A new fluorescent probe based on BODIPY for testing NO2 released from propellants
After long-term storage, solid propellants often exhibit various aging characteristics. This study presents a strategy for assessing the state of propellants using the Boron-dipyrrole Ni complex (BDP-Ni) as a probe. The thermogravimetric and cyclic voltammetry results indicate that the probe BDP-Ni...
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| Format: | Article |
| Language: | English |
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KeAi Communications Co. Ltd.
2025-03-01
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| Series: | Energetic Materials Frontiers |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2666647224000812 |
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| author | Ying-cui Cui De-bin Xia Zhong-yu Cui Yu-jing Li Jian Zhang Ping Wang Ting Guo Kai-feng Lin Yu-lin Yang |
| author_facet | Ying-cui Cui De-bin Xia Zhong-yu Cui Yu-jing Li Jian Zhang Ping Wang Ting Guo Kai-feng Lin Yu-lin Yang |
| author_sort | Ying-cui Cui |
| collection | DOAJ |
| description | After long-term storage, solid propellants often exhibit various aging characteristics. This study presents a strategy for assessing the state of propellants using the Boron-dipyrrole Ni complex (BDP-Ni) as a probe. The thermogravimetric and cyclic voltammetry results indicate that the probe BDP-Ni exhibits excellent thermal stability and electrochemical stability. By utilizing both solution and thin films of BDP-Ni, we successfully detected NO2 gas and observed a significant fluorescence intensity response to varying concentrations of NO2. Subsequently, selectivity experiments with other characteristic gases confirmed the high specificity of BDP-Ni for NO2. Furthermore, accelerated aging experiments of propellants were conducted alongside BDP-Ni films under identical conditions. This method can not only calculate the NO2 gas concentration released from propellants based on fluorescence changes of BDP-Ni but also infer the state of propellants. The probe can additionally function as an 'alarm' to evaluate the extent of stabilizer consumption in the propellant. This work illustrates the preparation of the fluorescence probe and offers a new approach for detecting characteristic gases released from propellants. |
| format | Article |
| id | doaj-art-34b7958ae8fd4460ba6258923ce5ed2d |
| institution | DOAJ |
| issn | 2666-6472 |
| language | English |
| publishDate | 2025-03-01 |
| publisher | KeAi Communications Co. Ltd. |
| record_format | Article |
| series | Energetic Materials Frontiers |
| spelling | doaj-art-34b7958ae8fd4460ba6258923ce5ed2d2025-08-20T03:10:28ZengKeAi Communications Co. Ltd.Energetic Materials Frontiers2666-64722025-03-016111211710.1016/j.enmf.2024.11.001A new fluorescent probe based on BODIPY for testing NO2 released from propellantsYing-cui Cui0De-bin Xia1Zhong-yu Cui2Yu-jing Li3Jian Zhang4Ping Wang5Ting Guo6Kai-feng Lin7Yu-lin Yang8State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, China; Corresponding author. State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China.State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaState Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaInner Mongolia Synthetic Chemical Engineering Institute, Huhhot, 010010, ChinaState Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, China; National Key Laboratory of Aerospace Chemical Power, Xiangyang, 441003, China; Corresponding author. State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China.State Key Laboratory of Space Power-Sources, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, 150001, China; MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage, Harbin Institute of Technology, Harbin, 150001, ChinaAfter long-term storage, solid propellants often exhibit various aging characteristics. This study presents a strategy for assessing the state of propellants using the Boron-dipyrrole Ni complex (BDP-Ni) as a probe. The thermogravimetric and cyclic voltammetry results indicate that the probe BDP-Ni exhibits excellent thermal stability and electrochemical stability. By utilizing both solution and thin films of BDP-Ni, we successfully detected NO2 gas and observed a significant fluorescence intensity response to varying concentrations of NO2. Subsequently, selectivity experiments with other characteristic gases confirmed the high specificity of BDP-Ni for NO2. Furthermore, accelerated aging experiments of propellants were conducted alongside BDP-Ni films under identical conditions. This method can not only calculate the NO2 gas concentration released from propellants based on fluorescence changes of BDP-Ni but also infer the state of propellants. The probe can additionally function as an 'alarm' to evaluate the extent of stabilizer consumption in the propellant. This work illustrates the preparation of the fluorescence probe and offers a new approach for detecting characteristic gases released from propellants.http://www.sciencedirect.com/science/article/pii/S2666647224000812PropellantAgingNO2Fluorescent probe |
| spellingShingle | Ying-cui Cui De-bin Xia Zhong-yu Cui Yu-jing Li Jian Zhang Ping Wang Ting Guo Kai-feng Lin Yu-lin Yang A new fluorescent probe based on BODIPY for testing NO2 released from propellants Energetic Materials Frontiers Propellant Aging NO2 Fluorescent probe |
| title | A new fluorescent probe based on BODIPY for testing NO2 released from propellants |
| title_full | A new fluorescent probe based on BODIPY for testing NO2 released from propellants |
| title_fullStr | A new fluorescent probe based on BODIPY for testing NO2 released from propellants |
| title_full_unstemmed | A new fluorescent probe based on BODIPY for testing NO2 released from propellants |
| title_short | A new fluorescent probe based on BODIPY for testing NO2 released from propellants |
| title_sort | new fluorescent probe based on bodipy for testing no2 released from propellants |
| topic | Propellant Aging NO2 Fluorescent probe |
| url | http://www.sciencedirect.com/science/article/pii/S2666647224000812 |
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