Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers
Abstract A highly efficient magnetic nanocatalyst has been developed by covalently grafting a Pd(0)-Sb@A complex onto a silica-coated nickel ferrite support. This innovative nanocatalyst has been thoroughly analyzed using various techniques, including FT-IR, VSM, XRD, ICP, EDX, XPS, TEM, and FE-SEM....
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Nature Portfolio
2025-07-01
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| Series: | Scientific Reports |
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| Online Access: | https://doi.org/10.1038/s41598-025-10878-2 |
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| author | Anjan Kumar Ahmed M. Naglah Chou-Yi Hsu Jayanti Makasana Suhas Ballal Munther Kadheem Abhayveer Singh T. Krithiga Swati Mishra Pushpa Negi Bhakuni |
| author_facet | Anjan Kumar Ahmed M. Naglah Chou-Yi Hsu Jayanti Makasana Suhas Ballal Munther Kadheem Abhayveer Singh T. Krithiga Swati Mishra Pushpa Negi Bhakuni |
| author_sort | Anjan Kumar |
| collection | DOAJ |
| description | Abstract A highly efficient magnetic nanocatalyst has been developed by covalently grafting a Pd(0)-Sb@A complex onto a silica-coated nickel ferrite support. This innovative nanocatalyst has been thoroughly analyzed using various techniques, including FT-IR, VSM, XRD, ICP, EDX, XPS, TEM, and FE-SEM. Its performance was then evaluated in the synthesis of symmetrical sulfides and unsymmetrical ether derivatives. Key advantages of this approach include high product yields, reduced reaction times, straightforward synthesis, easy magnetic separation, and excellent catalyst recoverability, maintaining activity for at least four cycles without notable degradation. |
| format | Article |
| id | doaj-art-36df1a873ffa46dd92f75e5b650d022d |
| institution | Kabale University |
| issn | 2045-2322 |
| language | English |
| publishDate | 2025-07-01 |
| publisher | Nature Portfolio |
| record_format | Article |
| series | Scientific Reports |
| spelling | doaj-art-36df1a873ffa46dd92f75e5b650d022d2025-08-20T03:42:38ZengNature PortfolioScientific Reports2045-23222025-07-0115111510.1038/s41598-025-10878-2Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethersAnjan Kumar0Ahmed M. Naglah1Chou-Yi Hsu2Jayanti Makasana3Suhas Ballal4Munther Kadheem5Abhayveer Singh6T. Krithiga7Swati Mishra8Pushpa Negi Bhakuni9Department of Electronics and Communication Engineering, GLA UniversityDrug Exploration and Development Chair (DEDC), Department of Pharmaceutical Chemistry, College of Pharmacy, King Saud UniversityThunderbird School of Global Management, Arizona State University Tempe CampusDepartment of Chemistry, Faculty of Science, Marwadi University Research Center, Marwadi UniversityDepartment of Chemistry and Biochemistry, School of Sciences, JAIN (Deemed to Be University)College of Pharmacy, the Islamic UniversityCentre for Research Impact & Outcome, Chitkara University Institute of Engineering and Technology, Chitkara UniversityDepartment of Chemistry, Sathyabama Institute of Science and TechnologyDepartment of Pharmacology IMS and SUM Hospital, Siksha ‘O’ Anusandhan (Deemed to Be University)Department of Allied Science, Graphic Era Hill UniversityAbstract A highly efficient magnetic nanocatalyst has been developed by covalently grafting a Pd(0)-Sb@A complex onto a silica-coated nickel ferrite support. This innovative nanocatalyst has been thoroughly analyzed using various techniques, including FT-IR, VSM, XRD, ICP, EDX, XPS, TEM, and FE-SEM. Its performance was then evaluated in the synthesis of symmetrical sulfides and unsymmetrical ether derivatives. Key advantages of this approach include high product yields, reduced reaction times, straightforward synthesis, easy magnetic separation, and excellent catalyst recoverability, maintaining activity for at least four cycles without notable degradation.https://doi.org/10.1038/s41598-025-10878-2Schiff baseCouplingComplexNanoparticlesNiFe2O4 |
| spellingShingle | Anjan Kumar Ahmed M. Naglah Chou-Yi Hsu Jayanti Makasana Suhas Ballal Munther Kadheem Abhayveer Singh T. Krithiga Swati Mishra Pushpa Negi Bhakuni Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers Scientific Reports Schiff base Coupling Complex Nanoparticles NiFe2O4 |
| title | Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| title_full | Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| title_fullStr | Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| title_full_unstemmed | Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| title_short | Pd(0)-Sb@A@SiO2@NiFe2O4 yolk-shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| title_sort | pd 0 sb a sio2 nife2o4 yolk shell nanostructures as an effective and reusable nanocatalyst for the synthesis of symmetrical sulfides and unsymmetrical ethers |
| topic | Schiff base Coupling Complex Nanoparticles NiFe2O4 |
| url | https://doi.org/10.1038/s41598-025-10878-2 |
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