Characterization of nanoplastics and small-sized microplastics in sewage treatment

Abstract The presence of nanoplastics (NPs) in sewage treatment plants (STPs) remains a critical yet underexplored environmental issue. Here, we present a novel investigation into the occurrence, recovery, and characterization of nanoplastics and small-size microplastics (50–2500 nm) in raw and trea...

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Main Authors: Shaima Iskandarani, Sarvajith Manjunath, Rosa Busquets, Lorenzo Raeli, Pascal E. Saikaly, Luiza C. Campos
Format: Article
Language:English
Published: Nature Portfolio 2025-08-01
Series:Scientific Reports
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Online Access:https://doi.org/10.1038/s41598-025-15504-9
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author Shaima Iskandarani
Sarvajith Manjunath
Rosa Busquets
Lorenzo Raeli
Pascal E. Saikaly
Luiza C. Campos
author_facet Shaima Iskandarani
Sarvajith Manjunath
Rosa Busquets
Lorenzo Raeli
Pascal E. Saikaly
Luiza C. Campos
author_sort Shaima Iskandarani
collection DOAJ
description Abstract The presence of nanoplastics (NPs) in sewage treatment plants (STPs) remains a critical yet underexplored environmental issue. Here, we present a novel investigation into the occurrence, recovery, and characterization of nanoplastics and small-size microplastics (50–2500 nm) in raw and treated sewage effluent from a full-scale STP (treating 4000 m3/day) operating with activated sludge. To our knowledge, this research includes the first confirmed assessment of nanoplastics in such a system and applies nano-flow cytometry to wastewater analysis for the first time globally. It is also the first study addressing micro- and nanoplastics in wastewater in Saudi Arabia, advancing plastic particle analysis in complex matrices. Particles in the 50– < 100 nm range accounted for 44% of total particles detected in STP effluents. Overall, plastic particles accounted for 16% (± 10%) of total particles within 50-2500 nm in raw sewage, increasing to 41% (± 13%) in treated effluent. This increase highlights the inefficiency of conventional treatment in fully removing plastic particles and suggests preferential removal based on size or density. The composition of a representative selection of particles was characterized by micro-Raman spectroscopy and Scanning Electron Microscopy with Energy-Dispersive X-ray. Identified polymers included polystyrene, polyvinyl chloride, polyethylene, polytetrafluoroethylene, polyamide, and polypropylene. These findings provide important insights into treated sewage composition, particularly for reuse in arid regions.
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spelling doaj-art-35355a9f8f06404a84f22ea02b4477d62025-08-20T03:44:05ZengNature PortfolioScientific Reports2045-23222025-08-0115111110.1038/s41598-025-15504-9Characterization of nanoplastics and small-sized microplastics in sewage treatmentShaima Iskandarani0Sarvajith Manjunath1Rosa Busquets2Lorenzo Raeli3Pascal E. Saikaly4Luiza C. Campos5Centre for Urban Sustainability and Resilience, Department of Civil, Environmental and Geomatic Engineering, University College LondonBiological and Environmental Science and Engineering (BESE) Division, King Abdullah University of Science and Technology (KAUST)Centre for Urban Sustainability and Resilience, Department of Civil, Environmental and Geomatic Engineering, University College LondonBioscience Core Lab, KAUSTBiological and Environmental Science and Engineering (BESE) Division, King Abdullah University of Science and Technology (KAUST)Centre for Urban Sustainability and Resilience, Department of Civil, Environmental and Geomatic Engineering, University College LondonAbstract The presence of nanoplastics (NPs) in sewage treatment plants (STPs) remains a critical yet underexplored environmental issue. Here, we present a novel investigation into the occurrence, recovery, and characterization of nanoplastics and small-size microplastics (50–2500 nm) in raw and treated sewage effluent from a full-scale STP (treating 4000 m3/day) operating with activated sludge. To our knowledge, this research includes the first confirmed assessment of nanoplastics in such a system and applies nano-flow cytometry to wastewater analysis for the first time globally. It is also the first study addressing micro- and nanoplastics in wastewater in Saudi Arabia, advancing plastic particle analysis in complex matrices. Particles in the 50– < 100 nm range accounted for 44% of total particles detected in STP effluents. Overall, plastic particles accounted for 16% (± 10%) of total particles within 50-2500 nm in raw sewage, increasing to 41% (± 13%) in treated effluent. This increase highlights the inefficiency of conventional treatment in fully removing plastic particles and suggests preferential removal based on size or density. The composition of a representative selection of particles was characterized by micro-Raman spectroscopy and Scanning Electron Microscopy with Energy-Dispersive X-ray. Identified polymers included polystyrene, polyvinyl chloride, polyethylene, polytetrafluoroethylene, polyamide, and polypropylene. These findings provide important insights into treated sewage composition, particularly for reuse in arid regions.https://doi.org/10.1038/s41598-025-15504-9WastewaterTreated sewage effluentSewage treatment plantNano-flow cytometryConfocal Raman
spellingShingle Shaima Iskandarani
Sarvajith Manjunath
Rosa Busquets
Lorenzo Raeli
Pascal E. Saikaly
Luiza C. Campos
Characterization of nanoplastics and small-sized microplastics in sewage treatment
Scientific Reports
Wastewater
Treated sewage effluent
Sewage treatment plant
Nano-flow cytometry
Confocal Raman
title Characterization of nanoplastics and small-sized microplastics in sewage treatment
title_full Characterization of nanoplastics and small-sized microplastics in sewage treatment
title_fullStr Characterization of nanoplastics and small-sized microplastics in sewage treatment
title_full_unstemmed Characterization of nanoplastics and small-sized microplastics in sewage treatment
title_short Characterization of nanoplastics and small-sized microplastics in sewage treatment
title_sort characterization of nanoplastics and small sized microplastics in sewage treatment
topic Wastewater
Treated sewage effluent
Sewage treatment plant
Nano-flow cytometry
Confocal Raman
url https://doi.org/10.1038/s41598-025-15504-9
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