Crystal Structure Studies of Human Dental Apatite as a Function of Age

Studies of the average crystal structure properties of human dental apatite as a function of age in the range of 5–87 years are reported. The crystallinity of the dental hydroxyapatite decreases with the age. The a-lattice constant that is associated with the carbonate content in carbonate apatite d...

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Bibliographic Details
Main Authors: Th. Leventouri, A. Antonakos, A. Kyriacou, R. Venturelli, E. Liarokapis, V. Perdikatsis
Format: Article
Language:English
Published: Wiley 2009-01-01
Series:International Journal of Biomaterials
Online Access:http://dx.doi.org/10.1155/2009/698547
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Summary:Studies of the average crystal structure properties of human dental apatite as a function of age in the range of 5–87 years are reported. The crystallinity of the dental hydroxyapatite decreases with the age. The a-lattice constant that is associated with the carbonate content in carbonate apatite decreases with age in a systematic way, whereas the c-lattice constant does not change significantly. Thermogravimetric measurements demonstrate an increase of the carbonate content with the age. FTIR spectroscopy reveals both B and A-type carbonate substitutions with the B-type greater than the A-type substitution by a factor up to ~5. An increase of the carbonate content as a function of age can be deduced from the ratio of the 𝜈2CO3 to the 𝜈1PO4 IR modes.
ISSN:1687-8787
1687-8795