Nucleotide degradation and ribose salvage in yeast

Abstract Nucleotide degradation is a universal metabolic capability. Here we combine metabolomics, genetics and biochemistry to characterize the yeast pathway. Nutrient starvation, via PKA, AMPK/SNF1, and TOR, triggers autophagic breakdown of ribosomes into nucleotides. A protein not previously asso...

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Main Authors: Yi‐Fan Xu, Fabien Létisse, Farnaz Absalan, Wenyun Lu, Ekaterina Kuznetsova, Greg Brown, Amy A Caudy, Alexander F Yakunin, James R Broach, Joshua D Rabinowitz
Format: Article
Language:English
Published: Springer Nature 2013-05-01
Series:Molecular Systems Biology
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Online Access:https://doi.org/10.1038/msb.2013.21
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author Yi‐Fan Xu
Fabien Létisse
Farnaz Absalan
Wenyun Lu
Ekaterina Kuznetsova
Greg Brown
Amy A Caudy
Alexander F Yakunin
James R Broach
Joshua D Rabinowitz
author_facet Yi‐Fan Xu
Fabien Létisse
Farnaz Absalan
Wenyun Lu
Ekaterina Kuznetsova
Greg Brown
Amy A Caudy
Alexander F Yakunin
James R Broach
Joshua D Rabinowitz
author_sort Yi‐Fan Xu
collection DOAJ
description Abstract Nucleotide degradation is a universal metabolic capability. Here we combine metabolomics, genetics and biochemistry to characterize the yeast pathway. Nutrient starvation, via PKA, AMPK/SNF1, and TOR, triggers autophagic breakdown of ribosomes into nucleotides. A protein not previously associated with nucleotide degradation, Phm8, converts nucleotide monophosphates into nucleosides. Downstream steps, which involve the purine nucleoside phosphorylase, Pnp1, and pyrimidine nucleoside hydrolase, Urh1, funnel ribose into the nonoxidative pentose phosphate pathway. During carbon starvation, the ribose‐derived carbon accumulates as sedoheptulose‐7‐phosphate, whose consumption by transaldolase is impaired due to depletion of transaldolase's other substrate, glyceraldehyde‐3‐phosphate. Oxidative stress increases glyceraldehyde‐3‐phosphate, resulting in rapid consumption of sedoheptulose‐7‐phosphate to make NADPH for antioxidant defense. Ablation of Phm8 or double deletion of Pnp1 and Urh1 prevent effective nucleotide salvage, resulting in metabolite depletion and impaired survival of starving yeast. Thus, ribose salvage provides means of surviving nutrient starvation and oxidative stress.
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spelling doaj-art-3604c67e8fc44eb89cba3406fe3e0b452025-08-20T03:42:11ZengSpringer NatureMolecular Systems Biology1744-42922013-05-019111210.1038/msb.2013.21Nucleotide degradation and ribose salvage in yeastYi‐Fan Xu0Fabien Létisse1Farnaz Absalan2Wenyun Lu3Ekaterina Kuznetsova4Greg Brown5Amy A Caudy6Alexander F Yakunin7James R Broach8Joshua D Rabinowitz9Lewis Sigler Institute for Integrative Genomics, Princeton UniversityUniversité de Toulouse, INSA, UPS, INP; LISBPDepartment of Molecular Biology, Princeton UniversityLewis Sigler Institute for Integrative Genomics, Princeton UniversityDepartment of Chemical Engineering and Applied Chemistry, Banting and Best Department of Medical Research, University of TorontoDepartment of Chemical Engineering and Applied Chemistry, Banting and Best Department of Medical Research, University of TorontoDonnelly Centre for Cellular and Biomolecular Research, University of TorontoDepartment of Chemical Engineering and Applied Chemistry, Banting and Best Department of Medical Research, University of TorontoDepartment of Molecular Biology, Princeton UniversityLewis Sigler Institute for Integrative Genomics, Princeton UniversityAbstract Nucleotide degradation is a universal metabolic capability. Here we combine metabolomics, genetics and biochemistry to characterize the yeast pathway. Nutrient starvation, via PKA, AMPK/SNF1, and TOR, triggers autophagic breakdown of ribosomes into nucleotides. A protein not previously associated with nucleotide degradation, Phm8, converts nucleotide monophosphates into nucleosides. Downstream steps, which involve the purine nucleoside phosphorylase, Pnp1, and pyrimidine nucleoside hydrolase, Urh1, funnel ribose into the nonoxidative pentose phosphate pathway. During carbon starvation, the ribose‐derived carbon accumulates as sedoheptulose‐7‐phosphate, whose consumption by transaldolase is impaired due to depletion of transaldolase's other substrate, glyceraldehyde‐3‐phosphate. Oxidative stress increases glyceraldehyde‐3‐phosphate, resulting in rapid consumption of sedoheptulose‐7‐phosphate to make NADPH for antioxidant defense. Ablation of Phm8 or double deletion of Pnp1 and Urh1 prevent effective nucleotide salvage, resulting in metabolite depletion and impaired survival of starving yeast. Thus, ribose salvage provides means of surviving nutrient starvation and oxidative stress.https://doi.org/10.1038/msb.2013.21autophagymass spectrometrymetabolismnutrient starvationSaccharomyces cerevisiae
spellingShingle Yi‐Fan Xu
Fabien Létisse
Farnaz Absalan
Wenyun Lu
Ekaterina Kuznetsova
Greg Brown
Amy A Caudy
Alexander F Yakunin
James R Broach
Joshua D Rabinowitz
Nucleotide degradation and ribose salvage in yeast
Molecular Systems Biology
autophagy
mass spectrometry
metabolism
nutrient starvation
Saccharomyces cerevisiae
title Nucleotide degradation and ribose salvage in yeast
title_full Nucleotide degradation and ribose salvage in yeast
title_fullStr Nucleotide degradation and ribose salvage in yeast
title_full_unstemmed Nucleotide degradation and ribose salvage in yeast
title_short Nucleotide degradation and ribose salvage in yeast
title_sort nucleotide degradation and ribose salvage in yeast
topic autophagy
mass spectrometry
metabolism
nutrient starvation
Saccharomyces cerevisiae
url https://doi.org/10.1038/msb.2013.21
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