Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization

Three phenol-formaldehyde resins having pendant maleimides were prepared by poly condensation of N-(hydroxyphenyl) maleimides with formaldehyde under conditions similar to those in Novolac preparation. The prepared resins were modified by two methods, the first one includes esterification of phenoli...

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Main Author: Baghdad Science Journal
Format: Article
Language:English
Published: University of Baghdad, College of Science for Women 2007-03-01
Series:مجلة بغداد للعلوم
Online Access:http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/775
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author Baghdad Science Journal
author_facet Baghdad Science Journal
author_sort Baghdad Science Journal
collection DOAJ
description Three phenol-formaldehyde resins having pendant maleimides were prepared by poly condensation of N-(hydroxyphenyl) maleimides with formaldehyde under conditions similar to those in Novolac preparation. The prepared resins were modified by two methods, the first one includes esterification of phenolic hydroxyl groups in the prepared resins via their treatment with benzoyl, acryloyl, methacryloyl and cinnamoyl chlorides respectively in the presence of triethylamine, while the second modification includes free radical polymerization of vinylic bonds in the prepared resins to produce cross-linked thermally stable polymers.
format Article
id doaj-art-36cc9f8e6760426485b22cfddf59f540
institution Kabale University
issn 2078-8665
2411-7986
language English
publishDate 2007-03-01
publisher University of Baghdad, College of Science for Women
record_format Article
series مجلة بغداد للعلوم
spelling doaj-art-36cc9f8e6760426485b22cfddf59f5402025-08-20T03:33:10ZengUniversity of Baghdad, College of Science for Womenمجلة بغداد للعلوم2078-86652411-79862007-03-014110.21123/bsj.4.1.110-118Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical PolymerizationBaghdad Science JournalThree phenol-formaldehyde resins having pendant maleimides were prepared by poly condensation of N-(hydroxyphenyl) maleimides with formaldehyde under conditions similar to those in Novolac preparation. The prepared resins were modified by two methods, the first one includes esterification of phenolic hydroxyl groups in the prepared resins via their treatment with benzoyl, acryloyl, methacryloyl and cinnamoyl chlorides respectively in the presence of triethylamine, while the second modification includes free radical polymerization of vinylic bonds in the prepared resins to produce cross-linked thermally stable polymers.http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/775
spellingShingle Baghdad Science Journal
Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
مجلة بغداد للعلوم
title Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
title_full Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
title_fullStr Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
title_full_unstemmed Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
title_short Curing of Maleimidyl Phenol-Formaldehyde Resins Via Esterification and Free Radical Polymerization
title_sort curing of maleimidyl phenol formaldehyde resins via esterification and free radical polymerization
url http://bsj.uobaghdad.edu.iq/index.php/BSJ/article/view/775
work_keys_str_mv AT baghdadsciencejournal curingofmaleimidylphenolformaldehyderesinsviaesterificationandfreeradicalpolymerization