Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes
In the dynamic field of pentafluorosulfanyl (SF5) chemistry, the SF5-alkynes have emerged as essential, readily accessible, and modular building blocks for the construction of a wide variety of SF5-containing molecules. This polarized platform has been used to perform highly regio-, chemo-, and ster...
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| Language: | English |
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Académie des sciences
2024-11-01
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| Series: | Comptes Rendus. Chimie |
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| Online Access: | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.350/ |
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| author | René, Floriane Clément–Comoy, Léo Blanchard, Nicolas Bizet, Vincent |
| author_facet | René, Floriane Clément–Comoy, Léo Blanchard, Nicolas Bizet, Vincent |
| author_sort | René, Floriane |
| collection | DOAJ |
| description | In the dynamic field of pentafluorosulfanyl (SF5) chemistry, the SF5-alkynes have emerged as essential, readily accessible, and modular building blocks for the construction of a wide variety of SF5-containing molecules. This polarized platform has been used to perform highly regio-, chemo-, and stereoselective transformations such as heterocycle synthesis, cycloaddition, and hydroelementation reactions. This brief review provides an overview of recent developments in the synthesis and reactivity of SF5-alkynes, which are fascinating building blocks that have yet to reveal their full synthetic potential. |
| format | Article |
| id | doaj-art-37647b5890594579a1a1adcb9921035d |
| institution | Kabale University |
| issn | 1878-1543 |
| language | English |
| publishDate | 2024-11-01 |
| publisher | Académie des sciences |
| record_format | Article |
| series | Comptes Rendus. Chimie |
| spelling | doaj-art-37647b5890594579a1a1adcb9921035d2025-02-07T13:39:46ZengAcadémie des sciencesComptes Rendus. Chimie1878-15432024-11-0127G122724010.5802/crchim.35010.5802/crchim.350Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynesRené, Floriane0https://orcid.org/0009-0003-3197-9960Clément–Comoy, Léo1https://orcid.org/0009-0003-5951-5818Blanchard, Nicolas2https://orcid.org/0000-0002-3097-0548Bizet, Vincent3https://orcid.org/0000-0002-0870-1747Université de Haute-Alsace, Université de Strasbourg, CNRS, LIMA, UMR 7042, 3bis rue Werner, 68000 Mulhouse, FranceUniversité de Haute-Alsace, Université de Strasbourg, CNRS, LIMA, UMR 7042, 3bis rue Werner, 68000 Mulhouse, FranceUniversité de Haute-Alsace, Université de Strasbourg, CNRS, LIMA, UMR 7042, 3bis rue Werner, 68000 Mulhouse, FranceUniversité de Haute-Alsace, Université de Strasbourg, CNRS, LIMA, UMR 7042, 3bis rue Werner, 68000 Mulhouse, FranceIn the dynamic field of pentafluorosulfanyl (SF5) chemistry, the SF5-alkynes have emerged as essential, readily accessible, and modular building blocks for the construction of a wide variety of SF5-containing molecules. This polarized platform has been used to perform highly regio-, chemo-, and stereoselective transformations such as heterocycle synthesis, cycloaddition, and hydroelementation reactions. This brief review provides an overview of recent developments in the synthesis and reactivity of SF5-alkynes, which are fascinating building blocks that have yet to reveal their full synthetic potential.https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.350/PentafluorosulfanylSF<sub>5</sub>-alkyneCycloadditionHydrofunctionalizationRegioselectiveStereoselective |
| spellingShingle | René, Floriane Clément–Comoy, Léo Blanchard, Nicolas Bizet, Vincent Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes Comptes Rendus. Chimie Pentafluorosulfanyl SF<sub>5</sub>-alkyne Cycloaddition Hydrofunctionalization Regioselective Stereoselective |
| title | Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes |
| title_full | Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes |
| title_fullStr | Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes |
| title_full_unstemmed | Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes |
| title_short | Recent achievements in the synthesis and reactivity of pentafluorosulfanyl-alkynes |
| title_sort | recent achievements in the synthesis and reactivity of pentafluorosulfanyl alkynes |
| topic | Pentafluorosulfanyl SF<sub>5</sub>-alkyne Cycloaddition Hydrofunctionalization Regioselective Stereoselective |
| url | https://comptes-rendus.academie-sciences.fr/chimie/articles/10.5802/crchim.350/ |
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