Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures
Abstract Interlayer excitons (IXs) at the interface of heterostructures (HSs) with a staggered band alignment are fascinating quantum quasi‐particles with light‐emitting and long‐lifetime characteristics. In this study, the energy band alignments (EBAs) of the HS of MAPbI3 perovskite thin sheets wit...
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Wiley
2023-05-01
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| Series: | Advanced Science |
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| Online Access: | https://doi.org/10.1002/advs.202207653 |
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| author | Taek Joon Kim Sang‐hun Lee Eunji Lee Changwon Seo Jeongyong Kim Jinsoo Joo |
| author_facet | Taek Joon Kim Sang‐hun Lee Eunji Lee Changwon Seo Jeongyong Kim Jinsoo Joo |
| author_sort | Taek Joon Kim |
| collection | DOAJ |
| description | Abstract Interlayer excitons (IXs) at the interface of heterostructures (HSs) with a staggered band alignment are fascinating quantum quasi‐particles with light‐emitting and long‐lifetime characteristics. In this study, the energy band alignments (EBAs) of the HS of MAPbI3 perovskite thin sheets with CdSe‐ZnS core–shell quantum dot (QD) layers are modulated by using different diameters of the QDs. Far‐red IX emission is observed at 1.42 eV from the HS of MAPbI3/CdSe‐ZnS‐QD (λem = 645 nm) with type‐II EBA owing to charge transfer. The lifetime of the far‐red IXs is estimated to be 5.68 µs, which is considerably longer than that (0.715 ns) of the intralayer excitons from CdSe‐ZnS‐QD. With increasing incident excitation power, the PL peak and its intensity of IXs are blue‐shifted and linearly increased, respectively, indicating a strong dipole alignment of far‐red IXs at the heterojunction. Back focal plane imaging suggests that the directions of dipole moments of the IXs are relatively out‐of‐plane compared to those of the intralayer excitons (MAPbI3 and CdSe‐ZnS‐QD). Notably, the abnormal behavior of the optical characteristics is observed near the phase transition temperature (90 K) of MAPbI3. MAPbI3/CdSe‐ZnS‐QD HS photodetectors show the increase in photocurrent and detectivity compared to MAPbI3 at IX excitation. |
| format | Article |
| id | doaj-art-35c5ad1a1fa84af680f3bed82b26ec86 |
| institution | DOAJ |
| issn | 2198-3844 |
| language | English |
| publishDate | 2023-05-01 |
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| series | Advanced Science |
| spelling | doaj-art-35c5ad1a1fa84af680f3bed82b26ec862025-08-20T03:04:57ZengWileyAdvanced Science2198-38442023-05-011014n/an/a10.1002/advs.202207653Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot HeterostructuresTaek Joon Kim0Sang‐hun Lee1Eunji Lee2Changwon Seo3Jeongyong Kim4Jinsoo Joo5Department of Physics Korea University Seoul 02841 Republic of KoreaDepartment of Physics Korea University Seoul 02841 Republic of KoreaDepartment of Energy Science Sungkyunkwan University Suwon 16419 Republic of KoreaDepartment of Energy Science Sungkyunkwan University Suwon 16419 Republic of KoreaDepartment of Energy Science Sungkyunkwan University Suwon 16419 Republic of KoreaDepartment of Physics Korea University Seoul 02841 Republic of KoreaAbstract Interlayer excitons (IXs) at the interface of heterostructures (HSs) with a staggered band alignment are fascinating quantum quasi‐particles with light‐emitting and long‐lifetime characteristics. In this study, the energy band alignments (EBAs) of the HS of MAPbI3 perovskite thin sheets with CdSe‐ZnS core–shell quantum dot (QD) layers are modulated by using different diameters of the QDs. Far‐red IX emission is observed at 1.42 eV from the HS of MAPbI3/CdSe‐ZnS‐QD (λem = 645 nm) with type‐II EBA owing to charge transfer. The lifetime of the far‐red IXs is estimated to be 5.68 µs, which is considerably longer than that (0.715 ns) of the intralayer excitons from CdSe‐ZnS‐QD. With increasing incident excitation power, the PL peak and its intensity of IXs are blue‐shifted and linearly increased, respectively, indicating a strong dipole alignment of far‐red IXs at the heterojunction. Back focal plane imaging suggests that the directions of dipole moments of the IXs are relatively out‐of‐plane compared to those of the intralayer excitons (MAPbI3 and CdSe‐ZnS‐QD). Notably, the abnormal behavior of the optical characteristics is observed near the phase transition temperature (90 K) of MAPbI3. MAPbI3/CdSe‐ZnS‐QD HS photodetectors show the increase in photocurrent and detectivity compared to MAPbI3 at IX excitation.https://doi.org/10.1002/advs.202207653charge transferfar‐redinterlayer excitonoptoelectronicsperovskitequantum dots |
| spellingShingle | Taek Joon Kim Sang‐hun Lee Eunji Lee Changwon Seo Jeongyong Kim Jinsoo Joo Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures Advanced Science charge transfer far‐red interlayer exciton optoelectronics perovskite quantum dots |
| title | Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures |
| title_full | Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures |
| title_fullStr | Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures |
| title_full_unstemmed | Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures |
| title_short | Far‐Red Interlayer Excitons of Perovskite/Quantum‐Dot Heterostructures |
| title_sort | far red interlayer excitons of perovskite quantum dot heterostructures |
| topic | charge transfer far‐red interlayer exciton optoelectronics perovskite quantum dots |
| url | https://doi.org/10.1002/advs.202207653 |
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