Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation

A series of oxovanadium(IV) complexes of the type [VO(mac)]SO4 (where mac = tetraazamacrocyclic ligands derived from condensation of 4,4,4-trifluro-1-(2-furyl)-1,3-butanedione or 4,4,4-trifluro-1-(2-thenyl)-1,3-butanedione with p-phenylenediamine and their reaction with β-diketones) have been prepa...

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Main Authors: A. K. Yadava, H. S. Yadav, Sanjay Singh, U. S. Yadav, D. P. Rao
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/689518
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author A. K. Yadava
H. S. Yadav
Sanjay Singh
U. S. Yadav
D. P. Rao
author_facet A. K. Yadava
H. S. Yadav
Sanjay Singh
U. S. Yadav
D. P. Rao
author_sort A. K. Yadava
collection DOAJ
description A series of oxovanadium(IV) complexes of the type [VO(mac)]SO4 (where mac = tetraazamacrocyclic ligands derived from condensation of 4,4,4-trifluro-1-(2-furyl)-1,3-butanedione or 4,4,4-trifluro-1-(2-thenyl)-1,3-butanedione with p-phenylenediamine and their reaction with β-diketones) have been prepared using oxometal ion of vanadium as kinetic template. These complexes have been ascertained by electrical conductance, magnetic moment, elemental analyses, infrared, e.s.r. and electronic spectral data. All the oxovanadium(IV) complexes are five-coordinate ones.
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institution OA Journals
issn 2090-9063
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publishDate 2013-01-01
publisher Wiley
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spelling doaj-art-37e9983b44e242e88b711c72057fbbaf2025-08-20T02:08:00ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/689518689518Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) CationA. K. Yadava0H. S. Yadav1Sanjay Singh2U. S. Yadav3D. P. Rao4Department of Chemistry, North Eastern Regional Institute of Science and Technology (NERIST), Arunachal Pradesh, Nirjuli 791109, IndiaDepartment of Chemistry, North Eastern Regional Institute of Science and Technology (NERIST), Arunachal Pradesh, Nirjuli 791109, IndiaDepartment of Chemistry, M.G.P.G. College, Uattar Pradesh, Gorakhpur 273001, IndiaDepartment of Chemistry, J.P. University, Bihar, Chapra 841301, IndiaDepartment of Chemistry, D.A-V College, Uttar Pradesh, Kanpur 208001, IndiaA series of oxovanadium(IV) complexes of the type [VO(mac)]SO4 (where mac = tetraazamacrocyclic ligands derived from condensation of 4,4,4-trifluro-1-(2-furyl)-1,3-butanedione or 4,4,4-trifluro-1-(2-thenyl)-1,3-butanedione with p-phenylenediamine and their reaction with β-diketones) have been prepared using oxometal ion of vanadium as kinetic template. These complexes have been ascertained by electrical conductance, magnetic moment, elemental analyses, infrared, e.s.r. and electronic spectral data. All the oxovanadium(IV) complexes are five-coordinate ones.http://dx.doi.org/10.1155/2013/689518
spellingShingle A. K. Yadava
H. S. Yadav
Sanjay Singh
U. S. Yadav
D. P. Rao
Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
Journal of Chemistry
title Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
title_full Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
title_fullStr Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
title_full_unstemmed Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
title_short Synthesis and Characterization of Some Novel Schiff Base Complexes of Oxovanadium(IV) Cation
title_sort synthesis and characterization of some novel schiff base complexes of oxovanadium iv cation
url http://dx.doi.org/10.1155/2013/689518
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