In situ synthesis, structural chemistry and vibrational spectroscopy of Zn-doped Ca5Mg4(VO4)6

In situ synthesis, structural chemistry and vibrational spectroscopy of Zn-doped Ca5Mg4(VO4)6

The phase formation of the solid solution Ca5Mg4–xZnx(VO4)6 (0≤x≤4) was studied in situ using differential scanning calorimetry and high-temperature X-Ray powder diffraction (XRPD). XRPD analysis shows the appearance of unavoidable secondary pyrovanadate phases using conventional synthesis methods....

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Bibliographic Details
Main Authors:	Anna S. Tolkacheva, Sergey N. Shkerin, Sofya A. Petrova, Olga M. Fedorova, Svetlana G. Titova, Ivan I. Leonidov
Format:	Article
Language:	English
Published:	Ural Federal University 2022-03-01
Series:	Chimica Techno Acta
Subjects:	crystal structure, vibrational spectroscopy, x-ray diffraction, ceramics, differential scanning calorimetry, pyrovanadate, garnet
Online Access:	https://chimicatechnoacta.ru/article/view/4962
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