Hydrogels in Simulated Microgravity: Thermodynamics at Play

Hydrogels have become indispensable in biomedical research and regenerative therapies due to their high water content, tissue-like mechanics, and tunable biochemical properties. However, their behavior under altered gravitational conditions—particularly simulated microgravity (SMG)—presents a fronti...

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Main Authors: Azadeh Sepahvandi, Joseph Johnson, Ava Arasan, Ryan Cataldo, Seyed Majid Ghoreishian
Format: Article
Language:English
Published: MDPI AG 2025-05-01
Series:Gels
Subjects:
Online Access:https://www.mdpi.com/2310-2861/11/5/342
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author Azadeh Sepahvandi
Joseph Johnson
Ava Arasan
Ryan Cataldo
Seyed Majid Ghoreishian
author_facet Azadeh Sepahvandi
Joseph Johnson
Ava Arasan
Ryan Cataldo
Seyed Majid Ghoreishian
author_sort Azadeh Sepahvandi
collection DOAJ
description Hydrogels have become indispensable in biomedical research and regenerative therapies due to their high water content, tissue-like mechanics, and tunable biochemical properties. However, their behavior under altered gravitational conditions—particularly simulated microgravity (SMG)—presents a frontier of challenges and opportunities that remain underexplored. This comprehensive review provides a detailed comparative analysis of hydrogel performance in normal gravity versus SMG environments, focusing on the structural, physicochemical, and thermodynamic parameters that govern their functionality. We critically examine how microgravity influences polymer network formation, fluid dynamics, swelling behavior, mechanical stability, and degradation kinetics. SMG disrupts convection, sedimentation, and phase separation, often leading to inhomogeneous crosslinking and altered diffusion profiles. These changes can compromise hydrogel uniformity, anisotropy, and responsiveness, which are essential for biomedical applications such as drug delivery, tissue regeneration, and biosensing. To address these limitations, we propose a thermodynamic framework that integrates osmotic pressure regulation, entropy-driven swelling, and pressure–temperature control to enhance hydrogel stability and functionality in low-gravity environments. The integration of predictive modeling approaches—including finite element simulations, phase-field models, and swelling kinetics—provides a robust pathway to design space-adapted hydrogel systems. The review also outlines future directions for optimizing hydrogel platforms in extraterrestrial settings, advocating for synergistic advances in material science, biophysics, and space health. These insights offer a strategic foundation for the rational development of next-generation hydrogel technologies tailored for long-duration space missions and planetary biomedical infrastructure.
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spelling doaj-art-370c2190116d45b792023454b2fbfcbb2025-08-20T02:33:56ZengMDPI AGGels2310-28612025-05-0111534210.3390/gels11050342Hydrogels in Simulated Microgravity: Thermodynamics at PlayAzadeh Sepahvandi0Joseph Johnson1Ava Arasan2Ryan Cataldo3Seyed Majid Ghoreishian4Department of Mechanical Engineering, University of South Carolina, Columbia, SC 29201, USADepartment of Mechanical Engineering, University of South Carolina, Columbia, SC 29201, USADavis College of Engineering, University of California, Davis, CA 95616, USADepartment of Mechanical Engineering, University of South Carolina, Columbia, SC 29201, USACenter for Energy and Environmental Solutions (CEES), College of STEM-T, South Carolina State University, Orangeburg, SC 29117, USAHydrogels have become indispensable in biomedical research and regenerative therapies due to their high water content, tissue-like mechanics, and tunable biochemical properties. However, their behavior under altered gravitational conditions—particularly simulated microgravity (SMG)—presents a frontier of challenges and opportunities that remain underexplored. This comprehensive review provides a detailed comparative analysis of hydrogel performance in normal gravity versus SMG environments, focusing on the structural, physicochemical, and thermodynamic parameters that govern their functionality. We critically examine how microgravity influences polymer network formation, fluid dynamics, swelling behavior, mechanical stability, and degradation kinetics. SMG disrupts convection, sedimentation, and phase separation, often leading to inhomogeneous crosslinking and altered diffusion profiles. These changes can compromise hydrogel uniformity, anisotropy, and responsiveness, which are essential for biomedical applications such as drug delivery, tissue regeneration, and biosensing. To address these limitations, we propose a thermodynamic framework that integrates osmotic pressure regulation, entropy-driven swelling, and pressure–temperature control to enhance hydrogel stability and functionality in low-gravity environments. The integration of predictive modeling approaches—including finite element simulations, phase-field models, and swelling kinetics—provides a robust pathway to design space-adapted hydrogel systems. The review also outlines future directions for optimizing hydrogel platforms in extraterrestrial settings, advocating for synergistic advances in material science, biophysics, and space health. These insights offer a strategic foundation for the rational development of next-generation hydrogel technologies tailored for long-duration space missions and planetary biomedical infrastructure.https://www.mdpi.com/2310-2861/11/5/342hydrogelsimulated microgravitythermodynamicsmaterial behaviorswelling dynamicscrosslinking mechanisms
spellingShingle Azadeh Sepahvandi
Joseph Johnson
Ava Arasan
Ryan Cataldo
Seyed Majid Ghoreishian
Hydrogels in Simulated Microgravity: Thermodynamics at Play
Gels
hydrogel
simulated microgravity
thermodynamics
material behavior
swelling dynamics
crosslinking mechanisms
title Hydrogels in Simulated Microgravity: Thermodynamics at Play
title_full Hydrogels in Simulated Microgravity: Thermodynamics at Play
title_fullStr Hydrogels in Simulated Microgravity: Thermodynamics at Play
title_full_unstemmed Hydrogels in Simulated Microgravity: Thermodynamics at Play
title_short Hydrogels in Simulated Microgravity: Thermodynamics at Play
title_sort hydrogels in simulated microgravity thermodynamics at play
topic hydrogel
simulated microgravity
thermodynamics
material behavior
swelling dynamics
crosslinking mechanisms
url https://www.mdpi.com/2310-2861/11/5/342
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AT josephjohnson hydrogelsinsimulatedmicrogravitythermodynamicsatplay
AT avaarasan hydrogelsinsimulatedmicrogravitythermodynamicsatplay
AT ryancataldo hydrogelsinsimulatedmicrogravitythermodynamicsatplay
AT seyedmajidghoreishian hydrogelsinsimulatedmicrogravitythermodynamicsatplay