Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel

This article presents the results of tests on the functional properties of oxide layers (Fe<sub>2</sub>O<sub>3</sub>, Cr<sub>1.3</sub>Fe<sub>0.7</sub>O<sub>3</sub>) produced on AISI 316L austenitic steel, which is susceptible to friction we...

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Main Authors: Tomasz Borowski, Hubert Wójcik, Maciej Spychalski, Bogusława Adamczyk-Cieślak
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Metals
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Online Access:https://www.mdpi.com/2075-4701/15/7/707
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author Tomasz Borowski
Hubert Wójcik
Maciej Spychalski
Bogusława Adamczyk-Cieślak
author_facet Tomasz Borowski
Hubert Wójcik
Maciej Spychalski
Bogusława Adamczyk-Cieślak
author_sort Tomasz Borowski
collection DOAJ
description This article presents the results of tests on the functional properties of oxide layers (Fe<sub>2</sub>O<sub>3</sub>, Cr<sub>1.3</sub>Fe<sub>0.7</sub>O<sub>3</sub>) produced on AISI 316L austenitic steel, which is susceptible to friction wear, using a new, simple, inexpensive, and environmentally friendly process conducted in air at three different temperatures (400 °C, 450 °C and 500 °C). Vickers microhardness tests showed that the process slightly increased hardness only at lower indenter loads, indicating a low thickness of the layers. The greatest increase in hardness was observed in the sample oxidized at the lowest temperature. Tests performed using an optical profilometer showed a tendency for surface roughness to increase with oxidation temperature. Low surface roughness, enhanced microhardness and a low coefficient of friction resulted in the steel oxidized at 400 °C exhibiting the lowest wear rate in the “ball-on-disc” test. The contact angle measurements for all tested samples indicated hydrophilic properties. Potentiodynamic tests showed a deterioration in the corrosion resistance of the steel after oxidation at 450 °C and 500 °C. Oxidation at 400 °C did not cause a significant decrease in pitting corrosion resistance, while an increase in polarization resistance and a decrease in corrosion current density were observed. An interesting phenomenon, requiring further research, is the greatest increase in hardness and wear resistance observed in the layer formed at 400 °C.
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spelling doaj-art-35fd95ce6bf0492e9ce8c8cb5f0851d82025-08-20T02:47:10ZengMDPI AGMetals2075-47012025-06-0115770710.3390/met15070707Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic SteelTomasz Borowski0Hubert Wójcik1Maciej Spychalski2Bogusława Adamczyk-Cieślak3Faculty of Materials Science and Engineering, Warsaw University of Technology, 02-507 Warsaw, PolandFaculty of Materials Science and Engineering, Warsaw University of Technology, 02-507 Warsaw, PolandFaculty of Materials Science and Engineering, Warsaw University of Technology, 02-507 Warsaw, PolandFaculty of Materials Science and Engineering, Warsaw University of Technology, 02-507 Warsaw, PolandThis article presents the results of tests on the functional properties of oxide layers (Fe<sub>2</sub>O<sub>3</sub>, Cr<sub>1.3</sub>Fe<sub>0.7</sub>O<sub>3</sub>) produced on AISI 316L austenitic steel, which is susceptible to friction wear, using a new, simple, inexpensive, and environmentally friendly process conducted in air at three different temperatures (400 °C, 450 °C and 500 °C). Vickers microhardness tests showed that the process slightly increased hardness only at lower indenter loads, indicating a low thickness of the layers. The greatest increase in hardness was observed in the sample oxidized at the lowest temperature. Tests performed using an optical profilometer showed a tendency for surface roughness to increase with oxidation temperature. Low surface roughness, enhanced microhardness and a low coefficient of friction resulted in the steel oxidized at 400 °C exhibiting the lowest wear rate in the “ball-on-disc” test. The contact angle measurements for all tested samples indicated hydrophilic properties. Potentiodynamic tests showed a deterioration in the corrosion resistance of the steel after oxidation at 450 °C and 500 °C. Oxidation at 400 °C did not cause a significant decrease in pitting corrosion resistance, while an increase in polarization resistance and a decrease in corrosion current density were observed. An interesting phenomenon, requiring further research, is the greatest increase in hardness and wear resistance observed in the layer formed at 400 °C.https://www.mdpi.com/2075-4701/15/7/707austenitic steel316Loxidationroughnesshardnessfriction wear
spellingShingle Tomasz Borowski
Hubert Wójcik
Maciej Spychalski
Bogusława Adamczyk-Cieślak
Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
Metals
austenitic steel
316L
oxidation
roughness
hardness
friction wear
title Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
title_full Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
title_fullStr Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
title_full_unstemmed Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
title_short Wear and Corrosion Resistance of Thermally Formed Decorative Oxide Layers on Austenitic Steel
title_sort wear and corrosion resistance of thermally formed decorative oxide layers on austenitic steel
topic austenitic steel
316L
oxidation
roughness
hardness
friction wear
url https://www.mdpi.com/2075-4701/15/7/707
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AT hubertwojcik wearandcorrosionresistanceofthermallyformeddecorativeoxidelayersonausteniticsteel
AT maciejspychalski wearandcorrosionresistanceofthermallyformeddecorativeoxidelayersonausteniticsteel
AT bogusławaadamczykcieslak wearandcorrosionresistanceofthermallyformeddecorativeoxidelayersonausteniticsteel