Ökonomische Herstellung von Feinchemikalien: Tetronsäure

Tetronic acid (1) is synthesized from ethyl 2,4-dichloroacetoacetate (11) via 3-chlorotetronic acid (9). Ring closure of 11 to 9 is achieved by pyrolysis at normal pressure. In contrast to the bromo-derivative 8, the catalytic conversion of 9 to 1 takes place in water in the absence of base. In thi...

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Bibliographic Details
Main Authors: Thomas Meul, Raimund Miller, Leander Tenud
Format: Article
Language:deu
Published: Swiss Chemical Society 1987-03-01
Series:CHIMIA
Online Access:https://www.chimia.ch/chimia/article/view/9777
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