Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution

The leaching kinetics of reductive leaching of manganese from manganese dioxide ores (MDO) in dilute sulfuric acid in the presence of Phytolacca americana powder (PAP) was investigated. The effects of stirring speed, leaching temperature and leaching time, particle size, weight ratio of PAP to MDO (...

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Main Authors: Jianrong Xue, Hong Zhong, Shuai Wang, Changxin Li, Jinzhong Li, Fangfang Wu
Format: Article
Language:English
Published: Springer 2016-07-01
Series:Journal of Saudi Chemical Society
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Online Access:http://www.sciencedirect.com/science/article/pii/S1319610314001501
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author Jianrong Xue
Hong Zhong
Shuai Wang
Changxin Li
Jinzhong Li
Fangfang Wu
author_facet Jianrong Xue
Hong Zhong
Shuai Wang
Changxin Li
Jinzhong Li
Fangfang Wu
author_sort Jianrong Xue
collection DOAJ
description The leaching kinetics of reductive leaching of manganese from manganese dioxide ores (MDO) in dilute sulfuric acid in the presence of Phytolacca americana powder (PAP) was investigated. The effects of stirring speed, leaching temperature and leaching time, particle size, weight ratio of PAP to MDO (CW) and sulfuric acid concentration (CH) on the leaching efficiency of manganese were studied. The leaching efficiency of manganese based on the shrinking core model was found to be controlled by diffusion through the ash/inert layer composed of the associated minerals. The apparent activation energy is 15.18 kJ mol−1. The experimental results indicate reaction order of 0.797 for CH and 1.25 for CW. The overall leaching efficiency equations for MDO dissolution reaction with PAP in dilute sulfuric acid were proposed by a semi-empirical model.
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institution Kabale University
issn 1319-6103
language English
publishDate 2016-07-01
publisher Springer
record_format Article
series Journal of Saudi Chemical Society
spelling doaj-art-34f7d4b2d57c408a8e5b8374dc52d9c82025-08-20T03:49:12ZengSpringerJournal of Saudi Chemical Society1319-61032016-07-0120443744210.1016/j.jscs.2014.09.011Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solutionJianrong XueHong ZhongShuai WangChangxin LiJinzhong LiFangfang WuThe leaching kinetics of reductive leaching of manganese from manganese dioxide ores (MDO) in dilute sulfuric acid in the presence of Phytolacca americana powder (PAP) was investigated. The effects of stirring speed, leaching temperature and leaching time, particle size, weight ratio of PAP to MDO (CW) and sulfuric acid concentration (CH) on the leaching efficiency of manganese were studied. The leaching efficiency of manganese based on the shrinking core model was found to be controlled by diffusion through the ash/inert layer composed of the associated minerals. The apparent activation energy is 15.18 kJ mol−1. The experimental results indicate reaction order of 0.797 for CH and 1.25 for CW. The overall leaching efficiency equations for MDO dissolution reaction with PAP in dilute sulfuric acid were proposed by a semi-empirical model.http://www.sciencedirect.com/science/article/pii/S1319610314001501Manganese dioxide orePhytolacca americana branch powderReduction leachingKinetics
spellingShingle Jianrong Xue
Hong Zhong
Shuai Wang
Changxin Li
Jinzhong Li
Fangfang Wu
Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
Journal of Saudi Chemical Society
Manganese dioxide ore
Phytolacca americana branch powder
Reduction leaching
Kinetics
title Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
title_full Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
title_fullStr Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
title_full_unstemmed Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
title_short Kinetics of reduction leaching of manganese dioxide ore with Phytolacca americana in sulfuric acid solution
title_sort kinetics of reduction leaching of manganese dioxide ore with phytolacca americana in sulfuric acid solution
topic Manganese dioxide ore
Phytolacca americana branch powder
Reduction leaching
Kinetics
url http://www.sciencedirect.com/science/article/pii/S1319610314001501
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