-3417/15/7/3938
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